Results 101 to 110 of about 24,942 (205)

Redox Properties of Catalytically Generated Iminium Ions From α,β‐Unsaturated Aldehydes and Chiral Secondary Amines

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 24, 23 June 2026.
We present a rapid, operationally simple, and broadly applicable protocol for the catalytic formation and in situ electrochemical characterization of chiral a,b‐unsaturated iminium ions by cyclic voltammetry (CV). Using only 5 mol% of the aminocatalyst, we systematically measure the reduction potential of over 50 iminium intermediates, revealing how ...
Martí Gisbert   +2 more
wiley   +1 more source

Enhanced catalytic reduction through in situ synthesized gold nanoparticles embedded in glucosamine/alginate nanocomposites

open access: yesBeilstein Journal of Nanotechnology
This study introduces a highly efficient and straightforward method for synthesizing gold nanoparticles (AuNPs) within a glucosamine/alginate (GluN/Alg) nanocomposite via an ionotropic gelation mechanism in aqueous environment.
Chi-Hien Dang   +10 more
doaj   +1 more source

Asymmetric Michael Addition of Cyanide to α,β‐Unsaturated Aldehydes Catalyzed by Diarylmethyl‐Substituted Diphenylprolinol Silyl Ethers: Thermodynamically Controlled Product Formation under Kinetic Enantioselective Catalysis

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
Asymmetric Michael addition of cyanide to α,β‐unsaturated aldehydes catalyzed by diarylmethyl‐substituted diphenylprolinol silyl ethers:Thermodynamically controlled product formation under kinetic enantioselective catalysis. Diphenylprolinol silyl ether catalyzed asymmetric Michael/1,2‐addition reaction of cyanide to α,β‐unsaturated aldehydes at high ...
Konstantinos Daskalakis   +4 more
wiley   +1 more source

Dimolecular Reduction of Nitrophenols

open access: yesCommunications, Faculty Of Science, University of Ankara Series B Chemistry and Chemical Engineering, 1949
Celal TÜZÜN, Vedia ERTÜZÜN
openaire   +1 more source

Metal‐Dependent Effects and Crowding Robustness of Pseudomonas fluorescens Esterase I

open access: yesChemBioChem, Volume 27, Issue 11, 15 June 2026.
Pseudomonas fluorescens esterase I retains catalytic activity in metal‐rich and crowded environments, despite metal‐specific inhibitory effects. These findings highlight its robustness for biocatalytic applications in complex environments. Industrial biocatalysts are strongly influenced by their physicochemical environment, yet systematic studies on ...
Emmanouil Ntermanakis   +6 more
wiley   +1 more source

Semi‐Rational Engineering of Formate Dehydrogenase Reveals Loop Dynamics as a Key Determinant of Thermostability

open access: yesChemBioChem, Volume 27, Issue 11, 15 June 2026.
Semi‐rational engineering yields a thermostable Bacillus simplex formate dehydrogenase variant (Q125F) with a 25‐fold longer half‐life at 60°C and strong resistance to chemo‐inactivation. Molecular dynamics reveal enhanced π–π interactions stabilizing a flexible loop and enabling efficient NADH regeneration for robust biocatalytic detoxification ...
Rattima Boonkumkrong   +7 more
wiley   +1 more source

Catalytic reduction of p-nitrophenol and Eosin Yellow by lemongrass tea-stabilized copper nanoparticles

open access: yesGreen Chemistry Letters and Reviews
Green synthesis of nanoparticles for catalytic applications remains of continued interest, especially for reactions that would occur on an industrial scale or that may be of environmental significance.
Amanda R. Kale   +2 more
doaj   +1 more source

Obtaining and Characterizing the Osmium Nanoparticles/n-Decanol Bulk Membrane Used for the p-Nitrophenol Reduction and Separation System. [PDF]

open access: yesMembranes (Basel), 2022
Nechifor AC   +9 more
europepmc   +1 more source

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