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Multiphoton probing of molecular Rydberg states
Molecular Physics, 1986This feature article provides an overview of the additional insights that multiphoton excitation methods are providing to our understanding of the spectroscopy and the photophysics of some of the higher excited electronic states of gas phase molecular species.
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Rydberg-to-valence evolution in excited state molecular dynamics
International Reviews in Physical Chemistry, 2020We present an overview of experimental and theoretical investigations exploring the dynamical evolution of Rydberg-to-valence character in the electronically excited states of small polyatomic mole...
Martin J. Paterson, Dave Townsend
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Solvent effects on molecular rydberg states: the B 1Σu state of molecular hydrogen in helium
Chemical Physics Letters, 1983Abstract Supermolecule calculations at the SCF level are reported for the excited B 1Σu state of the complex H2(He)6 for regular and randomised environments of the hydrogen molecule. Whilst marked blue-shifts are observed in the simulated matrix environment, randomisation of the surrounding helium atoms causes the transition energy to fall to a value
E.M. Evleth, J.T. Gleghorn
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Polarization labelling spectroscopy of molecular Li2 rydberg states
Zeitschrift für Physik D Atoms, Molecules and Clusters, 1987A series ofnd δ1Δg Rydberg states of the Li2 molecule has been measured using the polarization labelling technique. The experimental term values and the quantum defects derived from them, are compared with theoretical values obtained from ab initio calculations. The different physical effects contributing to the quantum defects are discussed.
B. Hemmerling +3 more
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Rydberg states of Li2 and molecular constants of Li+2
Chemical Physics Letters, 1982Abstract A Rydberg series of excited electronic states of 7 Li 2 has been characterized by pulsed optical—optical double resonance spectroscopy. Molecular constants of these states have been extrapolated to give the ionization potential of 7 Li 2 and molecular constants of the X 2 Σ + g state of 7 Li + 2 .
Bernheim, R. A., Gold, L. P., Tipton, T.
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The electronic structure of molecular Rydberg states of diatomic molecules
Journal of Physics B: Atomic, Molecular and Optical Physics, 1991The authors present a theoretical study of the electronic structure of molecular Rydberg states of several second row diatomic molecules which involve binding between atomic 2s and 2p valence orbitals.
Lei Liu, Jia-Ming Li
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Stark Multiplets in Molecular Rydberg States
Physical Review Letters, 1986, Chevaleyre +3 more
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Chaotic autoionization of molecular Rydberg states
Physical Review Letters, 1994, Benvenuto, , Casati, , Shepelyansky
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The perturbation of molecular Rydberg states
Journal of Photochemistry, 1976L.R. Wilson, S. Lipsky
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