Results 121 to 130 of about 5,643,494 (299)

Kinetics‐Controlled Architecture of Binder‐Free Organic Electrodes for Enhanced Ion Transport

Advanced Functional Materials, EarlyView.
Pulse reverse electrodeposition controls nucleation and growth to create hierarchically porous Py‐derived oligomeric electrodes with enhanced ionic accessibility and reduced transport resistance. The resulting binder‐free architectures translate these transport advantages into practical sodium‐storage functionality.
Satendra Kumar, María del Carmen Giménez‐López   +1 more
wiley   +1 more source

Reconstructing Residual‐Solvent‐Involved Li+ Coordination in PVDF‐HFP Polymer Electrolytes for Stable Lithium Metal Batteries

Advanced Functional Materials, EarlyView.
2,2,2‐trifluoroethanamide‐mediated coordination regulation reconstructs the local Li+ environment in PVDF‐HFP polymer electrolytes by weakening residual DMF‐dominated coordination and promoting TFSI−‐involved anion‐rich solvation. This strategy facilitates Li+ migration and interfacial desolvation, promotes the formation of a thin inorganic‐rich SEI ...
Xiangsong Jiang, Qi Liu, Haohan Chen, Jianwei Lu, Yupeng Feng, Youwei Wang, Tianhao Zhao, Na Jiang, Wei Yang, Fei Li, Chunwei Dong, Shubiao Xia, Zhenzhen Shen, Weiwei Lei, Dan Liu, Jianping Long, Shimou Chen, Anjun Hu   +17 more
wiley   +1 more source

Spectroscopic studies to establish relationships between structure, bonding and reactivity in selected inorganic species. [PDF]

, 2005
This thesis explores the influence of molecular and electronic structure on the reactivity of some small inorganic complexes, beginning with a review of the nature and properties of metal-hydrogen and metal-carbon bonds of early transition metals and of ...
Pritchard, H.M.I.
core  

Inorganic Chemistry / Activation of Molecular Oxygen by a Molybdenum(IV) Imido Compound

, 2017
Activation of molecular dioxygen at a molybdenum(IV) imido compound led to the isolation and full characterization of a remarkably stable transition-metal imidoperoxido complex.
Zwettler, Niklas, Grover, Nidhi, Belaj, Ferdinand, Kirchner, Karl, Mösch-Zanetti, Nadia C.   +4 more
openaire   +2 more sources

Aza‐Diphosphazenanes: Inorganic Cyclohexane‐like Connectors with Stereochemically Tunable Exit Vectors for Molecular and Macromolecular Chemistry

Angewandte Chemie
AbstractMolecules that place functional groups at well‐defined angular and radial separations are valued as connectors in synthetic chemistry. Examples include rigid, polyvalent arenes and bicyclic compounds featuring strong C─C or C─H bonds.
Land, Michael A., Bedard, Joseph, George, Tanner, Masuda, Jason D., Chitnis, S. S.   +4 more
openaire   +2 more sources

Programmable Soft Actuator with Multi‐Responsiveness Based on Conductive MOF‐Liquid Crystal Polymer Composite

Advanced Functional Materials, EarlyView.
A sequential dual‐alignment strategy independently programs the orientation of conductive metal‐organic framework (c‐MOF) microrods and liquid crystals within a composite film. This approach creates an asymmetric bilayer structure that enables precise, multi‐responsive actuation.
Taegyun Hong, Geunho Kim, Changjae Lee, Sarang Lee, Jesse G. Park, Dong Ki Yoon   +5 more
wiley   +1 more source

2p3d Resonant X-ray emission spectroscopy of cobalt compounds [PDF]

, 2013
This manuscript demonstrates that 2p3d resonant X-ray emission spectroscopy (RXES) yields unique information on the chemically relevant valence electrons of transition metal atoms or ions.
Inorganic Chemistry and Catalysis, Sub Inorganic Chemistry and Catalysis, van Schooneveld, M.M.   +2 more
core   +1 more source

Nanoconfinement‐Induced Second‐Harmonic Circular Dichroism via Chirality–Ferroelectric Coupling

Advanced Functional Materials, EarlyView.
Nanoconfinement of a ferroelectric nematic liquid crystal within a chiral nanoporous sponge yields an enhanced second‐harmonic generation circular dichroism (|gSHG–CD| ≈ 1.1). Polarization‐resolved analysis suggests an additional magnetic‐dipole‐associated nonlinear contribution under nanoconfinement, highlighting chirality–ferroelectric coupling as a ...
Jae‐Jin Lee, Hiroya Nishikawa, Tae‐Woong Moon, Dong‐Ha Kim, Fumito Araoka, Suk‐Won Choi   +5 more
wiley   +1 more source

Symmetry Breaking of Molecules Triggered by Chiral Inorganic Nanostructures Without Organic Components

Advanced Science
Chirality transfer has garnered significant attention due to its potential to revolutionize asymmetric synthesis of enantiopure compounds and to provide fundamental insights into molecular symmetry breaking, which is widely believed to underlie the ...
Tao Yao, Xiao Chen, Yating Fang, Zhifeng Huang   +3 more
doaj   +1 more source

Preferential Interfacial Engineering of Hydrogels via Interdigitated Nanoparticle Assembly

Advanced Functional Materials, EarlyView.
Robust surface functionalization of hydrogel surfaces is performed via interdigitated metal nanoparticle assembly, inducing strong affinity with the hydrogel matrix. The partially exposed nanoparticle domains act as interfacial nanobridges that mediate both chemical and physical bonding with diverse materials, including small molecules, fluorous ...
Hyeonjin Kim, Hyeseoung Lim, Ji Min Lee, Heeyeon Kang, Yongkwon Song, Woojae Chang, So‐Jin Park, Jin Yoo, Atsushi Hozumi, Jinhan Cho, Jongkuk Ko, Sanghyuk Wooh   +11 more
wiley   +1 more source