Results 101 to 110 of about 623 (163)

Interfacial Mn‐Carbon Nitride Synergy Enables Selective Photocatalytic C─H Chlorination via Single‐Atom Catalysis

Angewandte Chemie International Edition, EarlyView.
A manganese single‐atom photocatalyst on functionalised carbon nitride enables selective visible‐light‐driven C(sp2)─H chlorination. DFT‐supported mechanistic studies indicate that photoinduced charge separation activates NCS, while isolated Mn sites stabilize Mn─Cl intermediates at the catalyst interface.
Jaro Vanderghinste, Prakash Kumar Sahoo, Xinbang Wu, Thanh Huyen Vuong, Anna Rokicińska, Susanna Monti, Giovanni Barcaro, Alina Skorynina, Aleksander Jaworski, Vivien Michaelis, Jabor Rabeah, Julia Bornhorst, Laura Simonelli, Piotr Kuśtrowski, Adam Slabon, Paul J. Dyson, Shoubhik Das   +16 more
wiley   +1 more source

A narrow bandgap Schottky heterojunction Fe2N/CeO2 microneedle triggering sonodynamic reactive oxygen species storm for drug‐resistance‐free skin fungal infection

BMEMat, EarlyView.
Inorganic sonosensitizers suffer from inefficient electron‐hole separation, rapid recombination, and wide bandgaps in anti‐fungal applications. We propose MN@Fe2N/CeO2 to directly eliminate fungi without drug resistance. Combining semiconductor CeO2's advantages with Fe2N's high work function and activity enables efficient Schottky heterojunctions ...
Li Wang, Jiayi Yang, Ning Tang, Youbin Zheng, Yichao Hou, Chutong Liu, Lihao Guo, Yingying Liao, Gandong Zhou, Weiwei Wu, Xin Du, Shuxiang Xu, Jie Yin, Miaomiao Yuan   +13 more
wiley   +1 more source

Carbon Dot Nano‐Spacers in Triazine Networks for Integrated Photothermal Seawater Desalination and H2O2 Production

Carbon Energy, EarlyView.
Cyanated carbon dots (CN‐CDs) are synthesized by the hydrothermal method with carboxymethyl cellulose and cyanobenzoic acid, and CD‐CTN is obtained in situ via cyclotrimerization of CN‐CDs. CD‐CTN possesses excellent photothermal catalytic H2O2 production in seawater, and desalted H2O2 could be obtained, which demonstrates the practical application for
Xiaoxia Chen, Wenjie Tian, Huayang Zhang, Jingkai Lin, Anithadevi Sekar, Min Ge, Ruijia Wang, Hongda Guo, Shouxin Liu, Shujun Li, Jian Li, Tony D. James, Sai Kishore Ravi, Zhijun Chen   +13 more
wiley   +1 more source

Superior CO2 Conversion Performance by Er‐Doped BiOCl Nanosheets Through Synergistic Photocatalytic Memory Effect and Er‐Doping

Carbon Energy, EarlyView.
Er‐doping and the photocatalytic memory effect through visible‐light irradiation synergistically reconstruct internal electronic states of ultrathin Er‐doped BiOCl nanosheets and generate stable oxygen vacancies. Light absorption, charge carrier separation, and CO2 adsorption capability are subsequently enhanced, leading to a significant increase in ...
Lizhen Lu, Xinghua Zhu, Yuan Liang, Jinghui Wang, Haoyu Zhang, Jinbo Xue, Qianqian Shen, Jian Ku Shang, Qi Li   +8 more
wiley   +1 more source

1D/3D Heterojunction for High‐Efficiency Hole‐Transport Layer‐Free Carbon‐Based Wide‐Bandgap Perovskite Solar Cells

Carbon Energy, EarlyView.
By modifying wide‐bandgap high‐Cs perovskite surfaces with quaternary ammonium salts of varying alkyl‐chain lengths, tetrapropylammonium bromide (TPABr) is shown to successfully construct a 1D/3D heterojunction. This structure effectively passivates interface defects and optimizes energy level alignment, achieving a champion efficiency of 20.14% with ...
Lingcong Li, Zhujie Wu, Wei Xiong, Bin Liu, Yinlong Lai, Weizi Cai, Huashang Rao, Jianmin Luo, Xinhua Zhong, Zhenxiao Pan   +9 more
wiley   +1 more source

Dynamic‐FLPs Enabled by Orbital Hybridization Tuning: Boosting 100% CO Selectivity for Dilute CO2‐to‐CO Conversion

Carbon Energy, EarlyView.
This study, for the first time, constructs photostructured dynamic frustrated Lewis pairs (DFLPs) via a p‐p orbital hybridization regulation strategy, achieving the 100% reduction of low‐concentration CO₂ to CO and breaking the stability‐activity trade‐off.
Xiao‐hong Wang, Wen‐qing Gao, Jin‐li Liu, Yi‐lei Li, Hui‐ying Mu, Ying Liu, Fa‐tang Li   +6 more
wiley   +1 more source

Coupled Photocatalytic Hydrogen Production With Selective Biomass Valorization via Active Sites Construction and Electron Transport Channels Engineering

Carbon Energy, EarlyView.
A ternary CdS/1T‐WS2/CNTs heterojunction is in‐situ constructed via hydrothermal method, which is used for photocatalytic biomass reforming (biomass‐derived alcohols, lignin). It exhibits outstanding performance: H2 production rate of 26.17 mmol/g/h for benzyl alcohol (BA), benzaldehyde (BD) generation rate of 8.29 mmol/g/h, 90.06% BD selectivity, 100%
Ermiao Liang, Yi Li, Xue Liu, Ke Cheng, Baoqi Li, Mingcong Xu, Sha Luo, Chunhui Ma, Zhijun Chen, Zupeng Chen, Shouxin Liu, Wei Li   +11 more
wiley   +1 more source

Fe Atoms Accelerator Coupled With Oxygen Vacancies Channel Synergistically Boost OER Performance of Fe‐CoMoO4‐Ov Nanosheets

Carbon Energy, EarlyView.
Fe‐CoMoO4‐Ov/NF demonstrates significantly improved OER catalytic performance compared to CoMoO4. Specifically, the introduced Fe atoms act as a promoter for surface reconstruction, significantly reducing the energy required for surface reconstruction to generate FeCoOOH. The oxygen vacancies serve as electron channels between the core Fe‐CoMoO4‐Ov and
Chaojie Lyu, Jiarun Cheng, Yanhui Yu, Xinlong Tian, Yiming Liu   +4 more
wiley   +1 more source

Fe–Mn Heterojunction Modulated Electronic Environment for Enhanced CO2 Capture and In Situ Conversion

Carbon Energy, EarlyView.
Fe–Mn heterojunctions in CaO‐based dual‐functional materials create a built‐in electric field that drives electron transfer. This process generates oxygen vacancies and facilitates CO2 activation, achieving superior conversion. Waste‐derived Fe/Ca oxides enable low‐cost, thermally stable materials, offering a strategy for sustainable carbon capture and
Han Zhang, Ziyan Yang, Xiaohang Huang, Junxian Han, Yujing Zhang, Yuqi Zhang, Fumei Wang, Lina Liu, Zhikun Zhang   +8 more
wiley   +1 more source

Engineering Halide Perovskites With Chalcogen‐Based Compounds: Insights Into Stability, Interfaces, and Device Integration

Carbon Energy, EarlyView.
Chalcogen‐based compounds are explored as versatile tools to enhance the stability and performance of halide perovskites. Their roles in defect passivation, ion migration suppression, and interface engineering are analyzed, along with impacts on device efficiency.
Atanu Jana, Deblina Das, Sourav Mal, Tarak Nath Mandal, Sangeun Cho   +4 more
wiley   +1 more source