Results 51 to 60 of about 56,303 (261)

Solventless synthesis of MOFs at high pressure

open access: yes, 2016
Besides the substitution or minimization of the use of harmful solvents, one essential goal of chemistry is to try to avoid their use altogether whenever possible. In the case of the synthesis of MOFs (metal–organic frameworks), this can only be achieved
Paseta, Lorena   +3 more
core   +1 more source

Functionalizing Micro‐to‐Mesoscopic Electrode Architectures for Regulating Electron Transfer Behaviors in Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
A systematic review is conducted to assess the influence of electrode architecture across micro‐ to mesoscopic length scales on electron‐transfer pathways in electrocatalysis. We discuss the structure‐activity relationships in electrocatalytic applications, including resource recovery and environmental remediation, and provide cost‐effective, efficient
Manshu Zhao   +6 more
wiley   +1 more source

Theoretical and experimental exploration of tri-metallic organic frameworks (t-MOFs) for efficient electrocatalytic oxygen evolution reaction

open access: yes, 2021
High performance and cost-effective electrocatalysts are crucial to the oxygen evolution reaction (OER) in water splitting. Herein, we use density functional theory (DFT) calculation to systematically explore the catalytic activities of single-metallic ...
Tian, Y   +6 more
core   +1 more source

2D Co‐Assembly of Solid Acids Enables Stable Superprotonic Conduction Above 260°C

open access: yesAdvanced Functional Materials, EarlyView.
A two‐dimensional co‐assembly strategy integrates antimony phosphate and phosphotungstic acid nanosheets into free‐standing inorganic lamellar membranes with confined acid–acid interfaces. The resulting interfacial hydrogen‐bond network enables anhydrous proton conductivity exceeding 0.1 S cm−1 at 260°C and supports stable high‐temperature fuel‐cell ...
Qiuning Li   +8 more
wiley   +1 more source

Metal-organic frameworks (MOFs) for bone treatment and mineralization

open access: yesEuropean Cells & Materials
Metal-organic frameworks (MOFs) have emerged as a flexible class of porous materials with tunable physicochemical properties, making them well-suited for biomedical applications, particularly bone regeneration and biomineralization.
Hani Nasser Abdelhamid
doaj   +1 more source

Vanadium‐based metal‐organic frameworks and their derivatives for electrochemical energy conversion and storage

open access: yesSmartMat, 2022
With the excessive consumption of nonrenewable resources, the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system.
Jing Zhu   +7 more
doaj   +1 more source

Balancing Hydrophobicity and Hydrophilicity: Dual Filler‐Engineered Proton Exchange Membranes for Durable, High‐Power Fuel Cells

open access: yesAdvanced Functional Materials, EarlyView.
Polarity‐matched Zr–MOFs program Nafion's nanoscale morphology during solution casting. Hydrophilic UiO‐66 preserves hydrated pathways, while hydrophobic UiO‐67 increases the proton hopping sites by densifying ionic clusters. Combining both fillers yields a membrane that delivers 176 mS cm−1 conductivity, reaches 1.46 W cm−2 under 200 kPa, and triples ...
Yonghwi Cho   +13 more
wiley   +1 more source

Conductivity and mechanical properties of PEO/PVA/UiO-66 composite polymers for membrane of lithium-ion batteries

open access: yesCommunications in Science and Technology
Lithium batteries are crucial for energy storage in electronics, transportation, and industrial sectors. However, lithium-ion battery separators such as Celgard require significant improvements, particularly in ionic conductivity (?).
Aep Patah   +3 more
doaj   +1 more source

Gradient‐Conductivity Architecture Enables Synchronous Enhancement of Sensitivity and Detection Range in Multifunctional All‐Paper Sensors

open access: yesAdvanced Functional Materials, EarlyView.
A gradient‐engineered all‐paper sensor is fabricated by integrating MXene and in situ grown AgNPs within hierarchical cellulose networks. The device breaks the sensitivity–detection range trade‐off through cascaded conductive pathways, enabling ultrahigh pressure sensitivity, humidity–pressure decoupled dual‐mode sensing, and outstanding EMI shielding,
Ao Li   +7 more
wiley   +1 more source

Hollowing out MOFs: hierarchical micro- and mesoporous MOFs with tailorable porosity via selective acid etching [PDF]

open access: yes, 2017
We report a new strategy for the synthesis of robust hierarchical micro- and mesoporous MOFs from water stable MOFs via a selective acid etching process. The process is controlled by the size-selective diffusion of acid molecules through the MOF windows.
Kim, Yonghwi   +11 more
core   +1 more source

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