The inverted F‐type ZnWO4/In2S3 heterojunction enables efficient charge separation and retention of strong oxidative capability through interfacial electric field regulation, leading to non‐toxic degradation of contaminants for sustainable water treatment.
Yanxian Jin +9 more
wiley +1 more source
Epitaxial Growth of β‑Ga<sub>2</sub>O<sub>3</sub> Thin Films on α‑Al<sub>2</sub>O<sub>3</sub> Substrates via Two-Step Metal-Organic Chemical Vapor Deposition: Influence of Growth Temperature on Crystallinity and Interface Formation. [PDF]
Chen WC +7 more
europepmc +1 more source
A dynamic catalyst–H2O heterojunction (CWH) forms on ACG during OER, with periodic bubble evolution modulating band bending and interfacial charge transfer. Electron–radical coupling drives the generation of •OH/•O2− species, converting Ga2O3 into GaOOH, whereas surface CO32− from C doping stabilizes the interface, suppressing catalyst dissolution and ...
Ruijie Dai +6 more
wiley +1 more source
Phase Stability of Monoclinic KDP Single Crystalline Fibers Obtained in Room-Temperature Solution. [PDF]
Li C, Bao Q, Song J, Zhang C, Ren Y.
europepmc +1 more source
We report a modular spin crossover‐photoluminescence (SCO‐PL) system: heteroleptic, mononuclear Fe(II) coordination compounds bearing equatorial BODIPY fluorophores that exhibit synergistic PL response upon spin state switching. Exchanging apical nitrile co‐ligands tunes electronic and structural properties, giving precise control over the SCO and PL ...
Martin Huber +4 more
wiley +1 more source
(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius +5 more
wiley +1 more source
Structural, Electronic, and Optical Properties of Monoclinic Pharmaceutical Crystals: A DFT Study of Salicylic Acid, Acetylsalicylic Acid, Acetaminophen, and Ibuprofen. [PDF]
Ferreira LL +6 more
europepmc +1 more source
Sodium Tetraazidoaurate(III)—From Na[AuCl4]·2H2O to Na[Au(N3)4] and Beyond One Step at a Time
Novel sodium chlorido‐/azidoaurate(III) dihydrates Na[AuCl4–x(N3)x]·2H2O (x = 0, 1, 2, 3, 4) provide the first example of a complete series of gradual substitution on tetramer complex anions to be described. Controlled dehydration of Na[Au(N3)4]·2H2O leads to Na[Au(N3)4]·H2O and Na[Au(N3)4], the latter being a highly explosive material.
Mehmet Somer +10 more
wiley +1 more source
Structural Phase Transitions and Magnetic Characterization of Ba<sub>2</sub>GdNbO<sub>6</sub> for Low-Temperature Magnetocaloric Refrigeration. [PDF]
Berardi F +6 more
europepmc +1 more source
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado +4 more
wiley +1 more source

