A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam +3 more
wiley +2 more sources
Computational Experiments Probing the Adaptability of the [NCCH<sub>2</sub>]<sup>-</sup> Electronic Structure to Various Bonding Environments. [PDF]
Rio J, Brière JF, Gérard H.
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TfOH-Promoted Cascade Reaction of Nitriles and 1,5-Enynes: An Efficient Route to Amido-Functionalized Fluorenes. [PDF]
Gore BS, Liu WJ, Pan LW, Li CH, Wang JJ.
europepmc +1 more source
Efficient, Functional Group-Tolerant, and Catalyst-Free Nitrile Formation from Aldehydes. [PDF]
Aydonat S, Campagna D, Göstl R.
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Direct cyanation of aromatic rings using dinitrogen and methane promoted by nonthermal plasma. [PDF]
Yu L +12 more
europepmc +1 more source
Noncovalent interaction-driven regio- and enantioselective hydroalkynylation of unactivated alkenes to access remote chiral nitriles. [PDF]
Meng F +5 more
europepmc +1 more source
Abiotic formation of nitrile precursors to amino acids and nucleobases in interstellar ice analogues. [PDF]
Wang J +8 more
europepmc +1 more source
Dibenzazepine Bridged Network Polymeric Phthalocyanines as Degradable Heterogeneous Photocatalysts
Dibenzazepine photodynamic bridge has been introduced to zinc and cobalt networks phthalocyanines (NP‐Pcs) to obtain degradable heterogeneous photocatalysts. For the first time, light irradiation plays a key role in “design, use and degradation” of NP‐Pcs.
Erem Ahmetali +4 more
wiley +1 more source
Recent Advances in Metal-Based Catalysts for Nitrile Hydration to Amides: Mechanistic Aspects. [PDF]
Essebbar FE +3 more
europepmc +1 more source
Efficient solvent-free amide synthesis via Ritter reaction catalyzed by a reusable Fe<sub>3</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/ NTMPA nanocomposite. [PDF]
Karimitabar H, Sardarian AR.
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