Results 181 to 190 of about 60,850 (257)

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

Chemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents

Chemistry – A European Journal, EarlyView.
ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter, Olaf Hübner, Hans‐Jörg Himmel   +2 more
wiley   +1 more source

Investigation of the In Vitro and In Vivo Metabolism and μ‐Opioid Receptor Affinity of the Nitazene N‐Pyrrolidino Fluetonitazene

Drug Testing and Analysis, EarlyView.
Eight metabolites for N‐pyrrolidino fluetonitazene were identified in vitro, three of which (M2, M6 and M8) were present in an authentic urine sample. M2 was the most abundant in vivo metabolite and is a common marker metabolite of nitazepyne‐type substances.
Severin Zemp, Gaia Alluisetti, Wolfgang Weinmann, Bettina Schrag, Frank Sporkert, Maurine Leclerc, Katharina Elisabeth Grafinger   +6 more
wiley   +1 more source

A Thermally Robust Luminescent Antimony Halide for Real‐Time Detection of Volatile Iodine at Elevated Temperatures

EcoEnergy, EarlyView.
Zero‐dimensional antimony halides drive efficient iodine capture through electron transfer and display rapid fluorescence quenching at 75°C (348 K), establishing the first luminescent sensor for real‐time I2 detection at elevated temperatures. ABSTRACT Real‐time monitoring of volatile molecular iodine (I2), a hazardous radioactive byproduct of nuclear ...
Ying Jiang, Yumin Wang, Fu Peng, Junren Wang, Shangge Zhang, Linwei He, Guangyuan Chen, Jianrong Zeng, Fangling Jiang, Lin Zhu, Kai Li, Long Chen, Shuao Wang, Yaxing Wang   +13 more
wiley   +1 more source

Mixed‐Impurity Co‐Poisoning of NH3‐SCR Catalysts: Poisoning Mechanisms, Antagonistic Effects, and Anti‐Inactivation Strategies

EcoEnergy, EarlyView.
This review summarizes the synergistic effects of mixed impurities on ammonia‐selective catalytic reduction (NH3‐SCR) catalysts, including the poisoning mechanism of the catalyst caused by mixed impurities, the antagonistic effects between the impurities, and the research on the anti‐poisoning strategies for the catalyst in recent years.
Hongyan Xue, Manas Pal, Zhaoteng Xue, Dongsen Mao   +3 more
wiley   +1 more source

A Review of Grain Boundaries: Formation Mechanism, Synthesis Strategy, and Application in Electrocatalysis

EcoEnergy, EarlyView.
An overview of grain boundary engineering in the field of electrocatalysis. ABSTRACT Key electrocatalytic reactions such as HER, OER, ORR, CO2RR, and NRR offer promising routes for storing renewable energy as chemical fuels. However, their widespread application is constrained due to the lack of highly active and stable catalysts. Grain boundaries (GBs)
Jingyu Gao, Fengming Zhou, Xinying Li, Ying Deng, Zexing Wu, Siyuan Feng, Yujing Zhu, Dan Zhang, Zhenyu Xiao   +8 more
wiley   +1 more source

Design of a Novel CeW/Fe‐TiO2 Catalyst With High Oxygen Vacancy for Enhancing the Reactivity and SO2 Resistance in Low‐Temperature NH3‐SCR Reaction

EcoEnergy, EarlyView.
Fe3+ was introduced into the TiO2 lattice using the hydrothermal method, and low‐valent cations replaced part of Ti4+ to generate oxygen vacancies within the Fe‐Ov‐Ti unit, resulting in CeW/Fe‐TiO2 catalysts with oxygen‐deficient structures. Compared with CeW/TiO2 catalyst, the increase in oxygen vacancy content significantly improved the catalytic ...
Yuhang Wang, Xiaosheng Huang, Guodong Zhang, Haitao Zhang, Yongjie Xi, Zhicheng Tang   +5 more
wiley   +1 more source

Organic–Inorganic Composite Nanofibers Based on YSZ Nanofibers Anchored PANI/SnS2 Heterojunction for Flexible Room Temperature NO2 Sensor

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel organic–inorganic YSZ@PANI/SnS2 composite nanofiber film was prepared via an in‐situ construction strategy of a PANI interfacial layer. The biomimetic "branch‐leaf" structure effectively disperses and releases stress and energy, while accelerating gas diffusion/transport and providing abundant active sites.
Han Zhang, Mingyu Gao, Jiajia Deng, Yan Wang, Yingru Li, Xinjian Song, Rong Li, Jianfeng Tan   +7 more
wiley   +1 more source

Highly Permeable CeO2 Porous Hollow Microspheres with Multilevel Gas Channels for Rapid NH3 Gas Response and Recovery Performance

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this study, a series of highly permeable CeO2 porous hollow microspheres with multilevel gas channels and tunable pore sizes were first prepared via the hydrothermal method, achieving rapid response and fast recovery to ammonia gas. Fast response and recovery performance is highly significant for real‐time monitoring of NH3 gas due to the toxic and ...
Mengke Li, Kairui Liu, XingYu Jin, Mengyuan Ma, Lihao Lv, Zhihao Wang, Siyi Liu, Hengchao Zhang, Chong Li, Xinbing Jiang, Ke Yang, Lingmin Yu   +11 more
wiley   +1 more source

Insights to Industrial Electrocatalytic Sulfide Oxidation: Electrode Fabrication, System Engineering, and High‐Value Product Acquisition

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review summarizes recent advances in electrocatalytic sulfide oxidation (SOR), focusing on catalyst design strategies, reaction system engineering, and pathways for high‐value product generation. The roles of different reduced sulfur species (S2−, HS−, H2S) under various industrial conditions are highlighted, along with approaches to enhance ...
Zhongyuan Wang, Yinxi Han, Yufei Zhang, Jinghuan Chen, Jiade Wang   +4 more
wiley   +1 more source