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Recent Developments in Sustainable Solubilization
We highlight several recent developments in sustainable solubilization. Particular attention is given to the use of bio‐based solvents derived from renewable resources, the strategic use of water as a solvent, and alternative, sustainable solubilizers such as hydrotropes.
Eva Müller, Werner Kunz
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A sustainable, ligand‐free Pd‐catalyzed borrowing hydrogen protocol in a biodegradable hydrophobic natural deep eutectic solvent (NADES) (thymol/DL‐menthol) enables the N‐alkylation of primary amines with benzylic alcohols under mild, aerobic conditions, allowing efficient reuse of both catalyst and solvent for seven consecutive cycles. The hydrophobic
Maryam Saeb +5 more
wiley +1 more source
Abstract We present novel observations of C‐band Synthetic Aperture Radar (SAR) coherence sensitivities and patterns for snow on first‐year sea ice (FYI) consistent with snow thermodynamics and wind redistribution. Wintertime SAR coherence and backscatter change observations of landfast FYI in Dease Strait, Nunavut, Canada are made using 12‐day repeat ...
John Yackel +8 more
wiley +1 more source
Toxicity of Natural Deep Eutectic Solvent Betaine:Glycerol in Rats [PDF]
Natural deep eutectic solvents (NaDES) are new natural solvents in green chemistry that in some cases have been shown to allow better extraction of plant bioactive molecules compared to conventional solvents and higher phenolic compound absorption in rodents. However, there is a serious lack of information regarding their in vivo safety. The purpose of
Benlebna, Melha +8 more
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Deep eutectic solvents—Teaching nature lessons that it knew already
2021When Brønsted and Lewis acids and bases are mixed strong hydrogen bonds develop and these deviate from ideal mixtures resulting in a significant depression of freezing point. Many of these mixtures are liquid at ambient temperatures. These so-called deep eutectic solvents have become an area of intense study since their discovery.
Abbott, Andrew, P., Häkkinen, Riina
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Natural Deep Eutectic Solvents – Solvents for the 21st Century
ACS Sustainable Chemistry & Engineering, 2014Green technology actively seeks new solvents to replace common organic solvents that present inherent toxicity and have high volatility, leading to evaporation of volatile organic compounds to the atmosphere. Over the past two decades, ionic liquids (ILs) have gained enormous attention from the scientific community, and the number of reported articles ...
Alexandre Paiva +5 more
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Natural deep eutectic solvent—A novel green solvent for protein stabilization
International Journal of Biological Macromolecules, 2023Natural deep eutectic solvents (NADESs) have been explored to provide a favorable environment for protein stabilization. In this context, NADESs were prepared with the molar ratio of trehalose to betaine ranging from 1:3 to 1:9 (NADES 1-3 to NADES 1-9).
Yu, Tian +3 more
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Biocatalyzed Vinyl Laurate Transesterification in Natural Deep Eutectic Solvents
Waste and Biomass Valorization, 2023Abstract: Purpose Natural deep eutectic solvents (NADES) represent a green alternative to conventional organic solvents as reaction medium, offering more benign properties. To efficiently design NADES for biocatalysis, a better understanding of their effect on these reactions is needed.
Attila Kovács +5 more
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