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Mild Generation of Highly Nucleophilic N‐Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation

open access: yesAngewandte Chemie, EarlyView.
A less hindered and highly nucleophilic N‐heterocyclic carbene (NHC) boryl anion is generated at room temperature by reacting sp2–sp3 diboron reagent (NHC)BH2Bpin with KOtBu. This highly reactive anion demonstrates broad reactivity with various electrophiles, including those traditionally considered inert, enabling their efficient borylation.
Weixuan Sun, Peiqi Zhang, Hairong Lyu
wiley   +2 more sources

Figure of merit for piezoelectric MEMS speakers. [PDF]

open access: yesMicrosyst Nanoeng
Sun M   +8 more
europepmc   +1 more source

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