Results 211 to 220 of about 6,939,509 (283)

Competing Charge Separation Pathways Govern Charge Generation in Organic Photovoltaic Blends: Insights From Transient Electron Spin Resonance

open access: yesAdvanced Energy Materials, EarlyView.
Transient electron spin resonance distinguishes interfacial charge‐transfer states from separated charges, revealing competing charge separation pathways in organic photovoltaic blends. The relative contributions of fast charge separation and a pathway mediated by spin‐polarized charge‐transfer states vary across different blends, with high‐efficiency ...
Jack M. S. Palmer, Claudia E. Tait
wiley   +1 more source

Monitoring the Microwave Synthesis of d0‐Free Disordered Rocksalt Cathodes Using In Situ Infrared Pyrometry

open access: yesAngewandte Chemie, EarlyView.
Despite its promise for producing metastable materials, the mechanisms underlying solid‐state microwave synthesis remain poorly understood. By combining in situ thermography with x‐ray diffraction and solid‐state NMR, this study uncovers a surprising order–disorder–order reaction pathway during the microwave synthesis of the Li1.1Mn0.9O1.9F0.1${\rm Li ...
Erick A. Lawrence   +8 more
wiley   +2 more sources

Multi-wavelength spin dynamics of defects in hexagonal boron nitride. [PDF]

open access: yesLight Sci Appl
Zhigulin I   +6 more
europepmc   +1 more source

Fluorescent Hydrogel‐Based Strain Sensor With Machine Learning‐Augmented Performance

open access: yesAdvanced Intelligent Discovery, EarlyView.
Fluorescent hydrogel strain sensor based on carbon quantum dots enabling optical readout of deformation through strain‐dependent emission changes, coupled with Random Forest analysis to capture nonlinear fluorescence‐concentration relationships and identify optimal sensing conditions. Hydrogels are ideal matrices for bio‐integrated wearable sensors due
Tailai Chen   +4 more
wiley   +1 more source

Hydrogen‐Bonding Order Associated With Radical Delocalization in Layered Organic Cathode Materials

open access: yesAngewandte Chemie, EarlyView.
“TAQ” and TAPT share the same pyrazine‐based molecular structure but differ in degree of crystallinity. Combined x‐ray scattering, solid‐state NMR, MicroED, and EPR reveal that “TAQ”'s higher crystallinity and ordered hydrogen‐bonding network are associated with enhanced radical delocalization and conductivity, highlighting structural order as a design
Alae Eddine Lakraychi   +14 more
wiley   +2 more sources

Evaluation of therapeutic effects of D‐limonene following orchiopexy in the rat model of cryptorchidism

open access: yesAnimal Models and Experimental Medicine, EarlyView.
D‐limonene supplementation enhances testicular recovery following orchiopexy in a rat model of bilateral cryptorchidism. Treatment with D‐limonene reduces oxidative stress (↓MDA, ↑SOD, ↑GPx, ↑TAC), downregulates pro‐apoptotic proteins (↓TNF‐α, ↓BAX, ↓Caspase‐3), and upregulates anti‐apoptotic Bcl‐2 expression.
Arman Norouzi‐Ghalehbala   +6 more
wiley   +1 more source

Gold Clusters With Open‐Shell Ligands: Superatom Mediated Magnetic Interaction

open access: yesAngewandte Chemie, EarlyView.
Open‐shell verdazyl radicals were covalently integrated with atomically precise Ir‐doped Au12 (Ir@Au12) superatoms. The resulting radical–superatom hybrids exhibit photoinduced electron transfer, spin delocalization onto the metal‐cluster core, and weak ferromagnetic communication between radicals mediated by the superatomic electronic structure ...
Katsuya Mutoh   +7 more
wiley   +2 more sources

Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex

open access: yesAngewandte Chemie, EarlyView.
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer   +6 more
wiley   +2 more sources

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