Results 171 to 180 of about 53,388 (262)

Dual Activation of H2 and CO2 by a Pincer‐Type Ni–Zn Heterobimetallic Complex

Angewandte Chemie, EarlyView.
A bimetallic Ni−Zn complex performs sequential activations of H2 (1 equiv) and CO2 (2 equiv). This bimetallic cooperativity is attributed to the weak Lewis acidic nature of Zn(II), which promotes fluxional ligand binding. Namely, an X‐type ligand at Ni, where X is hydride or formate, toggles between two different binding modes: bridging Zn(μ‐X)Ni and ...
Krishnendu Dey, Matthias Borowski, Gregor Schnakenburg, Connie C. Lu   +3 more
wiley   +2 more sources

Monte Carlo simulation and unfolding of an extended Bonner sphere system for secondary neutron spectrometry in proton therapy facilities using conventional BSS experimental data. [PDF]

Front Oncol
Díaz-Comeche A, Oliver S, Juste B, Jardin D, Zakhary M, Mossahebi S, Mille MM, Lee C, Miró R, Verdú G, Morató S.   +10 more
europepmc   +1 more source

Unraveling A4GALT Mechanism and Its Modulation With Adamantyl‐Galactosylceramide Analogues: Advancing Fabry Disease Therapeutic Strategies

Angewandte Chemie, EarlyView.
A 310‐helix‐mediated conformational switch promotes a front‐face SNi‐like catalysis by human A4GALT. Mechanism‐guided design identifies AdaGalCer as a selective modulator of globotriaosylceramide (Gb3) biosynthesis, opening a clear route toward new Fabry disease therapeutics.
Nicky de Koster, Òscar Vidal‐Gironès, Rowan de Graaf, Ken Kok, Lindsey T. Lelieveld, Jackelien Hoogervorst, Maria J. Ferraz, José Pablo Rivas‐Fernández, Rob F. Lammers, Herman S. Overkleeft, Johannes M. F. G. Aerts, Rolf G. Boot, Carme Rovira, Marta Artola   +13 more
wiley   +2 more sources

A Porphyrinic Covalent Organic Polymer Nanoplatform for Carborane Delivery and Multifunctional Imaging-Guided Boron Neutron Capture Therapy of Breast Cancer. [PDF]

Int J Nanomedicine
Ren J, Wang T, Zuo C, Zhang R, Li L.
europepmc   +1 more source

Stochastic analysis of compact stars under composite polytropes. [PDF]

Sci Rep
Nouh MI, El-Essawy SH, Foda MM, Aboueisha MS.   +3 more
europepmc   +1 more source

<i>Vitess 3.8</i>: a modernized framework for Monte Carlo neutron tracing simulations. [PDF]

J Appl Crystallogr
Robledo JI, Violini N, Beule F, Voigt J, Zakalek P, Lieutenant K.   +5 more
europepmc   +1 more source

Structural and magnetic investigations of the Weyl semimetal family CeAlSi_1-xGe_x. [PDF]

Acta Crystallogr B Struct Sci Cryst Eng Mater
Mayoh DA, Sharma S, Chamberlain TW, Wood GDA, da-Silva I, Goddard PA, Lees MR, Balakrishnan G.   +7 more
europepmc   +1 more source

Accurate simulations of magnetic excitations in the neutron simulation package <i>McStas</i>. [PDF]

J Appl Crystallogr
Schack SB, Krighaar KML, Lenander EY, Lefmann K.   +3 more
europepmc   +1 more source

Taming a Blue Gas—Structure and Chemistry of Hexafluorothioacetone

Angewandte Chemie International Edition, EarlyView.
Hexafluorothioacetone (1), a blue gas at r.t., was synthesized by flash vacuum pyrolysis of its cyclic dimer at 660°C. We discuss fundamental properties of elusive 1, including single‐crystal structure and nuclear magnetic resonance spectroscopy, despite its tendency to dimerize even at –74°C.
Hennes Günther, Antti J. Karttunen, Xiulan Xie, Frank Tambornino   +3 more
wiley   +1 more source