Results 171 to 180 of about 361,154 (280)

Entropy‐Stabilized Pd/HEO Bifunctional Catalyst for Selective Aqueous‐Phase Hydrogenolysis of Cellulose to Ethylene Glycol

open access: yesEcoEnergy, EarlyView.
An entropy‐stabilized Pd/HEO catalyst integrates Lewis acid and hydrogenation sites within a robust oxide–metal interface, enabling efficient and selective conversion of cellulose to ethylene glycol (68.3%) in water. ABSTRACT The selective conversion of cellulose into ethylene glycol (EG) under aqueous conditions is an attractive yet challenging route ...
Dandan Wang   +6 more
wiley   +1 more source

Stabilization of Pd Active Sites by Defective NaY Zeolite Framework for Enhanced Stability in Dimethyl Carbonate Synthesis

open access: yesEcoEnergy, EarlyView.
A tailored‐defect strategy employing sequential high‐temperature calcination and acetylacetone treatment was developed to generate framework defects in NaY zeolite while preventing the formation of strong acid sites. These defects facilitate electron transfer from Pd to the zeolite framework and stabilize the Pd2+ active sites, thereby conferring ...
Chunzheng Wang   +9 more
wiley   +1 more source

Thermodynamic Mechanisms of Co‐S Bond Anchoring in Few‐Layered 1T‐MoS2 for Enhanced Capacitive Performance via Spin State Regulation and Ion Diffusion Kinetics

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The one‐pot hydrothermal prep of Co‐doped few‐layer 1T‐MoS2 shows Co‐S bonds stabilizing the 1T phase, enhancing supercapacitor performance. Few‐layered 1T‐MoS2 is highly promising for supercapacitor applications due to its wide interlayer spacing, high electrical conductivity, and abundant active sites.
Qingling Jia   +4 more
wiley   +1 more source

Constructing Cu/Cu2O Heterogeneous Interface for Efficient Urea Electrosynthesis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this study, a Cu/Cu2O heterogeneous interface with dual active sites is prepared for electrocatalytic CO2 and NO3−$$ {\mathrm{NO}}_3^{-} $$ coupling to urea. The catalyst shows high yield rates of 1156.63 mmol g−1 h−1 and FE of 29.67% at −1.0 V (vs RHE), which is significantly higher than Cu and Cu2O, highlighting the advantages of heterogeneous ...
Jiani Liu   +7 more
wiley   +1 more source

Evaluation of acid rain in urban areas of the United States of America and Mexico from 2003 to 2019. [PDF]

open access: yesEnviron Monit Assess
Jiménez Alcántara A   +3 more
europepmc   +1 more source

Hydrophobic eutectic solvent‐engineered membranes for highly permeable, selective, and antifouling pharmaceutical removal from municipal wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Single‐step incorporation of a hydrophobic deep eutectic solvent (HDES) into polyethersulfone ultrafiltration membranes via non‐solvent induced phase separation creates selective, antifouling membranes for pharmaceutical removal. The HDES nanodomains enhance permeability, electrostatic interactions, and adsorption affinity, enabling efficient and ...
Anjali Goyal   +8 more
wiley   +1 more source

Organic–Inorganic Composite Nanofibers Based on YSZ Nanofibers Anchored PANI/SnS2 Heterojunction for Flexible Room Temperature NO2 Sensor

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel organic–inorganic YSZ@PANI/SnS2 composite nanofiber film was prepared via an in‐situ construction strategy of a PANI interfacial layer. The biomimetic "branch‐leaf" structure effectively disperses and releases stress and energy, while accelerating gas diffusion/transport and providing abundant active sites.
Han Zhang   +7 more
wiley   +1 more source

Triptindane‐9,10,11‐triol: Threefold Hydride Transfer from Lithium Aluminum Hydride as the Key Step to C3‐Symmetrically Trifunctionalized Tribenzo[3.3.3]propellanes

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Threefold reduction of 9,10,11‐triptindanetrione with LiAlH4 or NaBH4 yields exclusively the C3‐symmetric triol, suggesting an intracomplex (“rolling”) mechanism. However, use of LiAlH4/LiAlD4 (1 : 1) reveals a preceding hydride exchange. Mechanistic implications are discussed including the reduction of the related diketone.
Thorsten Hackfort   +5 more
wiley   +1 more source

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