Results 101 to 110 of about 3,630 (225)

The Dimensional Revolution of Phosphorus: From Allotropicity to Battery System Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Phosphorus‐based materials are promising high‐capacity anodes classified by dimension (0D–3D) to systematically explore their properties and composite strategies. When combined with materials such as carbon to form heterostructures, the electrical conductivity and stability are effectively enhanced.
Shuhan Zhang   +8 more
wiley   +1 more source

Implantable electrochemical sensors for continuous blood monitoring

open access: yesFlexMat, EarlyView.
Implantable electrochemical sensors enable direct, in situ, and continuous blood monitoring, shifting diagnosis from population‐based averages to dynamic, individualized analysis. This review systematically examines the influence of the unique blood properties on sensor design.
Kuangyi Zou   +3 more
wiley   +1 more source

Extension and Limits of Cryoscopy for Nanoconfined Solutions

open access: yesThe Journal of Physical Chemistry Letters, 2020
This work investigates the phase behavior of aqueous solutions of glycerol confined in MCM-41 and SBA-15 nanoporous matrixes by calorimetry. Limitations due to overfilling and eutectic freezing are prevented by the absence of an external liquid reservoir and by the glass-forming property of glycerol.
Malfait, Benjamin   +3 more
openaire   +5 more sources

Nanoconfinement-Induced β‑Phase Formation Inside Poly(vinylidene fluoride)-Based Block Copolymers [PDF]

open access: yes, 2018
The electroactive properties of poly­(vinylidene fluoride) (PVDF) are a direct consequence of its crystalline phases. Although poorly understood, nanostructuring PVDF in confined geometries can drastically change its crystallization behavior.
Niels L. Meereboer (5473844)   +4 more
core   +1 more source

Hydrogen-bond dynamics and proton transfer in nanoconfinement [PDF]

open access: yes, 2015
Proton transfer is of fundamental importance to both biology and chemistry. Much is known about proton transfer in large water volumes but often proton transfer reactions take place in very small nanometer sized volumes for example between lipid layers ...
van der Loop, T.H.
core   +2 more sources

Conjugated Polymers Engineered for Flexible/Stretchable Electronics

open access: yesJournal of Polymer Science, EarlyView.
This review highlights glass transition temperature (Tg) as the central parameter linking molecular structure to device performance in conjugated polymers. By tuning backbone rigidity, side‐chain architecture, and dynamic bonding, Tg governs the balance between π–π stacking–enabled charge transport and mechanical compliance.
Yunchong Yang   +5 more
wiley   +1 more source

Gelation of Poly(Vinylidene Fluoride) Solutions in Native and Organically Modified Silica Nanopores

open access: yesMolecules, 2018
The purpose of this study is to highlight the surface and size effects of the nanopores on the thermodynamics and kinetics of gelation. The effects have been probed by applying differential scanning calorimetry to poly(vinylidene fluoride) solutions in ...
Alejandra Espinosa-Dzib   +1 more
doaj   +1 more source

Reactivity of Oxidized Porous Silicon with Calcium Ion in Aqueous Media: Stability, pH Behavior, and Host‐Guest Strategies

open access: yesSmall, EarlyView.
Oxidized porous silicon, composed of an elemental silicon porous skeleton coated with a silica shell, reacts with aqueous Ca2+ to generate a mixed silica–calcium silicate matrix that is remarkably efficient at trapping small molecules. With an emphasis on the engineering of controlled‐release drug delivery systems, this study identifies the factors ...
Ruhan Fan   +2 more
wiley   +1 more source

Restructuring polymers via nanoconfinement and subsequent release

open access: yesBeilstein Journal of Organic Chemistry, 2012
During the past several years my students and I have been utilizing certain small-molecule hosts to create nanostructured polymers. This is accomplished by first forming noncovalently bonded inclusion complexes (ICs) between these small-molecule hosts ...
Alan E. Tonelli
doaj   +1 more source

Enhanced Biocatalysis in Nanofluidic Membrane Reactors With Goldilocks Nanopores for Enzymes

open access: yesSmall, EarlyView.
We show that enzyme confinement within the three‐dimensionally interconnected nanochannels of a polyurea molecular network membrane, featuring pore‐size tunability to match the enzyme size, enables a highly active nanofluidic reactor platform. Stable continuous‐flow operation for >200 h and a 30 000‐fold increase in specific space‐time yield over ...
Wangsuk Oh, Ji‐Woong Park
wiley   +1 more source

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