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Fe-Catalyzed Fluoroalkyl(hetero)arylation of Vinyl Azaarenes: Rapid and Modular Synthesis of Unsymmetrical 1,1-Bis(hetero)arylalkanes. [PDF]
Guerrero M+3 more
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Feedstock chemical dichloromethane as the C1 source for the chemoselective multicomponent synthesis of valuable 1,4,2-dioxazoles. [PDF]
Xie MJ+9 more
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Organic Letters, 2021
Polarity reversal ("umpolung") of a functional group can override its inherent reactivity and lead to distinct bond-forming modes. Herein we describe a rarely studied cycloaddition between nitrile oxides and electron-rich alkynes with reversed ...
Qiang Feng, Hai Huang, Jianwei Sun
semanticscholar +1 more source
Polarity reversal ("umpolung") of a functional group can override its inherent reactivity and lead to distinct bond-forming modes. Herein we describe a rarely studied cycloaddition between nitrile oxides and electron-rich alkynes with reversed ...
Qiang Feng, Hai Huang, Jianwei Sun
semanticscholar +1 more source
Catalyst-Free Formation of Nitrile Oxides and Their Further Transformations to Diverse Heterocycles.
Organic Letters, 2021The formation of nitrile oxides with diazocarbonyl compounds by nitrosyl transfer from tert-butyl nitrite under mild conditions and without the use of a catalyst or an additive is reported.
Luca De Angelis+5 more
semanticscholar +1 more source
Palladium-Catalyzed (3+3) Annulation of Allenylethylene Carbonates with Nitrile Oxides.
Organic Letters, 2021In this paper, we designed and synthesized a new type of cyclic carbonates, allenylethylene carbonates (AECs). With AECs as reactive precursors, we developed palladium-catalyzed (3+3) annulation of AECs with nitrile oxides.
Ting Pan+9 more
semanticscholar +1 more source
ChemPlusChem, 2020
The 1,3-dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes and alkynes are useful methods for the synthesis of 2-isoxazolines and isoxazoles respectively, which are important classes of heterocyclic compounds in organic and ...
J. Plumet
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The 1,3-dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes and alkynes are useful methods for the synthesis of 2-isoxazolines and isoxazoles respectively, which are important classes of heterocyclic compounds in organic and ...
J. Plumet
semanticscholar +1 more source
Polyfluorinated nitrile oxides
Chemistry of Heterocyclic Compounds, 1989(2+3)-Cycloaddition of polyfluorinated aliphatic nitrile oxides, generated in situ, to donor dipolarophiles takes place regioselectively to give the 5-substituted isoxazolines, and is limited by the donor and steric properties of the dipolarophiles.
G. A. Sokol'skii+3 more
openaire +3 more sources