Results 191 to 200 of about 19,327 (265)

Pressure‐Enhanced CO2‐to‐CO Electroreduction on Ag‐Based Catalysts: Industrially Relevant Rates and Mechanistic Insights

open access: yesCarbon Energy, EarlyView.
Ag‐based catalysts operated under elevated CO2 pressures exhibit markedly enhanced intrinsic activity for CO formation, with OD‐Ag achieving −200 mA cm–2 and 90% FECO at −1.3 VRHE. Mechanistic analysis shows that high pressure strengthens a *COOH‐mediated pathway by increasing intermediate coverage and suppressing hydrogen evolution, establishing CO2 ...
Sheraz Ahmed   +6 more
wiley   +1 more source

The Effect of Water Management and Cell Compression in Bipolar Membrane CO2 Electrolysis to CO

open access: yesCarbon Energy, EarlyView.
In‐operando neutron imaging uncovers water management challenges in bipolar membrane CO2 electrolysis: Internal water generation floods the cathode, while compression dictates membrane and gas diffusion electrode integrity. Strategic adjustments are applied in this work: dry gas feed and mechanical support of the gas diffusion electrode enable stable ...
Frederik Brendel   +7 more
wiley   +1 more source

Catalyst‐Free Cyanation of Arenes by Acetonitrile in a Plasma–Liquid Microreactor

open access: yesChemistry – A European Journal, EarlyView.
An original approach of arylnitrile synthesis was developed by generating an argon plasma in contact with solutions of arene in acetonitrile within a gas‐liquid microreactor. Plasma activation of acetonitrile generated cyano radicals, enabling a catalyst‐free C‐H cyanation of arenes.
Pierre Dedieu   +4 more
wiley   +1 more source

Global and Detailed Calculation of Tube Wall Temperature in a Process Furnace Steam Superheater

open access: yesChemie Ingenieur Technik, EarlyView.
This study presents a comparison between an iterative global model and multiple approaches to a new non‐iterative model with the purpose of predicting tube wall temperature of a superheater. The results show that the non‐iterative method achieves sufficient accuracy while improving the prediction of local temperature distribution and better ...
Anežka Michálková, Zdeněk Jegla
wiley   +1 more source

An Analytical Design Model of a Vacuum Pressure Swing Adsorption Process for Biogas Upgrading

open access: yesChemie Ingenieur Technik, EarlyView.
A steady‐state model was developed for a vacuum pressure swing adsorption (VPSA) process comprising adsorption, depressurization, and evacuation steps. The resulting analytical plant design model provides the optimal adsorber height required to achieve a target product purity with maximum bed utilization.
Thomas Welter   +3 more
wiley   +1 more source

Selective Non‐Catalytic Reduction of NOx in the Exhaust Gas of Small Wood Gasification Boilers

open access: yesChemie Ingenieur Technik, EarlyView.
Kinetic studies of the SNCR reaction were conducted to investigate NOx reduction in the exhaust gas of small‐scale wood gasification boilers. Both the experimental results and the derived global kinetic model indicate that SNCR can achieve a significant reduction in NOx emissions under typical operating conditions. ABSTRACT The gas‐phase reaction of NO
Alexander Groß, Sven Kureti
wiley   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque   +3 more
wiley   +1 more source

Microwave‐assisted catalytic pyrolysis of textile wastes: Synergistic effects and product characteristics

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study examines the microwave‐assisted catalytic pyrolysis (MACP) of individual and blended textiles (cotton, polyester, nylon 6) using ZnO and a ZnO/natural zeolite catalyst. In a custom‐built microwave reactor operated at 500°C, 1 kW power, and a 15‐min residence time, textile wastes were pyrolyzed.
Peyman Alizadeh   +3 more
wiley   +1 more source

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