Challenges and Modification Strategies of Ni-Rich Cathode Materials Operating at High-Voltage [PDF]
Ni-rich cathode materials have become promising candidates for lithium-based automotive batteries due to the obvious advantage of electrochemical performance.
Caijian Liao, Fangkun Li, Jun Liu
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Weakly solvated EC-free linear alkyl carbonate electrolytes for Ni-rich cathode in rechargeable lithium battery [PDF]
Summary: Ethylene carbonate (EC) in the electrolyte is not stable in cells operated at high voltage (≥4.4V) or with Li metal anode, which greatly reduce the energy density and lifetime of the rechargeable lithium battery.
Guohuang Kang +11 more
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Comprehensive Understanding of Elemental Doping and Substitution of Ni‐Rich Cathode Materials for Lithium‐Ion Batteries via In Situ Operando Analyses [PDF]
This review explores the challenges and advancements in the development of high‐energy lithium‐ion batteries (LIBs), particularly focusing on the electrochemical and structural stability of Ni‐rich cathode materials.
Yun Seong Byeon +6 more
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Rational design of mechanically robust Ni-rich cathode materials via concentration gradient strategy [PDF]
Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues.
Tongchao Liu +14 more
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Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries [PDF]
The commercialisation of promising Ni-rich cathodes is limited by capacity fading and thermal runaway. Here, the authors design a gradient Al-doped and LiAlO2-coated LiNi0.9Co0.1O2 cathode, which addresses the crystal degradation and interfacial ...
Haifeng Yu +7 more
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Research progress of Ni-rich ternary cathode materials
Ni-rich ternary cathode materials (LiNixCoyMnzO2, x ≥ 0.8) have significant potential for use in lithium-ion batteries because of advantages that include their high energy density, long cycle life, low cost, and environmental sustainability.
Xueyi GUO +5 more
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Direct Synthesis of Single‐Crystalline LiNi0.8Co0.1Mn0.1O2 Cathodes From Lithium‐Containing Precursors via Spray Pyrolysis [PDF]
Single‐crystalline cathode materials have attracted considerable attention for addressing the cycling instability of Ni‐rich layered cathode materials caused by anisotropic lattice strain during repeated cycling.
Tae Ha Kim +7 more
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Solvothermal synthesis-driven quaternary Ni-rich cathode for stability-improved Li-ion batteries
Recently, Ni-rich ternary transition metal oxides (Li(NiCoMn)O2, NCM) containing more than 80% Ni have been extensively studied as high-capacity cathodes.
Sung-Beom Kim +4 more
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An Effective Way to Stabilize Ni-Rich Layered Cathodes [PDF]
Stable cycling with a high energy density at an affordable cost is a key challenge for the prevailing cathode material, Ni-rich layered oxides, to power the development of long-range electric vehicles. Now, Sun and co-workers introduced a Li[Ni0.90Co0.09Ta0.01]O2 cathode in Nature Energy, demonstrating great potential to overcome this challenge.
Jingyu Lu, Chao Xu
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The growing demand for efficient lithium-ion batteries to power vehicles and energy storage entails improving cathode material properties. Maintaining the stability of Ni-rich layered structure oxide cathodes is critical for long-term Li-ion battery ...
Magdalena Zybert +9 more
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