A self-stiffness finishing for cotton fabric with N-methylmorpholine-N-oxide
Cellulose, 2015In this study, the surface layer of cotton fabric was swelled with N-methylmorpholine-N-oxide with 18 % water content, washed and dried to improve its stiffness property. Finally, the finished fabric had no auxiliaries and self-stiffened. The results showed that the bending rigidity increased from 0.75 × 105 to 1.57 × 105 mN cm, the acute elastic ...
Fang Xu +4 more
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Homogeneous alkalization of cellulose in N-methylmorpholine-N-oxide/water solution
Cellulose, 2017Alkali cellulose is an important intermediate in the production of cellulose derivatives. N-methylmorpholine-N-oxide (NMMO)/H2O was used as a homogeneous reaction medium for the cellulose alkalization process to intensify the alkalization degree and improve the substitution uniformity.
Yong Zhang, Shengwei Tang, Tao Zhang
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Mechanism of the interaction of dimethyl sulfoxide with N-methylmorpholine-N-oxide Monohydrate
Russian Journal of Physical Chemistry, 2006The interaction of dimethyl sulfoxide with N-methylmorpholine-N-oxide (NMMO) monohydrate was studied by the NMR relaxation method. The mobility of DMSO molecules in the presence of NMMO monohydrate decreases due to the formation of a hydrogen bond between the water molecule of the monohydrate and a DMSO molecule.
E. S. Sashina, N. P. Novoselov
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Aqueous N-methylmorpholine N-oxide as a new medium for alkylation of pyrazoles
Chemistry of Heterocyclic Compounds, 2018It is shown that alkylation of pyrazoles with (E)/(Z)-1,3-dichlorobut-2-enes can be carried out in an alkaline aqueous medium in the presence of N-methylmorpholine N-oxide. In some cases, this technique may substitute phase-transfer catalysis. Conformational analysis of the reaction products showed that a mixture of (E)/(Z) isomers is formed in a ratio
Ani H. Hasratyan +6 more
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Oxidation of Activated Halides to Aldehydes and Ketones by N-Methylmorpholine-N-oxide
Synthetic Communications, 1992Abstract N-methylmorpholine-N-oxide (NMO) in acetonitrile solution will oxidise activated primary halides to aldehydes and secondary halides to ketones in good yields at room temperature.
William P. Griffith +4 more
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Spectral features of the N-methylmorpholine-N-oxide-water-cellulose system
Polymer Science U.S.S.R., 1986Abstract The spectral featuresof N-methylmorpholine-N-oxide (MMO) — a solvent for cellulose — have been studied. Temperature studies show that the IR-spectroscopic features of the phase state of the hydrated and anyydride forms of MMO disappear in the melt state.
T.A. Belousova +4 more
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Solutions of mixtures of cellulose and synthetic polymers in N-methylmorpholine-N-oxide
Polymer Science Series A, 2009Phase state and morphological features of solutions of cellulose blends with rigid-chain thermotropic LC copolyesters and isotropic poly(m-phenyleneisophthalamide) in the highly polar donor solvent N-methylmorpholine-N-oxide are studied by DSC and polarization microscopy.
L. K. Golova +5 more
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Relaxation phenomena in water - n-methylmorpholin n-oxide binary mixtures
Journal of Molecular Liquids, 1988Abstract Binary mixtures composed of water and N-methylmorpholin N-oxide (NMMNO) were studied in the concentration range 0.19 m to 26.5 m with shear and longitudinal waves. The dependence on temperature and molality of 1)the ultrasonic spectrum, 2)the real part of the complex mechanical impedance and 3)the ultrasonic velocity indicates equilibrium ...
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Biogas Production from N-Methylmorpholine-N-oxide (NMMO) Pretreated Forest Residues
Applied Biochemistry and Biotechnology, 2014Lignocellulosic biomass represents a great potential for biogas production. However, a suitable pretreatment is needed to improve their digestibility. This study investigates the effects of an organic solvent, N-Methylmorpholine-N-oxide (NMMO) at temperatures of 120 and 90 °C, NMMO concentrations of 75 and 85% and treatment times of 3 and 15 h on the ...
Solmaz, Aslanzadeh +3 more
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Vapor pressure over the system cellulose-N-methylmorpholine-N-oxide-water
Fibre Chemistry, 1987The vapor pressure over solid cellulose-N-methylmorpholine-N-oxide-water systems and over liquid solutions is higher than that over the MMO·H2O solvent.
M. M. Iovleva, A. N. Sokira
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