Role of lattice distortion and A site cation in the phase transitions of methylammonium lead halide perovskites [PDF]
The rapid increase in power conversion efficiencies of photovoltaic devices incorporating lead halide perovskites has resulted in intense interest in the cause of their excellent properties. In the present paper, resonant ultrasound spectroscopy has been used to determine the elastic and anelastic properties of CH3NH3PbX3 (where X=Cl, Br, or I) and ...
Harwell, Jonathon R. +8 more
openaire +3 more sources
Junction Physics and Architectural Paradigms in Optoelectronic Semiconductor Fibers
Optoelectronic fibers are emerging as a key platform for distributed sensing, energy harvesting, and optical communication in deformable systems. Their performance is fundamentally governed by junction formation under confined, dynamic processing conditions.
Hailiang Wang +4 more
wiley +1 more source
Does Dipolar Motion of Organic Cations Affect Polaron Dynamics and Bimolecular Recombination in Halide Perovskites? [PDF]
The role of dipolar motion of organic cations in the A-sites of halide perovskites has been debated in an effort to understand why these materials possess such remarkable properties. Here, we show that the dipolar motion of cations such as methylammonium
Jianing Gan (8682156) +3 more
core +1 more source
A vapor‐phase molecular toughening strategy is developed for pilot‐scale roll‐to‐roll (R2R) ‐compatible fabrication of flexible perovskite solar modules. Thiol vapor selectively regulates crystallization and anchors at grain boundaries, reducing defects while enhancing mechanical resilience.
Lirong Dong +18 more
wiley +2 more sources
Mixed‐Polymer Hole Transport Layers Reinforce Au‐Anode Top Emitting Perovskite Light Emitting Diodes
Au‐anode corrosion is shown to occur rapidly under voltage bias in MAPbI3 perovskite LEDs. Resulting Au+ migration quickly leads to device shorting and unstable emission during constant current driving. We demonstrate that using a simple mixed‐polymer hole transport layer containing polyTPD and PVK can reduce Au‐corrosion and stabilize LED operation ...
James C. Loy +5 more
wiley +1 more source
Based on the largest printable mesoscopic perovskite solar cells database we established, stacking model achieved precise PCE prediction (R2 = 0.73, MAE = 2.18%). Multiple experiments verified the accuracy of the model, which guided the fabrication of high‐PCE devices with an efficiency of 19.36%.
Hao Meng +9 more
wiley +1 more source
Dual Interface Modification for Reduced Nonradiative Recombination in n–i–p Methylammonium-Free Perovskite Solar Cells [PDF]
High defect concentrations at the interfaces are the basis of charge extraction losses and instability in perovskite solar cells. Surface engineering with organic cations is a common practice to solve this issue.
Turren Cruz, Silver Hamill
core +1 more source
Dry‑Contact Trimming for All‑Perovskite Tandem Solar Cells via Solid‑Solution Homogenization
Narrow‐bandgap Sn–Pb perovskites are promising bottom absorbers for all‐perovskite tandems but suffer from Sn‐rich surfaces and depth‐dependent lattice/compositional inhomogeneity. Layered‐perovskite‐assisted dry‐contact trimming removes Sn‐rich surface species and reconfigures the Sn–Pb absorber, enabling efficient charge collection, reduced voltage ...
Woocheol Han +10 more
wiley +1 more source
Relationship between the Nature of Monovalent Cations and Charge Recombination in Metal Halide Perovskites [PDF]
We report charge recombination rates in lead iodide perovskites with alloys of formamidinium (FA) and methylammonium (MA) cations, FAxMA1–xPbI3, 0 ≤ x ≤ 0.9, prepared through ion exchange with minimal differences in morphology and charge trap density ...
Ying-Zhong Ma (1343253) +11 more
core +1 more source
Solar cells based on the novel triple cation tin perovskite MA0.75FA0.15PEA0.1SnI3 exhibit PCEs of 5.0% and notably good stability over more than 5000 hours.
Thomas Rath +9 more
openaire +2 more sources

