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On-Surface Synthesis of Nonmetal Porphyrins
Journal of the American Chemical Society, 2020We report the on-surface synthesis of a nonmetal porphyrin, namely, silicon tetraphenylporphyrin (Si-TPP), by the deposition of atomic silicon onto a free-base TPP layer on a Ag(100) surface under ultrahigh vacuum (UHV) conditions. Scanning tunneling microscopy provides insights into the self-assembly of the TPP molecules before and after Si insertion.
Aleksandr Baklanov +10 more
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Reports on Progress in Physics, 1970
An account is given of some of the mechanisms which can lead to a transition from a metallic to a nonmetallic state, when a parameter such as the interatomic distance or temperature is varied. The simplest of these is the band overlap or Wilson transition, which occurs when a conduction band overlaps a valence band; this is discussed in § 2 and for ...
N F Mott, Z Zinamon
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An account is given of some of the mechanisms which can lead to a transition from a metallic to a nonmetallic state, when a parameter such as the interatomic distance or temperature is varied. The simplest of these is the band overlap or Wilson transition, which occurs when a conduction band overlaps a valence band; this is discussed in § 2 and for ...
N F Mott, Z Zinamon
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Putting Nonmetals into Fullerenes
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Martin Saunders, R. James Cross
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Phase diagram and thermal properties of organic analogues of nonmetal–nonmetal systems
Journal of Thermal Analysis and Calorimetry, 2015The solid–liquid phase equilibrium data on three binary organic systems, namely 4-hydroxy benzaldehyde (HB)–2-methyl-4-nitro aniline (MNA), 3-hydroxy-4-methoxybenzaldehyde (HMB)–2-chloro-4-nitroaniline (CNA) and 4-aminobenzophenone (ABP)–m-nitrobenzoic acid (NBA), determined by the thaw-melt method, show the formation of a eutectic at 0.60 mol fraction
R. N. Rai, Priyanka Pandey, U. S. Rai
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