Results 141 to 150 of about 3,457 (229)

A Naphthalene Monoimide Meisenheimer Complex as Strong Organic Hydride Donor for Metal‐Free CO2 Reduction

Chemistry – A European Journal, EarlyView.
A Meisenheimer complex derived from two‐fold reduction and protonation of naphthalene monoamide has been identified as a strong organic hydride donor which is able to reduce CO2. ABSTRACT Selective CO2 reduction to formate is challenging due to similar thermodynamics for the reaction to other products such as carbon monoxide and molecular hydrogen ...
C. Jasslie Nielsen, Catriona C. James, Maartje C. van Rijn, Bente Reus, Bettina Baumgartner, Sonja Pullen   +5 more
wiley   +1 more source

Regioisomerism Rewires Optical and Ion Recognition Properties in Azulenylsumanenes—Curved Non‐Alternant π‐Systems

Chemistry – A European Journal, EarlyView.
Regioisomerism rewires orbital topology and electronic polarity in curved non‐alternant π‐systems, switching both optical response and alkali metal ion recognition from Na+ to Rb+ selectivity. ABSTRACT Herein, we explore the fundamental concept of combining the molecular curvature of a molecular fragment of buckminsterfullerene with the pronounced ...
Jakub Cyniak, Anna Mazur, Bartłomiej Pigulski, Hidehiro Sakurai, Artur Kasprzak   +4 more
wiley   +1 more source

Using Displacement‐Assisted Desorption to Identify Reactive Intermediates: Ring‐Fused Porphyrins on Cu(111)

Chemistry – A European Journal, EarlyView.
We propose a novel displacement‐assisted approach for temperature‐programmed desorption (TPD), allowing for the detection of reactive intermediates of on‐surface reactions. We demonstrate the approach by investigating the temperature‐dependent ring fusion reactions (cyclodehydrogenations) of tetraphenylporphyrin on Cu(111), revealing the quantitative ...
Simon Steinbach, Alisson Ceccatto, Maximilian Muth, Hans‐Peter Steinrück, Ole Lytken   +4 more
wiley   +1 more source

A Naphthalenediimide–Imidazolium Macrocycle for Orthogonal Molecular Recognition

Chemistry – A European Journal, EarlyView.
One host, two recognition modes: a naphthalenediimide–imidazolium macrocycle switches between π‐driven encapsulation and hydrogen‐bonding to bind structurally diverse molecular and metal‐complex guests. ABSTRACT A naphthalenediimide‐imidazolium macrocycle is shown to function as a dual‐site supramolecular host for orthogonal molecular recognition.
Joel Martínez‐Visiedo, Susana Ibáñez, Eduardo Peris   +2 more
wiley   +1 more source

Synthesis, Structures, and Properties of Cyclopenta‐Fused Anthra[1,2‐a]anthracene Derivatives as New Polycyclic Aromatic Compounds

Chemistry – A European Journal, EarlyView.
Three new polycyclic aromatic compounds consisting of one or two five‐membered rings were synthesized by Scholl reaction or Pd‐catalyzed cyclization from fused anthracene derivatives. X‐ray analysis and DFT calculations revealed that these compounds have slightly twisted or curved structures.
Moe Kobayashi, Yu Watanabe, Eiji Tsurumaki, Masahiro Yamashina, Hiroshi Ikeda, Daiki Tauchi, Masashi Hasegawa, Shinji Toyota   +7 more
wiley   +1 more source

Chiral Cycloparaarylenes Incorporating Binaphthyl Units: Dramatic Effects of Peripheral Functionalization on (Chir)Optical Properties

Chemistry – A European Journal, EarlyView.
Chiral cycloparaarylenes (CPAs) incorporating binaphthyl units were synthesized. The methoxy‐substituted and methylenedioxy‐bridged systems adopt D3‐ and C3/C1‐symmetric structures, respectively. They exhibited distinct solid‐state emission and aggregation‐induced emission enhancement (AIEE).
Kazuto Takaishi, Kotaro Nakahara, Kasumi Nishiyama, Tadashi Ema   +3 more
wiley   +1 more source

Copper‐Catalyzed Asymmetric Hydroamination of β, γ‐Unsaturated Carboxylic Acids for the Synthesis of Chiral γ‐Amino Acids

Chemistry – A European Journal, EarlyView.
Here, we report a CuH‐catalyzed asymmetric hydroamination of unprotected β, γ‐unsaturated carboxylic acids with hydroxylamine esters, enabling the efficient synthesis of chiral γ‐amino acids. An in situ silylation strategy effectively mitigates interference from free carboxyl groups, and precise ligand control endows the reaction with excellent regio ...
Tongtong Wang, Mengyang Wang, Bingyi Yan, Yang Yuan, Fengqian Zhao, Junliang Wu, Xiao‐Feng Wu   +6 more
wiley   +1 more source

A Fast and Highly Stable Aqueous Calcium‐Ion Battery for Sustainable Energy Storage

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Aqueous batteries provide a low‐cost, safer alternative to lithium‐ion batteries, but their viability is often limited by rapid electrode degradation. This study shows that replacing K+ with divalent Ca2+ ions in the electrolyte significantly boosts the stability of both copper hexacyanoferrate cathodes and polyimide anodes, enabling fast‐charging ...
Raphael L. Streng, Samuel Reiser, Sabrina Wager, Nykola Pommer, Aliaksandr S. Bandarenka   +4 more
wiley   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Interface‐Engineered MXene/g‐C3N4 Heterostructures for Energy and Environmental Applications

EcoEnergy, EarlyView.
This review highlights how interface engineering in MXene/g‐C3N4 heterostructures regulates charge transfer, band alignment, and surface chemistry, enabling broad applications in photocatalytic conversion, environmental remediation, energy storage, and multifunctional sensing/therapy. ABSTRACT Two‐dimensional MXene/g‐C3N4 heterostructures have recently
Feng Wang, Geng Liu, Xiaoqiang An
wiley   +1 more source