Results 241 to 250 of about 764,997 (298)

High Pressure Stabilizes the Elusive Hexacoordinated Carbon

open access: yesChemistryEurope, EarlyView.
The MCF6 species (M = Ca, Sr) is more stable than the bicomponent MF2…CF4 mixture in the solid‐state at high pressure (p > 400 GPa). The main building block is the [CF6]2− unit in which carbon is hexacoordinated. Unusually high coordination number for elements has been of great interest in chemistry.
Shovan Das, Adrish Das, Ayan Datta
wiley   +1 more source

Bis‐Dichlorosilyl Functionalized C4‐Cumulene With Unique Bonding Scenario

open access: yesChemistry – A European Journal, EarlyView.
Herein, we report a silylene‐functionalized C4‐cumulene (2) and investigate its bonding scenario employing computational methods such as NBO analysis, AIM, and energy decomposition analysis‐natural orbital for chemical valence (EDA‐NOCV). The EDA‐NOCV analysis showed that compound 2 prefers to possess electron‐sharing covalent sigma and dative covalent
Saroj Kumar Kushvaha   +10 more
wiley   +1 more source

Critical period of weed-crop competition in irrigated chickpea as a tool for judicious weed control. [PDF]

open access: yesSci Rep
Hakeem SA   +10 more
europepmc   +1 more source

Synthetic Studies towards Darobactin A

open access: yesChemistry – A European Journal, EarlyView.
The urgent need for new antibiotics led us to develop a new methodology for the synthesis of the natural product darobactin A selectively targeting gram‐negative bacteria. This study provides new insights into the synthesis of strained indole‐containing macrocycles.
Till Steiner   +4 more
wiley   +1 more source

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