Results 161 to 170 of about 5,659,205 (204)

Interface‐Mediated Catalysis for Improved Hydrogen Storage in Reactive Hydride Composites

open access: yesAdvanced Materials, EarlyView.
Catalyst–hydride interfaces are engineered in Co@C‐ and Ni@C‐modified 2LiH + MgB2 reactive hydride composites to accelerate hydrogen uptake and release. Multiscale scattering, in‐situ synchrotron radiation powder x‐ray diffraction and density functional theory calculations reveal the structural and electronic origin of the catalytic enhancement ...
Yuanyuan Shang   +12 more
wiley   +1 more source

Phase‐Engineered MoS2 Quantum Monolayer Catalysts

open access: yesAdvanced Materials, EarlyView.
A new type of catalyst model—phase‐engineered MoS2 quantum‐monolayer catalyst (∼0.8 nm thick, < 6 nm in the lateral size; switchable freely among metallic 1T, semiconducting 2H, and a hybrid phase of metallic‐semiconducting 1T‐2H)—is reported. It can efficiently and stably drive photochemical H2, syngas and ammonia synthesis as a catalyst or co ...
Ruijie Yang   +12 more
wiley   +1 more source

Ionic Cocrystal Programming of Spatial Ionic Organization in Carbon Nitrides Enables Highly Efficient H2O2 Photosynthesis

open access: yesAdvanced Materials, EarlyView.
Ionic cocrystal‐programmed ionic organization establishes a general strategy for electrostatic programming in polymeric photocatalysts. ABSTRACT Controlling the spatial organization of ions in polymeric photocatalysts remains a fundamental challenge for optimizing charge transport and catalytic selectivity in solar‐driven hydrogen peroxide (H2O2 ...
Anna Lo Presti   +6 more
wiley   +1 more source

High‐Mobility Chalcogenophene‐Engineered Diketopyrrolopyrrole Mixed Ionic‐Electronic Conductors With Doping Tolerance for Low‐Power Organic Electrochemical Transistors

open access: yesAdvanced Materials, EarlyView.
Chalcogen substitution emerges as a powerful strategy for designing high‐performance OMIECs. In aliphatic–glycol side chain diketopyrrolopyrrole polymers, biselenophene incorporation promotes a planar, polarizable, and doping‐tolerant quinoidal framework, enabling PDPP‐4EG‐Se2 to combine high hole mobility, large µC*, enhanced operational stability ...
Shinbee Oh   +9 more
wiley   +1 more source

Helicity‐Defined Analog Conductance States in Chiral Perovskite Synapses

open access: yesAdvanced Materials, EarlyView.
Chiral perovskite synapses convert the handedness of circularly polarized light into persistent analog memory during electrical programming. An optimized n = 3 structure combines strong helicity selectivity with low read noise, enabling 72 distinct conductance levels.
Min Jong Lee   +16 more
wiley   +1 more source

Breaking Bottlenecks in Solid Electrolyte Discovery With Large Artificial Intelligence Models

open access: yesAdvanced Materials, EarlyView.
Large AI models are presented as a route to break key bottlenecks in solid electrolyte discovery by linking materials databases, machine‐learning interatomic potentials, large language models, and autonomous experiments. This perspective highlights how AI can accelerate the identification of solid electrolytes with fast ion transport, stable interfaces,
Eric Jianfeng Cheng   +24 more
wiley   +1 more source

Disentangling Polaron Formation Pathways in Y6 by Probing Noninteracting and Interacting Chromophores via Transient Absorption Spectroscopy

open access: yesAdvanced Materials, EarlyView.
The central role of both electronically interacting and noninteracting chromophores in the photogeneration of charges has been unambiguously identified by ultrafast pump‐probe spectroscopy in thin films of the prototypical non‐fullerene acceptor Y6. Onsager‐like autoionization from higher‐energy excitations on Y6 aggregates is found to control polaron ...
Daniel Kroh   +3 more
wiley   +1 more source

Over 95% Optical Reflectance From Structurally Modulated All‐Biopolymer Multilayers

open access: yesAdvanced Materials, EarlyView.
A new dense–porous design turns ordinary polysaccharides into highly reflective photonic multilayers. Alternating dense pectin and porous cellulose nanofiber layers create strong refractive‐index contrast without inorganic or synthetic polymers, enabling nearly perfect visible reflection, high near‐infrared reflection, broadband metallic‐like colors ...
Takaaki Kasuga   +9 more
wiley   +1 more source

Adaptive Supramolecular Interactions Govern Redox‐Active Molecules in Aqueous Redox Flow Batteries

open access: yesAdvanced Materials, EarlyView.
Adaptive supramolecular interactions overcome the solubility‐stability trade‐off in aqueous redox flow batteries. Hydrophobic anions disrupt intrinsic π–π stacking to enable high solubility, while redox‐state‐dependent spin pairing and cation coordination dynamically stabilize reactive intermediates during operation.
Vikram Singh   +12 more
wiley   +1 more source

Orthogonal Passivation of Polar Facets for Efficient InSb Quantum Dot SWIR Photodetectors

open access: yesAdvanced Materials, EarlyView.
An orthogonal passivation strategy is developed for indium antimonide (InSb) colloidal quantum dots (CQDs): a metal halide passivates Sb‐terminated surface sites, while thiol ligands passivate In‐terminated sites. This site‐specific passivation reduces trap density, prolonging carrier lifetime and increasing carrier mobility, and enables InSb CQD ...
Sile Hu   +7 more
wiley   +1 more source

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