Results 41 to 50 of about 20,183 (213)

Coordination Chemistry of Boron Subphthalocyanine With BINOL Derivatives: Unexpected Oxidation to Oxa[4]Helicene and Properties of the Resulting Axially Coordinated Complexes Containing Oxa[4]Helicene and/or BINOL Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Treatment of BINOL with a boron subphthalocyanine derivative resulted in the formation of a complex coordinated to an oxa[4]helicene derivative, which is generated via a ring‐closure reaction of BINOL. In contrast, treatment of the monomethyl ether of 1,1′‐bi‐2‐naphthol (BINOL) afforded the expected axially coordinated complex.
Shafikul Islam   +5 more
wiley   +1 more source

Separate hydrolysis and fermentation of softwood bark pretreated with 2-naphthol by steam explosion

open access: yesBiotechnology for Biofuels and Bioproducts
Background 2-Naphthol, a carbocation scavenger, is known to mitigate lignin condensation during the acidic processing of lignocellulosic biomass, which may benefit downstream processing of the resulting materials. Consequently, various raw materials have
Andreas Averheim   +4 more
doaj   +1 more source

Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions

open access: yesChemistry – A European Journal, EarlyView.
Several new chiral cyclic hypervalent iodine(III) reagents have been synthesized and characterized. Carbon‐based ligands were successfully installed onto the hypervalent iodine centers, giving thus access to novel chiral cyano‐, trifluoromethyl‐ or alkynyl‐bearing λ3‐iodanes.
Emmanuel Valzer   +4 more
wiley   +1 more source

Carbocation scavenger enhanced pretreatment of wood for enzymatic saccharification – Experimental study and review

open access: yesIndustrial Crops and Products
The suppression of lignin repolymerization by carbocation scavengers in lignocellulosic biomass pretreatment improves both the bioconversion of cellulose and the quality of the obtained lignin.
Butrint Nikqi   +4 more
doaj   +1 more source

Synthesis of Chiral‐at‐Sulfur(VI) Sulfonimidamide Brønsted Acids

open access: yesChemistry – A European Journal, EarlyView.
A simple, modular route to chiral‐at‐sulfur(VI) Brønsted acids is described, delivering S‐chiral sulfonimidamides, C2‐symmetric acids, and BINOL‐based hybrid systems through stereospecific reactions of sulfonimidoyl fluorides and chlorides. ABSTRACT Herein, we report an efficient and simple strategy to access diverse chiral‐at‐sulfur(VI) Brønsted acids.
Yu Han   +6 more
wiley   +1 more source

Association between single and mixed exposure to polycyclic aromatic hydrocarbons and biological aging

open access: yesFrontiers in Public Health
BackgroundAging is one of the most important public health issues. Previous studies on the factors affecting aging focused on genetics and lifestyle, but the association between polycyclic aromatic hydrocarbons (PAHs) and aging is still unclear ...
Zuqiang Fu   +4 more
doaj   +1 more source

5-Amino-1-naphthol [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2009
In the title compound, C(10)H(9)NO, the amino and the hydr-oxy groups act both as a single donor and a single acceptor in hydrogen bonding. In the crystal, mol-ecules are connected via chains of inter-molecular ⋯N-H⋯O-H⋯ inter-actions, forming a two-dimensional polymeric structure resembling the hydrogen-bonded mol-ecular assembly found in the crystal ...
Agnieszka Czapik   +2 more
openaire   +3 more sources

Synergistic Regulation of Hierarchical Anode Interphase and Cathode Electronic Structure by a Fe(III) Complex for High‐Performance Aqueous Zinc‐Manganese Battery

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The NGB additive can concurrently address anode and cathode issues during Zn‐Mn battery cycling by constructing a hierarchical interfacial layer on the anode surface to alleviate side reactions and modulate zinc deposition and by incorporating Fe3+ ions into the α‐MnO2 cathode to improve its structural stability and electrical conductivity.
Xiaoliang Zhang   +7 more
wiley   +1 more source

Natural Anthraquinone‐Like Compound Extracted from Green Husk of Walnut Improves Photocatalytic H2O2 Production Catalyzed by TiO2 Nanoparticles

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this work, a novel biomolecule/semiconductor hybrid catalyst was prepared by loading anthraquinone‐liked juglone onto anatase TiO2. This catalyst exhibited high photocatalytic activity for H2O2 production. Hydrogen peroxide (H2O2) is a vital oxidant with broad industrial applications, and its production via photocatalysis represents a highly ...
Zengyin He   +4 more
wiley   +1 more source

Salting of Naphthols

open access: yes, 1981
Department of Chemistry, University of Roorkee, Roorkee-247 672, U.P. Manuscript received 29 August 1980, revised 2 September 1981, accepted 14 September 1981 Salting of Naphthols.
RATNA GHOSH, BHARATI DAS
openaire   +2 more sources

Home - About - Disclaimer - Privacy