Results 181 to 190 of about 49,182 (344)

Prolonged Hospitalization Among Children Aged < 5 Years Admitted With Acute Gastroenteritis at Siaya County Referral Hospital, in Rural Western Kenya: 2010–2020

open access: yesHealth Science Reports, Volume 8, Issue 9, September 2025.
ABSTRACT Background Acute gastroenteritis (AGE) causes substantial morbidity and mortality in children < 5 years old accounting for 9 million hospitalizations. Prolonged hospitalization can cause dire consequences to the patient and healthcare system. However, data on factors associated with prolonged hospitalization for AGE in developing countries are
Alex.O. Awuor   +15 more
wiley   +1 more source

Redox‐ and NIR‐Active Iron(III) Triradicals as Catalysts for Radical Polymerization of Acrylamides and Methacrylates

open access: yesAngewandte Chemie, Volume 137, Issue 34, August 18, 2025.
A redox‐active low‐spin Fe(III)‐triradical complex was isolated in good yield and utilized as a catalyst for radical polymerization of acrylamides and methacrylates at ambient conditions. Abstract Two unprecedented redox‐active, low‐spin Fe(III)‐triradical complexes, [Fe(III)(SS‐NHC═S•−)3]·NHC═S (1·NHC═S; E═S) and [Fe(III)(SS‐NHC═Se•−)3] (2; E═Se) have
Sujit Das   +11 more
wiley   +2 more sources

Surface characterization of sodium silicate glasses after initial water interaction

open access: yesJournal of the American Ceramic Society, Volume 108, Issue 9, September 2025.
Abstract The corrosion behavior of sodium silicate glass in water may be understood by clarifying the fundamental processes of interface reactions. We investigated the reaction mechanism of the glass surfaces in contact with water for just an immediate dipping up to 1 h later, using x‐ray photoelectron spectroscopy.
Katsuaki Miyatani   +9 more
wiley   +1 more source

Reactivity of a Methylene‐Bridged 1,3‐Bis(germylene) in Dynamic Equilibrium with Its Dimer

open access: yesAngewandte Chemie, Volume 137, Issue 34, August 18, 2025.
We report the properties and reactivity of an unprecedented methylene‐bridged 1,3‐bis(germylene) derivative. In the solid state, the 1,3‐bis(germylene) derivative undergoes dimerization to afford a 1,2,4,5‐tetragermacyclohexa‐1,4‐diene (Ge4CHD) derivative.
Daichi Uchida   +5 more
wiley   +2 more sources

Side‐on‐Koordination in Molekularen Erdalkalimetall‐Hypofluoriten FM(η2‐OF) (M = Mg, Ca, Sr und Ba)

open access: yesAngewandte Chemie, Volume 137, Issue 35, August 25, 2025.
Side‐on koordinierte Erdalkalimetall‐Hypofluorite F′M(η2‐OF) (M = Mg, Ca, Sr und Ba) wurden durch die Reaktionen laserablatierten Metallatomen mit OF₂ in Argon‐Matrizen dargestellt. Diese neuartigen Spezies weisen einen Fluorido‐Ligand F′− sowie einen side‐on koordinierten η2‐OF− Liganden auf, wobei der M─F─O─F′ Diederwinkel von Calcium bis Barium ...
Xiya Xia, Robert Medel, Sebastian Riedel
wiley   +1 more source

On the Reaction of Pacman-Phosphanes with Lewis Acids. [PDF]

open access: yesChemistry
The reactivity of a Pacman phosphane (a macrocyclic, multidentate phosphane ligand) with Lewis acids such as BPh₃, B(C₆F₅)₃, and GaCl₃ were investigated, revealing distinct bonding motifs and coordination behaviors. While B(C₆F₅)₃ forms a stable di‐adduct, GaCl₃ induces an unusual structural rearrangement with the formation of a [Pacman‐GaCl₂]⁺[GaCl₄]⁻
Ohms L   +4 more
europepmc   +2 more sources

Side‐On Coordination in Molecular Alkaline Earth Metal Hypofluorites FM(η2‐OF) (M = Mg, Ca, Sr, and Ba)

open access: yesAngewandte Chemie International Edition, Volume 64, Issue 35, August 25, 2025.
Side‐on coordinated alkaline earth metal hypofluorites F′M(η2‐OF) (M = Mg, Ca, Sr, and Ba) were prepared through the reactions of laser‐ablated metal atoms with OF2 in argon matrices. The species feature a fluorido F′− and a side‐on coordinated η2‐OF− ligand with the M─F─O─F′ dihedral angle increasing from calcium to barium, which parallel the non ...
Xiya Xia, Robert Medel, Sebastian Riedel
wiley   +1 more source

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