Results 101 to 110 of about 21,113 (164)

Interaction of molecular Rydberg states with metal surfaces

open access: yes, 2016
The interaction between high-n Rydberg states of molecular hydrogen and metal surfaces has been investigated for the first time. Rydberg states of hydrogen possessing either 0 or 2 units of rotational angular momentum, defined by the quantum number N+ , and principal quantum numbers in the range n= 17 22 (for the N+= 2 states) and n=41-45 (for the N+=
Lloyd, G, Lloyd, Geoffrey Robert
openaire   +1 more source

SELECTIVE POPULATION OF MOLECULAR CORE NONPENETRATING RYDBERG STATES

open access: yesProceedings of the 69th International Symposium on Molecular Spectroscopy, 2014
David Grimes   +4 more
openaire   +1 more source

Molecular Rydberg states. Low-energy Rydberg states of azulene

The Journal of Physical Chemistry, 1983
Electronic spectra of azulenes are discussed. The low-energy Rydberg states are emphasized. The 3d-Rydberg states lie at 45,000 to 50,000 cm/sup -1/. They are partially quenched by chemical substituents and totally quenched in condensed media. The 3p-Rydberg states lie at approx. 40,000 cm/sup -1/ in azulene and are largely quenched in all derivatives.
J. W. Lewis   +3 more
openaire   +1 more source

Molecular Rydberg states. VII. Water

The Journal of Chemical Physics, 1977
The optical absorption spectra of H2O and D2O are reported at various pressures for 2000?λ?950 Å. The 1670 Å band is vibrationally structured (ν2 bend) and the excited 1B1 state contains a considerable intravalence 4a1 component. The 1280 Å state 3sa1; 1A1 is linear and dominantly Rydberg.
H. -t. Wang, W. S. Felps, S. P. McGlynn
openaire   +1 more source

Autoionizing Rydberg States in Triplet Molecular Hydrogen

Physical Review Letters, 1985
We report the first observation of the autoinizing triplet $\mathrm{nd}$ series of ${\mathrm{H}}_{2}$ covering the region from $n=10$ to the series limit. The autoionizing states are produced by excitation of ${\mathrm{H}}_{2}$ $c^{3}\ensuremath{\Pi}_{\mathrm{u}}^{\ensuremath{-}}$ molecules in a fast (1 keV) beam with a frequency-doubled pulsed dye ...
, Kachru, , Helm
openaire   +2 more sources

Nonexponential autoionization decays in molecular Rydberg states

Physical Review A, 1989
Etude des desactivations d'autoionisation des etats de Rydberg nd 1 Λ g de Na 2 en presence d'un faible champ electrique. Dans certaines conditions, on observe des signaux dont la forme differe notablement du comportement usuel. Ces decroissances sont decrites par un modele simple qui rend compte des interactions avec des niveaux discrets et ...
, Bordas, , Labastie, , Brevet, , Broyer
openaire   +2 more sources

Method for calculating molecular Rydberg states

The Journal of Chemical Physics, 1974
The multiple-scattering X α method is used to construct a potential suitable for Rydberg states and to obtain its eigenvalues. The method is checked by performing atomic calculations for Z ≤ 36 and gives good values. Molecular calculations are carried out with HF or BF3, and good agreement is obtained with experiment. Extensions to larger molecules are
F. W. Averill   +2 more
openaire   +1 more source

Microwave transitions between molecular Rydberg states

Chemical Physics Letters, 1985
Abstract Microwave transitions are observed for the first time between molecular Rydberg states in an optical—optical—microwave triple-resonance experiment carried out on Rydberg states of the Na 2 molecule. A new Rydberg series of u symmetry is observed and its quantum defect is measured (μ = 0.14).
P. Goy   +4 more
openaire   +1 more source

Chaos in molecular Rydberg states

AIP Conference Proceedings, 1990
We discuss on the particular case of Rydberg states of a molecule the correspondence between classical chaos and quantum level distributions.
M. Lombardi   +3 more
openaire   +1 more source

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