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Isotropic Negative Thermal Expansion Metamaterials [PDF]
Negative thermal expansion materials are important and desirable in science and engineering applications. However, natural materials with isotropic negative thermal expansion are rare and usually unsatisfied in performance. Here, we propose a novel method to achieve negative thermal expansion via a metamaterial approach. The metamaterial is constructed
Lingling Wu, Ji Zhou
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Chemical Diversity for Tailoring Negative Thermal Expansion
Chemical Reviews, 2022Negative thermal expansion (NTE), referring to the lattice contraction upon heating, has been an attractive topic of solid-state chemistry and functional materials. The response of a lattice to the temperature field is deeply rooted in its structural features and is inseparable from the physical properties.
Kun Lin, Zhanning Liu, Lei Hu
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Negative Thermal Expansion in Nanosolids
Accounts of Chemical Research, 2019Nanosolids usually exhibit a variety of peculiar physical features due to the size effect. The unique surface electronic states and coordination structures of nanosolids make them particularly important as promising functional materials. After several decades of research effort on the preparation processes and formation mechanisms of nanomaterials, the
Qiang Li +4 more
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Negative thermal expansion materials
Physica B: Condensed Matter, 1997Abstract The recent discovery of negative thermal expansion over an unprecedented temperature range in ZrW 2 O 8 (which contracts continuously on warming from below 2 K to above 1000 K) has stimulated considerable interest in this unusual phenomenon.
John S O Evans, A W Sleight
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Negative thermal expansion in molecular materials
Chemical Communications, 2018Some mechanisms resulting in negative thermal expansion in molecular materials are summarized.
Zhanning Liu +5 more
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Negative thermal expansion: a review
Journal of Materials Science, 2009Most materials demonstrate an expansion upon heating, however a few are known to contract, i.e. exhibit a negative coefficient of thermal expansivity (NTE). This naturally occurring phenomenon has been shown to occur in a range of solids including complex metal oxides, polymers and zeolites, and opens the door to composites with a coefficient of ...
W. Miller +3 more
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Origin of the negative thermal expansion in and
Journal of Physics: Condensed Matter, 1996The negative thermal expansion recently observed over a wide range of temperatures in may be attributed to the existence of low-frequency phonon modes which can propagate with no distortions of the tetrahedra and octahedra, the so-called `rigid unit modes'.
Alexandra K A Pryde +5 more
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MRS Proceedings, 2002
ABSTRACTNegative thermal expansion behavior has been found in many oxides where oxygen or a cation has a coordination number of two. The MO2, AM2O7, A2M3O12, AMO5, and AO3 families, where A is an octahedral cation, M a tetrahedral cation, and the oxygen coordination is two, have been investigated for their thermal expansion properties. Negative thermal
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ABSTRACTNegative thermal expansion behavior has been found in many oxides where oxygen or a cation has a coordination number of two. The MO2, AM2O7, A2M3O12, AMO5, and AO3 families, where A is an octahedral cation, M a tetrahedral cation, and the oxygen coordination is two, have been investigated for their thermal expansion properties. Negative thermal
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Negative thermal expansion in Y2W3O12
International Journal of Inorganic Materials, 1999Abstract Neutron diffraction data were collected on polycrystalline Y2W3O12 at seven temperatures from 15 to 1373 K. All three cell edges of orthorhombic Y2W3O12 decrease with increasing temperature, giving an average linear thermal expansion coefficient of −7.0×10−6 K−1.
P.M. Forster, A.W. Sleight
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