Results 221 to 230 of about 152,056 (258)

Electron Bridge Enhanced Charge Polarization Enables Efficient and Ultra‐Long Stable Urea Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An electron bridge strategy is developed to regulate charge polarization in Pd1 and Ni1 dual single‐atom sites, promoting CO2 reduction, nitrate reduction, and C–N coupling simultaneously. The resulting catalyst achieves efficient urea electrosynthesis with high activity and record durability over 1700 h.
Fan Wu   +11 more
wiley   +1 more source

Post‐Synthetic Zinc Modifications to Correct Speciation in Ti‐MWW Zeolites for Catalytic Oxidation

open access: yesAngewandte Chemie, EarlyView.
Post‐synthetic Zn modifications of Ti‐MWW zeolite catalysts exhibit improved catalytic properties in the selective oxidation reaction, namely the ammoximation reaction. The origin of the beneficial effect of Zn is related via an array of spectroscopic and microscopic techniques to the modification of extra‐framework TiO2 and TiOx clusters and the ...
Christoph J. Kaul   +10 more
wiley   +1 more source

Solvent‐Induced Structural Modulation in Nanoscale Covalent Organic Frameworks Enables High‐Performance NO2 Sensing

open access: yesAngewandte Chemie, EarlyView.
Solvent intercalation disrupts the stacking order of protonated porphyrin‐based 2D COF nanoparticles, resulting in a less compactly packed structure with increased accessibility of porphyrin sites. This structural modulation leads to significantly enhanced chemiresistive NO2 sensing performance.
Yu Pan   +4 more
wiley   +1 more source

Vacuum‐Induced Surface Reconstruction of Mn–Ce Oxides for Low‐Temperature Coupled Redox Catalysis

open access: yesAngewandte Chemie, EarlyView.
Near‐surface reconstruction enhances low‐temperature redox catalysis in Mn–Ce mixed oxides. Sequential vacuum annealing and reduced‐pressure O2 treatment enrich Mn near the surface while preserving the CeO2 fluorite framework, promoting interfacial electron redistribution, oxygen activation, and redox cycling.
Yong Yin   +5 more
wiley   +1 more source

The Promise and Challenges of Ammonia Electrosynthesis From Dinitrogen and Water Using an Electrochemical Palladium Membrane

open access: yesAngewandte Chemie, EarlyView.
Electrosynthesis of ammonia from nitrogen gas and water at ambient temperature is demonstrated using a device equipped with an electrochemical palladium membrane, which provides exclusive selectivity for the transfer of protons between the aqueous water oxidation and non‐aqueous nitrogen reduction compartments.
Ngoc‐Trung Nguyen   +11 more
wiley   +1 more source

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