Results 181 to 190 of about 164,501 (255)

Mechanically Interlocked Indigo Photoswitches

open access: yesAngewandte Chemie, EarlyView.
By incorporating indigo photoswitches into the axle of a rotaxane, which features a hydrogen bonding macrocycle, we demonstrate improvement in activation wavelength, photostationary states and thermal reversion, an effect that is governed by topologically constrained supramolecular interactions.
Alexander M. Wilmshurst   +9 more
wiley   +2 more sources

Synthesis of Six Natural Products Enabled by Selective Hydroxylation of Orcinaldehyde‐Like Substrates With an Enzyme Library

open access: yesAngewandte Chemie, EarlyView.
Achieving selective (sp3)C–H hydroxylation can streamline the synthesis of complex organic molecules. Biocatalysis presents an opportunity to realize this transformation, however, identifying useful enzymes that enable synthetic strategies can be a challenge due to limitations in enzyme substrate scope.
Gonzalo J. Villegas Rodríguez   +5 more
wiley   +2 more sources

Generation of the Camptothecin Scaffold by a Flavin‐Catalyzed Photooxidative Skeletal Reorganization

open access: yesAngewandte Chemie, EarlyView.
The biosynthetic pathway of the anticancer drug precursor camptothecin involves an enigmatic skeletal reorganization from a 6/5/6 tetrahydro‐β‐carboline to a 6/6/5 pyrroloquinoline ring system. Here, we show that this transformation can be achieved by photooxidation with flavin cofactors, such as flavin mononucleotide (FMN) as catalysts.
Shenyu Liu   +6 more
wiley   +2 more sources

Disentangling the absorption lineshape of methylene blue for nanocavity strong coupling. [PDF]

open access: yesNanophotonics
Gomez SA   +5 more
europepmc   +1 more source

Ultra‐Thin and Highly Insulating Aromatic Monolayers by N‐Heterocyclic Carbenes

open access: yesAngewandte Chemie, EarlyView.
By using N‐heterocyclic carbenes extremally insulating and at the same time as thin as 0.3 nm molecular films are formed. The charge transport calculations indicate absence of destructive quantum interference effect which was so far the only way to suppress conductivity in aromatic molecules.
Mateusz Wróbel   +6 more
wiley   +2 more sources

Removal of Mini-Sling Anchor With Magnetic Resonance Imaging-Guided Site Marking With Methylene Blue. [PDF]

open access: yesO G Open
Shih S   +6 more
europepmc   +1 more source

Magnetic amino-functionalized hyper-crosslinked resin as a reusable adsorbent for methylene blue. [PDF]

open access: yesSci Rep
Cirillo C   +8 more
europepmc   +1 more source

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