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Responsive microgels and microgel assemblies in biocatalytic applications

Journal of Polymer Science, 2023
AbstractMicrogels are soft particles that offer excellent colloidal stability, large surface area, and fluid‐like transport characteristics, making them ideal for enzyme immobilization and reaction regulation. In recent years, the use of microgels in enzyme processes has rapidly increased and reviewed.
Nidhi C. Dubey   +2 more
openaire   +1 more source

Hollow Thermoresponsive Microgels

Small, 2005
AbstractThermoresponsive poly(N‐isopropyl acrylamide) (pNIPAm) microgels possessing a hollow structure have been synthesized from core–shell nanoparticles upon oxidation of the particle core, followed by removal of the produced polymer segments by centrifugation.
Satish, Nayak   +3 more
openaire   +2 more sources

Thermoresponsive copolymer microgels

Journal of Materials Chemistry B, 2013
Colloidal aqueous microgels have attracted notable attention due to their possible applications in both polymer chemistry and the (bio)material sector. Due to their soft internal network structure and their response to different external stimuli, they are suitable as carrier systems for different kinds of molecules (e.g.
Hertle, Yvonne, Hellweg, Thomas
openaire   +2 more sources

Microgel‐Stabilized Metal Nanoclusters: Size Control by Microgel Nanomorphology

Advanced Materials, 2003
Soluble crosslinked macromolecules (microgels) used as stabilizers of catalytically active metal nanoclusters allow control of the nanocluster size by simply changing the crosslinking degree of the microgel. Microgel‐stabilized metal nanoclusters are easily prepared and stored in the solid state, and those of Pd (see Figure) exhibit high catalytic ...
BIFFIS, ANDREA   +2 more
openaire   +3 more sources

Impact of Microgel Morphology on Functionalized Microgel−Drug Interactions

Langmuir, 2008
The interactions of a range of water-soluble drugs of different charges and hydrophobicities with carboxylic acid-functionalized poly(N-isopropylacrylamide)-based microgels containing different functional group distributions are investigated to determine the impact of drug properties and microgel morphologies on drug uptake and release.
Todd, Hoare, Robert, Pelton
openaire   +2 more sources

Marine Microgels

Annual Review of Marine Science, 2012
The ocean plays a critical role in global carbon cycling: it handles half of the global primary production, yielding the world's largest stock of reduced organic carbon (ROC) that supports one of the world's largest biomasses. However, the mechanisms whereby ROC becomes mineralized remain unresolved.
openaire   +2 more sources

Multiphase protein microgels.

Macromolecular bioscience, 2015
Peptides and proteins represent attractive building blocks for the development of new functional materials due to the biocompatibility and biodegradability of many naturally abundant proteins. In nature, sophisticated material functionality is commonly achieved through spatial control of protein localisation and structure on both the nano and micro ...
Ulyana Shimanovich   +4 more
openaire   +2 more sources

Microfiltration of deformable microgels

Soft Matter, 2016
Understanding the separation, concentration and purification processes of soft nanoparticles is essential for numerous applications in water filtration, bioprocessing and blood separation. Here we report unique translocation and rejection features of sub-micron sized microgels during frontal filtration using membranes having micron-sized porosity ...
Oded, Nir   +3 more
openaire   +2 more sources

Polyvinylalcohol Microgel

Chemistry Letters, 1997
Abstract Soap-free copolymerization of vinyl acetate and N,N′-dimethyl-N,N′-divinyl-sebacoyldiamide followed by alkaline hydrolysis afforded poly(vinyl alcohol) microgel.
Takashi Fukutomi   +2 more
openaire   +1 more source

Ultrasoft, highly deformable microgels

Soft Matter, 2015
PNIPAm microgels formed under crosslinker free conditions are soft and highly deformable.
Haylee Bachman   +13 more
openaire   +2 more sources

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