Results 81 to 90 of about 60,817 (284)

Scalable and Multifunctional PAN‐MXene Composite Fibers for Thermal Management, Photothermal Conversion, Energy Harvesting, and Sensing for Wearable Applications

open access: yesAdvanced Materials, EarlyView.
Electrospun PAN‐MXene nanofibers and yarns integrate enhanced thermal conductivity, photothermal conversion, and triboelectric energy harvesting within a flexible architecture. Interconnected MXene networks promote efficient phonon transport, while their surface chemistry strengthens tribo‐negative behavior, enabling a high power density of 432.7 mW m ...
Ahmadreza Moradi   +2 more
wiley   +1 more source

Self‐Regulating Sodium‐Ion Battery Materials: From Phase Reconstruction to Functional Activation

open access: yesAdvanced Materials, EarlyView.
Self‐regulating sodium‐ion batteries hinge on programmable phase behavior in layered oxides, interphases that renew without growth, and electrolytes that steer solvation and chemistry. This review distills mechanisms into design rules that span composition, site and entropy tuning, and self‐buffering anodes, linking operando evidence to choices and ...
Hong Gao   +10 more
wiley   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

open access: yesAdvanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard   +7 more
wiley   +1 more source

Improved Schmidt Conversion of Aldehydes to Nitriles Using Azidotrimethylsilane in 1,1,1,3,3,3-Hexafluoro-2-propanol

open access: yesMolecules, 2015
The Schmidt reaction of aromatic aldehydes using a substoichiometric amount (40 mol %) of triflic acid is described. Low catalyst loading was enabled by a strong hydrogen-bond-donating solvent hexafluoro-2-propanol (HFIP).
Hashim F. Motiwala   +2 more
doaj   +1 more source

Anti‐Slip Material‐Based Strategies and Approaches

open access: yesAdvanced Materials Technologies, EarlyView.
This review highlights the principle mechanisms of slipping at the microscale, linking contact mechanics with a friction behavior model for surface interfaces. Main strategies to develop anti‐slip properties to the surfaces are discussed alongside standardized testing approaches.
Sogand Abbaspoor‐Zanjani   +3 more
wiley   +1 more source

Metal-Mediated Addition of N-Nucleophiles to Isocyanides: Mechanistic Aspects

open access: yesMolecules, 2017
Despite the long history of the investigation of nucleophilic addition to metal-bound isocyanides, some important aspects of the reaction mechanism remain unclear even for the simplest systems.
Maxim L. Kuznetsov, Vadim Yu. Kukushkin
doaj   +1 more source

Degradation Mechanisms in PEM Water Electrolysis: Diagnosis and Impact

open access: yesAdvanced Materials Technologies, EarlyView.
This review provides an analysis of degradation mechanisms in proton electrolyte membrane water electrolyzers (PEMWE), focusing on all key components. It discusses diagnostic and measurement techniques for evaluating degradation, less‐studied mechanisms, and an expert survey.
Annik Bernhardt   +11 more
wiley   +1 more source

Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex.

open access: yesJournal of the American Chemical Society, 2016
The first example of a catalytic Michael addition reaction of non-activated aliphatic nitriles to α,β-unsaturated carbonyl compounds under mild, neutral conditions is reported.
A. Nerush   +5 more
semanticscholar   +1 more source

Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH2OH·HCl and TiO2

open access: yesMolecules, 2009
Aromatic aldehydes bearing electron-donating groups are easily converted into their respective nitriles using NH2OH·HCl and TiO2 under microwave irradiation, while those bearing an electron-withdrawing group give the corresponding oximes.
Lucas Villas-Boas Hoelz   +3 more
doaj   +1 more source

Magnetic Textiles: A Review of Materials, Fabrication, Properties, and Applications

open access: yesAdvanced Materials Technologies, EarlyView.
Magnetic textiles (M‐textiles) are emerging as a programmable materials platform that merges magnetic matter with hierarchical textile structures. This article consolidates magnetic material classes, textile architectures, and fabrication and magnetization strategies, revealing structure–property–function relationships that govern magneto‐mechanical ...
Li Ke   +3 more
wiley   +1 more source

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