Results 81 to 90 of about 45,497 (307)

(2‐Phosphinophenyl)aluminum Dichloride Complexes as Intramolecular Al/P Frustrated Lewis Pairs for Ketone, Ester, and Imine Activation

open access: yesChemistry – A European Journal, EarlyView.
Three 2‐phosphinophenylaluminum dichloride complexes were synthesized and characterized as novel intramolecular FLPs. These FLP systems exhibit high Lewis acidity and effectively activate challenging substrates including aliphatic ketones, imines, and esters. DFT analysis revealed that strain release and Al–P dynamics govern their reactivity. Abstract (
Yoshihiro Nishimoto   +2 more
wiley   +1 more source

Porphyrin‐Geländer–Helical Conjugated Banister Type Porphyrin Dyads

open access: yesChemistry – A European Journal, EarlyView.
Porphyrin arrays go chiral–A porphyrin Geländer macrocycle represents the intriguing prototype architecture of helically chiral butadiyne‐linked porphyrin arrays. This study combines synthetic, spectroscopic, and computational methods to shed light on its structure, chiroptical properties, and tunability, highlighting its promise for advancing ...
Joël F. Keller   +2 more
wiley   +1 more source

The Impact of Roaming Radicals on the Combustion Properties of Transportation Fuels

open access: yes, 2017
A systematic investigation on the effects of roaming radical reactions on global combustion properties for transportation fuels is presented. New software was developed that can automatically discover all the possible roaming pathways within a given ...
Goldsmith, C. Franklin, West, Richard H.
core   +1 more source

Hydroprocessing of synthetic kerosene over a non‐sulphided Ni/Al2O3 catalyst: Impact of alcohols and ketones on alkene conversion

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Synthetic jet fuel containing non‐petroleum‐derived kerosene can be produced from synthetic kerosene obtained through processes that include a hydroprocessing step. The potential use of non‐sulphided (reduced) nickel supported on alumina (Ni/Al2O3) was evaluated as an alternative to sulphided catalysts to saturate alkenes in sulphur‐free ...
Garima Chauhan   +3 more
wiley   +1 more source

Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)]

open access: yesActa Crystallographica Section E, 2009
The title compound, [Cd(C8H8O5)(C3H4N2)2]n, was synthesized by the reaction of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The CdII atom is seven-coordinated in a distorted pentagonal-bipyramidal configuration by
Na Wang, Yan-Jun Wang, Qiu-Yue Lin
doaj   +1 more source

Durene conversion in a methanol‐to‐jet process: Exploring conversion at 150–350°C over different acid catalysts

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Acid catalyzed conversion of durene by isomerization, disproportionation, and transalkylation is of interest to the development of a methanol‐to‐jet process to reduce the amount of durene in the kerosene. It was of interest to determine whether durene conversion could be performed at a temperature lower than 350°C.
Aida G. Velasco Ortiz   +2 more
wiley   +1 more source

Performance characteristics of a new structured packing [PDF]

open access: yes, 2010
A new structured packing using carbon fibres, called Sepcarb® 4D, is presented. This packing has several attractive properties, such as high voidage (ε=94%) and high effective area (a=420 m2 m−3).
Abbé, François   +6 more
core   +2 more sources

Synthesis, characterization, and performance of x_MoO3/Z‐22 and x_MoO3/MMP catalysts for biodiesel production

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Methyl transesterification of soybean oil using heterogeneous catalysts for biodiesel production. Abstract The growing global demand for renewable fuels has driven the search for efficient catalysts in biodiesel production. This study presents the synthesis and characterization of x_MoO3/Z‐22 and x_MoO3/MMP heterogeneous catalysts, and evaluates the ...
André Miranda da Silva   +4 more
wiley   +1 more source

Supercritical water deasphalting and desulphurization of heavy fuel oil with comprehensive molecular‐level analysis and techno‐economic analysis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Supercritical water deasphalting. Abstract The removal of sulphur from heavy fuel oil (HFO) is essential to address environmental concerns and comply with the stringent regulations imposed by the International Maritime Organization (IMO) in 2020. Previously, the acceptable limit for sulphur was 3.5 wt.%, but it was recently changed to 0.5 wt.%.
Biswajit Saha   +6 more
wiley   +1 more source

Application of the Fernandez-Terrazo et al. one-step chemistry model for partially premixed combustion to n-heptane

open access: yes, 2006
A set of model parameters has been derived for the use of the model with n-heptane following the procedure set out by Fernandez et ...
Richardson, E.S., Schroll, P.
core  

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