Results 281 to 290 of about 2,937,461 (378)

Correlating reductive vanadium oxide transformations with electrochemical N<sub>2</sub> activation and ammonia formation.

open access: yesPhys Chem Chem Phys
Balogun K   +8 more
europepmc   +1 more source

Ru-Catalyzed [3 + 2] Cycloaddition of Nitrile Oxides and Electron-Rich Alkynes with Reversed Regioselectivity.

Organic Letters, 2021
Polarity reversal ("umpolung") of a functional group can override its inherent reactivity and lead to distinct bond-forming modes. Herein we describe a rarely studied cycloaddition between nitrile oxides and electron-rich alkynes with reversed ...
Qiang Feng, Hai Huang, Jianwei Sun
semanticscholar   +1 more source

Catalyst-Free Formation of Nitrile Oxides and Their Further Transformations to Diverse Heterocycles.

Organic Letters, 2021
The formation of nitrile oxides with diazocarbonyl compounds by nitrosyl transfer from tert-butyl nitrite under mild conditions and without the use of a catalyst or an additive is reported.
Luca De Angelis   +5 more
semanticscholar   +1 more source

Palladium-Catalyzed (3+3) Annulation of Allenylethylene Carbonates with Nitrile Oxides.

Organic Letters, 2021
In this paper, we designed and synthesized a new type of cyclic carbonates, allenylethylene carbonates (AECs). With AECs as reactive precursors, we developed palladium-catalyzed (3+3) annulation of AECs with nitrile oxides.
Ting Pan   +9 more
semanticscholar   +1 more source

1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides under "Non-Conventional" Conditions: Green Solvents, Irradiation, and Continuous Flow.

ChemPlusChem, 2020
The 1,3-dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes and alkynes are useful methods for the synthesis of 2-isoxazolines and isoxazoles respectively, which are important classes of heterocyclic compounds in organic and ...
J. Plumet
semanticscholar   +1 more source

Polyfluorinated nitrile oxides

Chemistry of Heterocyclic Compounds, 1989
(2+3)-Cycloaddition of polyfluorinated aliphatic nitrile oxides, generated in situ, to donor dipolarophiles takes place regioselectively to give the 5-substituted isoxazolines, and is limited by the donor and steric properties of the dipolarophiles.
G. A. Sokol'skii   +3 more
openaire   +3 more sources

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