Results 41 to 50 of about 57,963 (315)

Electroactive Liquid Crystal Elastomers as Soft Actuators

Advanced Functional Materials, EarlyView.
Electroactive liquid crystal elastomers (eLCEs) can be actuated via electromechanical, electrochemical, or electrothermal effects. a) Electromechanical effects include Maxwell stress, electrostriction, and the electroclinic effect. b) Electrochemical effects arise from electrode redox reactions.
Yakui Deng, Min‐Hui Li
wiley   +1 more source

Stable BF2 Boracycles as Versatile Reagents for Selective Ortho C–H Functionalization

Angewandte Chemie, EarlyView.
We report a robust, metal‐free and scalable synthesis of stable BF2 boracycles via directed ortho CH borylation, delivering isolable, shelf‐stable reagents without chromatographic purification. These BF2 boracycles exhibit unique and tunable reactivity, enabling highly selective ipso‐functionalization across a broad range of transformations.
Ganesh H. Shinde, Jonatan Babiker, Michelle Mebrahtu, Anaïs Prigent, Gauthier Foucras, Yogesh N. Aher, Francoise M. Amombo Noa, Magnus J. Johansson, Janez Košmrlj, Ross D. Jansen‐van Vuuren, Thomas Cailly, Henrik Sundén   +11 more
wiley   +2 more sources

Crystallographic Distinction between “Contact” and “Separated” Ion Pairs:  Structural Effects on Electronic/ESR Spectra of Alkali-Metal Nitrobenzenides [PDF]

, 2004
The classic nitrobenzene anion-radical (NB-• or nitrobenzenide) is isolated for the first time as pure crystalline alkali-metal salts. The deliberate use of the supporting ligands 18-crown-6 and [2.2.2]cryptand allows the selective formation of contact ...
Davlieva, M. G., Kochi, Jay K., Lindeman, Sergey V., Lü, Jian-Ming   +3 more
core   +1 more source

Copper Single‐Atom Decorated Microfibrous Catalysts for Continuous‐Flow Reduction of Nitroarenes

Advanced Functional Materials, EarlyView.
Herein, a Cu‐single‐atom decorated, microfibrous catalyst (Cu1/CMF) is fabricated for chemoselective reduction of nitroarenes, demonstrating a superior processing capacity of 1.92 mmol mgcat−1 h−1 and superior durability (≥ 25 cycles) in a continuous‐flow manner.
Jiahan Zhao, Yingshuang Li, Zhuoyuan Bi, Guanwu Lian, Guokang Chen, Pei Liu, Yuan Meng, Fangrun Jin, Xiaoxu Zhao, Zhonghua Li, Jianyong Feng, Jiangbo Xi, Zhongxin Chen   +12 more
wiley   +1 more source

Proximity Engineering of Fe‒N4 Twins for Oriented Generation of Singlet Oxygen for Hospital Wastewater Treatment

Angewandte Chemie, EarlyView.
Precise modulation of Fe–N4 site distances constructs spin‐regulated Fe–N4 twins, triggering a volcano‐type Fenton‐like activity and promoting oriented singlet oxygen generation. The twin‐site catalyst enables highly selective and efficient hospital wastewater purification with simultaneous pharmaceutical degradation and disinfection under low ...
Xinhao Wang, Zhaokun Xiong, Shuai Yang, Hongyu Zhou, Yanbiao Shi, Zelin Wu, Bingkun Huang, Lei Yang, Chuan‐Shu He, Xiaoguang Duan, Bo Lai   +10 more
wiley   +2 more sources

A Novel Reaction System for Cogeneration of Chemicals and Electric Energy by Electrochemical Reduction of Nitrobenzene with Iron

International Journal of Electrochemical Science, 2016
We report a novel green route for generate electric energy by simultaneously electrochemical reduction of nitrobenzene with iron which is carried out in a home-made diaphragm electrolytic cell using iron as reducer. The result shows that nitrobenzene can
Yetao Li, Yang Yang, Yunxia Sun, Xingwang Gao, Liang Chen, Weimin Zhang, Song Chen   +6 more
doaj   +1 more source

2,6-Bis(phenylamino)-4-(iminophenyl)benzoquinone

Molbank, 2022
The reaction of 2,4-difluoronitrobenzene with an excess of aniline at 175 °C led to the isolation of an unexpected brown quinone substituted with two phenylamino groups and one phenylimino group.
M. John Plater
doaj   +1 more source

Controlling Competitive Radical Pathways: Insights From Aryl Diazonium Electrografting. [PDF]

Chemistry
This work shows that nitrobenzene diazonium electrografting results from competition between aryl and diazenyl radicals, which govern film composition. Using simulations and control strategies, grafting conditions are tuned to favor specific radicals. It enables selective formation of azo‐enriched films and paves the way toward the precise control of ...
Helis S, Pinson J, Decorse P, Hamon J, Noël JM, Breton T.   +5 more
europepmc   +2 more sources

Opportunities of Semiconducting Oxide Nanostructures as Advanced Luminescent Materials in Photonics

Advanced Materials, EarlyView.
The review discusses the challenges of wide and ultrawide bandgap semiconducting oxides as a suitable material platform for photonics. They offer great versatility in terms of tuning microstructure, native defects, doping, anisotropy, and micro‐ and nano‐structuring. The review focuses on their light emission, light‐confinement in optical cavities, and
Ana Cremades, Pedro Hidalgo, David Maestre, Ruth Martínez‐Casado, Emilio Nogales, Beatriz Rodríguez, G. Cristian Vásquez, Bianchi Méndez   +7 more
wiley   +1 more source

Responses of nitrobenzene removal performance and microbial community by modified biochar supported zerovalent iron in anaerobic soil

Scientific Reports
Biochar-supported ZVI have received increasing attention for their potential to remove nitrobenzene in groundwater and soil. However, the capacity of this material to enhance the biological reduction of nitrobenzene and alter microbial communities in ...
Lu Hainan, Li Peng, Li Qingqing, Liu Fang, Zhou Dong, Huang Shenfa, Yang Jie, Li Zhiheng   +7 more
doaj   +1 more source