Results 111 to 120 of about 171,016 (340)
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
Angewandte Chemie, EarlyView.In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources
2-Methylsulfanylbenzo[f]isoquinoline
Molbank, 2015 S-Methylation of a 4-(naphth-2-yl)-β-thiolactam gives an intermediate 4-(naphth-2-yl) substituted 1-azetine which undergoes a [2+2] ring-opening followed by electrocyclic ring closure of the resulting 2-azadiene to give a benzo[f]isoquinoline.
Faisal Jamshaid +2 more
doaj +1 more source
Advanced Electronic Materials, EarlyView.Combining high polymer orientation of n‐type copolymers by temperature rubbing and sequential doping with N‐DMBI results in a strong improvement of electrical conductivity and thermoelectric power factors reaching up to 9.8 ± 1.6 S cm−1 and 8 ± 3 µW m−1.K2, respectively.
Shubhradip Guchait +7 more
wiley +1 more source
Angewandte Chemie, EarlyView.This work reports, for the first time, aggregation‐ or crystallization‐induced emission in boron‐substituted carboranes, which was driven by photoinduced charge‐transfer from fluorophore attached via boron vertices. The emission properties can be tuned by varying the substituents, expanding design strategies for luminescent materials.
Balázs Szathmári +9 more
wiley +2 more sources
Advanced Electronic Materials, EarlyView.The use of air stable but thermally labile molecules provides an efficient strategy for the N‐type doping of organic semiconductors with relatively low electron affinities. Design criteria for efficient dopants should also take into account diffusion and phase segregation that cannot be decoupled from thermally activated doping.
Francesca Pallini +15 more
wiley +1 more source
Stabilization of the Benzene Radical Trianion in an Inverse‐Sandwich Yttrium Complex
Angewandte Chemie, EarlyView.A new type of benzene anion state is born: The unprecedented benzene radical trianion embedded in an inverse‐sandwich yttrium complex was synthesized by a one‐electron chemical reduction of its benzene dianion precursor using potassium graphite in the presence of [2.2.2]‐cryptand.
Weiqing Mao +5 more
wiley +2 more sources
Atmosphere, 2017 Exhaust gases from internal combustion engines are the main source of urban air pollution. Quantification of Polycyclic aromatic hydrocarbons (PAHs) in the exhaust gases is needed for emissions monitoring, enforcement, development, and testing of control
Nassiba Baimatova +2 more
doaj +1 more source
Oxidation of naphthenoaromatic and methyl-substituted aromatic compounds by naphthalene 1,2-dioxygenase [PDF]
, 1996 S.A. Selifonov +3 more
openalex +1 more source
Effect of Regiochemistry on Doping and Thermoelectric Properties of n‐Doped Fullerene Derivatives
Advanced Electronic Materials, EarlyView.Three fullerene derivatives doubly substituted with diethylene glycol chains (PDEG‐2) is presented. The different regiochemistry significantly affects the crystallinity and consequently the dielectric properties, electronic transport, and doping efficiency. By striking a balance between compatibility with the molecular dopant N‐DMBI and crystallinity a
Federico Ferrari +7 more
wiley +1 more source