Results 91 to 100 of about 64,062 (284)

High‐Rate FA‐Based Co‐Evaporated Perovskites: Understanding Rate Limitations and Practical Considerations to Overcome Their Impact

open access: yesAdvanced Functional Materials, EarlyView.
Vacuum‐based deposition is promising for perovskite solar cells to be successfully commercialized. However, co‐evaporation, the most common vapor phase deposition technique, suffers from very low deposition rates. In this work, we reveal that high deposition rates can lead to carbon flakes depositing into the perovskite absorber layers due to material ...
Thomas Feeney   +13 more
wiley   +1 more source

Influence of pH and type of myrosinase complex on the products obtained in the myrosinase catalysed hydrolysis of glucosinolates – a MECC study [PDF]

open access: yes, 2007
Environmental conditions, e.g. pH and the presence of Fe2+ are well known factors that influence the product profile of the myrosinase catalysed hydrolysis of glucosinolates.
Bellostas, Natalia   +2 more
core  

Electrosynthesis of Bioactive Chemicals, From Ions to Pharmaceuticals

open access: yesAdvanced Functional Materials, EarlyView.
This review discusses recent advances in electrosynthesis for biomedical and pharmaceutical applications. It covers key electrochemical materials enabling precise delivery of ions and small molecules for cellular modulation and disease treatment, alongside catalytic systems for pharmaceutical synthesis.
Gwangbin Lee   +4 more
wiley   +1 more source

Diastereoselective synthesis of 3,4-dihydro-2H-pyran-4-carboxamides through an unusual regiospecific quasi-hydrolysis of a cyano group

open access: yesBeilstein Journal of Organic Chemistry, 2016
An efficient diastereoselective approach for the synthesis of functionalized 3,4-dihydro-2H-pyran-4-carboxamides with variable frame was developed based on the reaction of available 4-oxoalkane-1,1,2,2-tetracarbonitriles (adducts of TCNE and ketones ...
Mikhail Yu. Ievlev   +5 more
doaj   +1 more source

Copper Single‐Atom Decorated Microfibrous Catalysts for Continuous‐Flow Reduction of Nitroarenes

open access: yesAdvanced Functional Materials, EarlyView.
Herein, a Cu‐single‐atom decorated, microfibrous catalyst (Cu1/CMF) is fabricated for chemoselective reduction of nitroarenes, demonstrating a superior processing capacity of 1.92 mmol mgcat−1 h−1 and superior durability (≥ 25 cycles) in a continuous‐flow manner.
Jiahan Zhao   +12 more
wiley   +1 more source

Electron–Matter Interactions During Electron Beam Nanopatterning

open access: yesAdvanced Functional Materials, EarlyView.
This article reviews the electron–matter interactions important to nanopatterning with electron beam lithography (EBL). Electron–matter interactions, including secondary electron generation routes, polymer radiolysis, and electron beam induced charging, are discussed.
Camila Faccini de Lima   +2 more
wiley   +1 more source

Charge Transport in Ternary Charge‐Transfer Solid Solution Single Crystals

open access: yesAdvanced Functional Materials, EarlyView.
This study deconvolutes the roles of indirect (superexchange) and direct electronic coupling on charge transport in single crystals of an organic charge‐transfer molecular semiconductor (OSC). This model system elegantly demonstrates that structural defects introduced by chemical dopants play a significant role in the electronic performance ...
Jonathan C. Novak   +7 more
wiley   +1 more source

Analyzing the Catalytic Role of Active Site Residues in the Fe-type Nitrile Hydratase from \u3cem\u3eComamonas testosteroni\u3c/em\u3e Ni1 [PDF]

open access: yes, 2015
A strictly conserved active site arginine residue (αR157) and two histidine residues (αH80 and αH81) located near the active site of the Fe-type nitrile hydratase from Comamonas testosteroni Ni1 (CtNHase), were mutated. These mutant enzymes were examined
Chan, Hei   +6 more
core   +1 more source

Facet‐Engineered S‐Scheme Heterostructure With Enhanced Active Sites for Efficient Photocatalytic Degradation of Organic Contaminants

open access: yesAdvanced Functional Materials, EarlyView.
The facet‐engineered ZnO/Zn3In2S6 heterostructure, dominated by {001} plane coupling, exposes abundant unsaturated Zn sites with elongated Zn─O bonds, directing photoexcited charge carriers along an S‐scheme pathway and suppressing recombination. Enhanced interfacial Zn adsorption toward bisphenol A and methylene blue further synergistically promotes ...
Yang Yang   +6 more
wiley   +1 more source

A Cobalt-Containing Eukaryotic Nitrile Hydratase [PDF]

open access: yes, 2017
Nitrile hydratase (NHase), an industrially important enzyme that catalyzes the hydration of nitriles to their corresponding amides, has only been characterized from prokaryotic microbes. The putative NHase from the eukaryotic unicellular choanoflagellate
Bennett, Brian   +3 more
core   +1 more source

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