Results 131 to 140 of about 30,361 (249)

Simultaneous Electronic and Crystallographic Modulation of Cs3Bi2Br9 by Single‐Element Sn Substitution for Enhanced CO2 Photoreduction

open access: yesAdvanced Energy Materials, EarlyView.
Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor   +7 more
wiley   +1 more source

Electron Bridge Enhanced Charge Polarization Enables Efficient and Ultra‐Long Stable Urea Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An electron bridge strategy is developed to regulate charge polarization in Pd1 and Ni1 dual single‐atom sites, promoting CO2 reduction, nitrate reduction, and C–N coupling simultaneously. The resulting catalyst achieves efficient urea electrosynthesis with high activity and record durability over 1700 h.
Fan Wu   +11 more
wiley   +2 more sources

Multifunctional Matrix‐Activated Electrodes Enabling Efficient Proton Transport and Durable Low‐Pt Operation for High‐Temperature Proton Exchange Membrane Fuel Cells

open access: yesAdvanced Energy Materials, EarlyView.
This work introduces a CeHP‐enabled multifunctional matrix‐activated electrode (MME) for high‐temperature PEM fuel cells, forming an electrochemically and mechanically functional matrix within the catalyst layer. The design increases peak power density by 38% and reduces voltage decay by 62% at 240 °C, while using only 40% of the Pt loading of a ...
Gyeongseok Gwak   +12 more
wiley   +1 more source

Ultrathin Membrane With Ion‐Specific Gating Enables Interfacial Decoupling of Conductivity–Selectivity for Aqueous Flow Batteries

open access: yesAngewandte Chemie, EarlyView.
An interfacial ion‐specific gating strategy shifts membrane design from ion diffusion within ion‐exchange channels to ion partitioning at the membrane–electrolyte interface, thereby decoupling selectivity from conductivity. The strategy underscores the pivotal yet underexplored role of the membrane–electrolyte interface, providing a broadly applicable ...
Di Mu   +6 more
wiley   +2 more sources

Surface‐Engineered Ti3C2Tx MXene/Cu2O Photocathodes for Highly Selective Photoelectrocatalytic CO2 Reduction to Ethanol

open access: yesAdvanced Energy Materials, EarlyView.
Surface‐engineering Ti3C2Tx MXenes with an in situ‐grown TiO2 layer on the surface in combination with visible‐light‐absorbing Cu2O significantly enhances charge separation and carrier extraction while improving Cu2O resistance to photocorrosion. The resulting Cu2O/TiO2‐MXene photocathodes enable highly selective, solar‐driven ethanol production ...
Luis A. M. Carrascosa   +4 more
wiley   +1 more source

Electro‐Organic Synthesis at a Stable Oil/Water/Solid Three‐Phase Interface Reactor

open access: yesAngewandte Chemie, EarlyView.
A porous membrane electrode (PME) reactor is developed to promote oil/water/solid three‐phase interfacial contact for electro‐organic synthesis. By promoting the formation of an oil/water interfacial region within or near an amphiphilic catalytic layer, the reactor enables efficient conversion of water‐insoluble organic reactants in aqueous ...
Deyin Chen   +7 more
wiley   +2 more sources

Preparation and voltammetric characterization of electrodes coated with Langmuir-Schaefer ultrathin films of Nafion®

open access: yesJournal of the Brazilian Chemical Society, 2003
Ultrathin films of Nafion® perfluorinated polymer were deposited on indium-tin oxide electrodes (ITO) by using Langmuir-Schaefer (LS) technique, after optimization of the subphase composition conditions.
Bertoncello Paolo, Ugo Paolo
doaj  

Hybrid Ionomer‐Free Porous Transport Electrodes With Catalyst Coated Membranes for Enhanced Water Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
We demonstrate how improved electrochemical performance during water electrolysis is achieved when a porous transport electrode (PTE) is coupled with a traditional catalyst coated membrane (CCM). Using operando neutron radiography, a more homogenous water distribution near the catalyst layer‐membrane interface is revealed in PTE‐based designs due to ...
Tess Seip   +8 more
wiley   +1 more source

Boosting Charge Storage in Ferri/Ferrocyanide‐Based Alkaline Redox Flow Batteries

open access: yesAngewandte Chemie, EarlyView.
By modifying the solvation environment, cation engineering through Li+ substitution of traditional K+ or Na+ boosts the alkaline solubility of the ferri/ferrocyanide catholyte redox couple, providing a viable pathway to overcome the long‐standing challenge of energy density limitations for aqueous redox flow batteries (RBFs).
Mahla Sarfaraz Khabbaz   +6 more
wiley   +2 more sources

Internal Electric Field‐Guided, Low‐Adsorption Ferroelectric Anode Protective Layers for Sustainable Suppression of Polysulfide Side Reactions in Lithium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A positively polarized ferroelectric β‐pvdf layer incorporating fluorinated boron nitride nanosheets (PPFBN) establishes a strong internal field that promotes Li+ transport toward the anode while suppressing the migration of polysulfide anions. In addition, its intrinsically low polysulfide affinity helps preserve protective‐layer functionality ...
Daehun Han   +6 more
wiley   +1 more source

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