Results 111 to 120 of about 119,324 (295)

The Ni,Cd Heteroatoms‐Initiated Synergistic Tuning of Electron Configuration in Fe2VO4 Nanosheets Electrocatalysts to Profoundly Stabilize Alkaline Seawater Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
A Ni,Cd‐codoped Fe2VO4/NF bifunctional electrocatalyst is rationally designed for efficient seawater electrolysis. Synergistic effect modulates electron configuration, optimizes intermediates adsorption, stabilizes high‐valence Fe/V sites, and repels chloride ions to suppress corrosion and side reactions, thus contributing to performance improvement of
Weiguo Huang   +15 more
wiley   +1 more source

Spectroscopic Investigation of Polysulfide Redox Evolution in Catholyte Solutions for Potassium–Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Potassium–sulfur batteries are investigated using UV–vis spectroscopy to track the evolution of potassium polysulfide species at elevated temperature. The study reveals sulfur radical anions as key intermediates and shows how solvent composition and cell design influence polysulfide stability, redox behavior, and cycling performance, providing insights
Chiara Morini   +7 more
wiley   +1 more source

Long‐Range Coordination Environment Modulates Single‐Atom Local States and Systemic Impact on CO2 Photoconversion

open access: yesAdvanced Functional Materials, EarlyView.
Terminal groups on Cu porphyrins modulate the electronic states of single‐atom Cu centers through a long‐range electronic effect, without altering the Cu coordination geometry. Meanwhile, a multi‐descriptor framework is established that incorporates porphyrin regulation, hybrid catalyst properties, and CO2 photoreduction capabilities.
Yi Zhang   +13 more
wiley   +1 more source

New planar cobalt(II) and nickel(II) complexes

open access: yes, 1972
Some planar complexes of cobalt(II) and nickel(II) derived from triazene 1-oxides are reported in this paper. The cobalt(II) complexes are very stable and are shown to be monomolecular in solution.
P.S. Zacharias   +3 more
core   +1 more source

Designed Lewis Acid–Base Passivation for High Performance Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
ABSTRACT Silicon's high cost and long energy payback time remain major barriers to the global expansion of solar power. In contrast, metal–halide perovskites offer abundant, solution‐processable absorbers, and have achieved efficiencies of 25%–30%, positioning them as strong competitors to silicon.
Afna Manaf   +4 more
wiley   +1 more source

A Molecular Shielding Strategy to Develop Low Protein Binding, Renal Clearable Pan‐Cancer Near‐Infrared Probes

open access: yesAdvanced Functional Materials, EarlyView.
A molecular shielding strategy to convert “protein‐sticky” and “non‐tumor specific” clinical ICG dye, into a “low protein binding” and “tumor‐targeting” dye with prolonged blood circulation and renal clearance is described. These shielded ICGs demonstrate strong tumor accumulation and optimal tissue clearance, resulting in high tumor‐to‐background ...
Li Xiang   +9 more
wiley   +1 more source

Trace Sulfur‐Doping Boosts NiCo Heterostructured Catalyst for Selective Glycerol‐to‐Formic Acid Electroreforming

open access: yesAdvanced Functional Materials, EarlyView.
A sulfur‐doped Ni–Co heterostructured catalyst is rationally designed to regulate interfacial electronic and adsorption properties for selective glycerol electrooxidation. The synergistic Ni–Co active sites promote hydroxide activation and glycerol adsorption, enabling efficient formic acid production and durable hydrogen generation under continuous ...
Lingqin Shen   +4 more
wiley   +1 more source

An electrochemical investigation of the formation of CoSx and its effect on the anodic dissolution of iron in ammoniacal-carbonate solutions

open access: yes, 2013
It has been found that the co-presence of cobalt (II) and thiosulphate ions in ammoniacal-carbonate solutions promotes the passivation of iron, under conditions in which it would otherwise continue to dissolve anodically. Electrochemical experiments have
Nikoloski, A.N., D'Aloya, A
core  

Pickering‐Engineered Microparticles for Magnetically Guided Motion and Light‐Triggered Catalysis

open access: yesAdvanced Functional Materials, EarlyView.
Magnetically responsive wax microparticles stabilized by hematite cubes through the Pickering emulsification strategy are developed, showing controlled size, motion, and light‐activated catalytic activity. Annealing under a magnetic field enhances their mobility and steering.
Chiara Ferlito   +6 more
wiley   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

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