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Detailed Chemical Kinetic Models for Nanothermites Combustion
Propellants, Explosives, Pyrotechnics, 2018AbstractThe development of nanothermites and the understanding of their behaviors need several improvements in many domains including thermochemistry and chemical kinetics. In this paper a brief state of the art is presented in these fields and possible approaches are presented.
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Melt dispersion mechanism for fast reaction of nanothermites
Applied Physics Letters, 2006An unexpected mechanism for fast oxidation of Al nanoparticles covered by a thin oxide shell (OS) is proposed. The volume change due to melting of Al induces pressures of 0.1–4GPa and causes spallation of the OS. A subsequent unloading wave creates high tensile pressures resulting in dispersion of liquid Al clusters, oxidation of which is not limited ...
Valery I. Levitas +3 more
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Reduced-Sensitivity Nanothermites Containing Manganese Oxide Filled Carbon Nanofibers
The Journal of Physical Chemistry C, 2010Nanothermites are versatile pyrotechnic systems composed of a metal oxide and a reducing metal powder, such as aluminum. The high mechanical sensitivity of some of these mixtures (e.g., MnO2/Al) makes their handling hazardous. Enclosing the metal oxide inside carbon nanofibers—thus separating oxidizer and reducing agent—is a new way to lower the ...
Benny Siegert +4 more
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Phosphorus-based nanothermites: A new generation of energetic materials
Journal of Physics and Chemistry of Solids, 2010Abstract Thermites are energetic materials that are classically made of a transition metal oxide mixed with a reducing metal. Contrary to explosives, thermites do not detonate because their combustion is relatively slow and their reaction by-products are often solid or liquid.
Marc Comet +5 more
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Electric-Spark Initiation of Nanothermites
Combustion, Explosion, and Shock Waves, 2023A. Yu. Dolgoborodov +7 more
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Nanothermite auf Sulfat‐Basis: ein weites Feld metastabiler Kompositmaterialien
Angewandte Chemie, 2015AbstractIn dieser Arbeit wurden Metallsulfate (Me=Ba, Bi, Ca, Cu, Mg, Mn, Na, Zn, Zr) als Oxidationsmittel in reaktiven Mischungen mit Al‐Nanopulvern umgesetzt. Die resultierenden neuen Arten dieser Nanothermite zeigen im Vergleich zu konventionellen Al/Metalloxid‐Mischungen (1.5–4.8 kJ g−1) besonders hohe Reaktionswärmen, (4–6 kJ g−1), verbunden mit ...
Marc Comet +5 more
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Reactive characterization of nanothermites
Journal of Thermal Analysis and Calorimetry, 2012Marc Comet +3 more
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IGNITION CHARACTERISTICS OF NANOTHERMITE SYSTEMS
International Journal of Energetic Materials and Chemical Propulsion, 2008Jan Puszynski +2 more
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Aluminum/lead tetroxide nanothermites for semiconductor bridge applications
Chemical Engineering Journal, 2023Chunpei Yu +11 more
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