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Nickel(II) Cyanoborates and Cyanoborate-Ligated Nickel(II) Complexes
Inorganic ChemistryNickel(II) cyanoborates Ni[BH2(CN)2]2·H2O (1b·H2O), Ni[BH(CN)3]2·0.5H2O (1c·0.5H2O), and Ni[B(CN)4]2·0.5H2O (1d·0.5H2O) were synthesized, and their reactivity with respect to dppeO2 (=1,2-bis-(diphenylphosphinoethane dioxide)), pyNO (=pyridine-N-oxide), dppe (=1,2-bis-(diphenylphosphinoethane), and DMSO (=dimethyl sulfoxide) was examined.
Martin S. Luff +4 more
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Nickel(II) Tetraphenylporphyrinate
2001[14172-92-0] C44H28N4Ni (MW 671.45) InChI = 1S/C44H28N4.Ni/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-; InChIKey = CXIRWLOIAQYBLZ-DAJBKUBHSA-N
Cynthia J. Burrows, Shiow-Jyi Wey
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π-cyclopentadienyls of nickel(II)
Journal of Organometallic Chemistry, 1971Abstract η 5 -C 5 H 5 NiPBu 3 CH(CN) 2 (I) readily undergoes ethyl- or phenyl-isothiocyanate insertion, producing the stable products η 5 -C 5 H 5 NiPBu 3 SC(NRH) = C(CN) 2 (IIIa; R = C 2 H 5 , IIIb; R = C 6 H 5 . η 5 -C 5 H 5 NiPPh 3 CH(CN) 2 (II) reacts with RNCS (R = C 2 H 5 and C 6 H 5 ) to undergo two types of insertion reaction; with C 2 H ...
Fumie Sato, Ken Nakamura, Masao Sato
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2014
(NiCl2) [7718-54-9] Cl2Ni (MW 129.59) InChI = 1S/2ClH.Ni/h2*1H;/q;;+2/p-2 InChIKey = QMMRZOWCJAIUJA-UHFFFAOYSA-L (NiCl2ċ6H2O) [7791-20-0] Cl2H12NiO6 (MW 237.71) InChI = 1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2 InChIKey = LAIZPRYFQUWUBN-UHFFFAOYSA-L (mild Lewis acid;2-5 catalyst for coupling reactions,1a,7-12 and in ...
Tien-Yau Luh +2 more
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(NiCl2) [7718-54-9] Cl2Ni (MW 129.59) InChI = 1S/2ClH.Ni/h2*1H;/q;;+2/p-2 InChIKey = QMMRZOWCJAIUJA-UHFFFAOYSA-L (NiCl2ċ6H2O) [7791-20-0] Cl2H12NiO6 (MW 237.71) InChI = 1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2 InChIKey = LAIZPRYFQUWUBN-UHFFFAOYSA-L (mild Lewis acid;2-5 catalyst for coupling reactions,1a,7-12 and in ...
Tien-Yau Luh +2 more
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Artificial Amino Acids in Nickel(II) and Nickel(II)/Lanthanide(III) Chemistry
Inorganic Chemistry, 2011The synthesis and magnetic properties of five new homo- and heterometallic nickel(II) complexes containing artificial amino acids are reported: [Ni(4)(aib)(3)(aibH)(3)(NO(3))](NO(3))(4)·3.05MeOH (1·3.05MeOH), [Ni(6)La(aib)(12)](NO(3))(3)·5.5H(2)O (2·5.5H(2)O), [Ni(6)Pr(aib)(12)](NO(3))(3)·5.5H(2)O (3·5.5H(2)O), [Ni(5)(OH)(2)(l-aba)(4)(OAc)(4)]·0.4EtOH ...
Tereza, Peristeraki +4 more
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2008
[13462-90-3] I2Ni (MW 312.50) InChI = 1S/2HI.Ni/h2*1H;/q;;+2/p-2 InChIKey = BFSQJYRFLQUZKX-UHFFFAOYSA-L (acceleration of SmI2 mediated reactions; catalyst for coupling reactions) Physical Data: mp 797; d 5.38 g cm−3. Solubility: sol H2O, ethanol.
Kenichi Yamanoi, Shinichi Saito
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[13462-90-3] I2Ni (MW 312.50) InChI = 1S/2HI.Ni/h2*1H;/q;;+2/p-2 InChIKey = BFSQJYRFLQUZKX-UHFFFAOYSA-L (acceleration of SmI2 mediated reactions; catalyst for coupling reactions) Physical Data: mp 797; d 5.38 g cm−3. Solubility: sol H2O, ethanol.
Kenichi Yamanoi, Shinichi Saito
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Nickel(II)‐imprinted monolithic columns for selective nickel recognition
Journal of Applied Polymer Science, 2010AbstractNi2+‐imprinted monolithic column was prepared for the removal of nickel ions from aqueous solutions. N‐Methacryloyl‐L‐histidine was used as a complexing monomer for Ni2+ ions in the preparation of the Ni2+‐imprinted monolithic column. The Ni2+‐imprinted poly(hydroxyethyl methacrylate‐N‐methacryloyl‐L‐histidine) (PHEMAH) monolithic column was ...
Alsancak, Guleren +4 more
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Stereochemical versatility of nickel(II). Nickel(II) complexes of cyclohexanone thiosemicarbazone
Transition Metal Chemistry, 1980Using cyclohexanone thiosemicarbazone as ligand (L), nickel(II) complexes, NiL2X2 · nH2O, have been prepared for various anions. Their properties are as follows: X = Cl, green paramagnetic, 5-coordinate; X = Br dimorphous; green, diamagnetic, square-red; paramagnetic, possibly square pyramidyl; X = nitrate, dimorphous-anhydrous, red, diamagnetic ...
Sulekh Chandra +2 more
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Thermal decompostion studies on nickel(II) bis(oxalato)nickelate(II) pentahydrate
Journal of Thermal Analysis, 1990The paper describes the synthesis and thermal decomposition of nickel(II)bis(oxalato)nickelate(II)pentahydrate, Ni[Ni(C2O4)2].5H2O. The complex was characterized by elemental analysis, infrared, electronic, e.s.r., magnetic moment measurement and X-ray powder diffraction studies.
N. Deb, P. K. Gogoi, N. N. Dass
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2001
[6018-89-9] C4H14NiO8 (MW 248.87) InChI = 1S/2C2H4O2.Ni.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2 InChIKey = OINIXPNQKAZCRL-UHFFFAOYSA-L (autoxidation catalyst;1 hydrogenation catalyst;2 catalyst for isomerization of aldoximine4 to amides;3 template for Schiff base condensations4) Physical Data ...
Cynthia J. Burrows, Shiow-Jyi Wey
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[6018-89-9] C4H14NiO8 (MW 248.87) InChI = 1S/2C2H4O2.Ni.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2 InChIKey = OINIXPNQKAZCRL-UHFFFAOYSA-L (autoxidation catalyst;1 hydrogenation catalyst;2 catalyst for isomerization of aldoximine4 to amides;3 template for Schiff base condensations4) Physical Data ...
Cynthia J. Burrows, Shiow-Jyi Wey
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