Results 181 to 190 of about 363,361 (302)

Comparative physiological and genomic characterization of a novel <i>Nitrobacter vulgaris</i> strain from a nitrate-contaminated subsurface. [PDF]

open access: yesAppl Environ Microbiol
Flinkstrom Z   +11 more
europepmc   +1 more source

Hydroquinone Oxidation by Redox‐active Guanidines and Thioguanidines: Faster Conversion to High‐Potential Than to Low‐Potential Quinones

open access: yesChemistry – A European Journal, EarlyView.
New redox‐active oligothioguanidines are developed and used in dehydrogenative P–P coupling reactions and hydroquinone oxidations. Tetrathioguanidino‐ and tetraguanidinobenzenes oxidize high‐potential halogenated hydroquinones faster than relatively low‐potential hydroquinone.
Ute Wild   +4 more
wiley   +1 more source

Bioresponsive pseudoGlucosinolates (psGSLs) Release Isothiocyanates (ITCs) in the Presence of Nitroreductases

open access: yesChemistry – A European Journal, EarlyView.
This work introduces the concept of pseudoglucosinolates (psGSLs) and reports the synthesis and evaluation of nitroreductase‐responsive psGSLs. These compounds represent a complementary prodrug strategy to natural glucosinolates (GSLs) for the controlled release of isothiocyanates (ITCs), enabling bio‐responsive protein labeling, as demonstrated in ...
Claire C. Jimidar   +13 more
wiley   +1 more source

Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita   +3 more
wiley   +1 more source

Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers

open access: yesChemistry – A European Journal, EarlyView.
Amorphous coordination polymers (Am‐CPs) showed a strict modulation of water uptake behavior via a solid solution approach. The desirable water uptake characteristics were corroborated by the type and local coordination geometry of the central metals, as revealed by a combination of L2,3‐ and K‐edge X‐ray absorption fine structure (XAFS) techniques ...
Haruka Yoshino   +8 more
wiley   +1 more source

Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†

open access: yesChinese Journal of Chemistry, EarlyView.
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley   +1 more source

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