Results 191 to 200 of about 729,228 (244)

Surface‐Strained NiMo Cathodes Enable Kinetics‐Decoupled Hydrogen Bubble Management for Stable Near‐Neutral Water Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
Surface strain tunes the NiMo/electrolyte interface without altering intrinsic hydrogen evolution reaction (HER) kinetics. The strained surface exhibits a lower effective bubble‐detachment tendency and faster release of smaller H2 bubbles, sustaining a more accessible catalytic interface in near‐neutral electrolyte. Reduced bubble‐induced transport and
Si Eun Je   +12 more
wiley   +1 more source

Constructing p‐d Orbital Hybridization via In Situ Generation of Bi19Br3S27/NiSx for Highly Selective Photothermal CO2 Reduction to C2H4

open access: yesAngewandte Chemie, EarlyView.
An in situ crystalline/amorphous Bi19Br3S27/NiSx interface unlocks orbital hybridization‐driven CO2 conversion. Newly formed p‐d coupling reshapes the reaction pathway, promotes C─C coupling, and steers photo‐thermal CO2 reduction toward highly selective C2H4 production.
Guangmei Gan   +6 more
wiley   +2 more sources

Interfacial Electronic Modulation of Vacancy‐Stabilized Pt Sites in Mo‐NiSeO4/NiSe2 Heterostructures for Industrial Alkaline Water Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
A vacancy‐stabilized Pt,Mo‐NiSeO4/NiSe2@Co2P heterostructure with atomically dispersed Pt sites and Mo‐regulated electronic structure enables efficient bifunctional water splitting. Strong interfacial coupling and defect‐assisted Pt stabilization promote rapid charge transfer and optimized intermediate adsorption, delivering outstanding HER/OER ...
Thokchom Anjali Devi   +7 more
wiley   +1 more source

Aromatic Pummerer‐Promoted Stereospecific Cross‐Coupling of Thiazoles With Boronic Esters

open access: yesAngewandte Chemie, EarlyView.
A lithiation–borylation–aromatic Pummerer (LiBAP) strategy enables stereospecific, C5‐selective C(sp2)–C(sp3) cross‐coupling of thiazoles with boronic esters. By using exocyclic sulfoxide activation to overcome the low nucleophilicity that frustrates SEAr‐type coupling, the method delivers enantioenriched alkylated thiazoles bearing a versatile C2 ...
Mark John P. Mandigma   +4 more
wiley   +2 more sources

Developments in Binuclear α-Diimine Nickel Catalysts for Ethylene Polymerization. [PDF]

open access: yesPolymers (Basel)
Yang J   +7 more
europepmc   +1 more source

Accelerating Materials Discovery: A Review of Machine Learning in X‐Ray Absorption Spectroscopy

open access: yesAdvanced Intelligent Systems, EarlyView.
This review systematically details how machine learning transforms X‐ray absorption spectroscopy (XAS) analysis. It covers advanced deep learning architectures for structure‐spectra mapping and inverse tasks, while discussing key challenges like the simulation‐to‐reality gap.
Melaku Lake Tegegne   +5 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

open access: yesAngewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang   +1 more
wiley   +1 more source

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