Comparative physiological and genomic characterization of a novel <i>Nitrobacter vulgaris</i> strain from a nitrate-contaminated subsurface. [PDF]
Flinkstrom Z +11 more
europepmc +1 more source
New redox‐active oligothioguanidines are developed and used in dehydrogenative P–P coupling reactions and hydroquinone oxidations. Tetrathioguanidino‐ and tetraguanidinobenzenes oxidize high‐potential halogenated hydroquinones faster than relatively low‐potential hydroquinone.
Ute Wild +4 more
wiley +1 more source
Acute Environmental Triggers and Intermediate-Term Modulators of Emergency Migraine-Related Health Care Encounters. [PDF]
Peles I +5 more
europepmc +1 more source
This work introduces the concept of pseudoglucosinolates (psGSLs) and reports the synthesis and evaluation of nitroreductase‐responsive psGSLs. These compounds represent a complementary prodrug strategy to natural glucosinolates (GSLs) for the controlled release of isothiocyanates (ITCs), enabling bio‐responsive protein labeling, as demonstrated in ...
Claire C. Jimidar +13 more
wiley +1 more source
Unveiling an {FeNO}<sup>6</sup> Intermediate: A Sequential Mechanistic Investigation of Nitrite Reduction in a Mononuclear Iron(II) Complex. [PDF]
Sun S +7 more
europepmc +1 more source
Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3
Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita +3 more
wiley +1 more source
Electroreduction of CO<sub>2</sub> From Flue Gas: Impurity Tolerance and Mechanistic Insights in Molecular Catalysis. [PDF]
Segura-Ramirez Y +4 more
europepmc +1 more source
Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers
Amorphous coordination polymers (Am‐CPs) showed a strict modulation of water uptake behavior via a solid solution approach. The desirable water uptake characteristics were corroborated by the type and local coordination geometry of the central metals, as revealed by a combination of L2,3‐ and K‐edge X‐ray absorption fine structure (XAFS) techniques ...
Haruka Yoshino +8 more
wiley +1 more source
Impact of Ambient Air Pollution on Cardiovascular Diseases in Low- and Lower-Middle-Income Countries: A Systematic Review and Meta-Analysis. [PDF]
Adeoye M +8 more
europepmc +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source

