Large Faraday rotation at room temperature is observed in thin films of discotic copper (Cu2+: 3d9) and vanadyl (VO2+: 3d1) enaminoketone complexes. The large Verdet constant originates from a high density of paramagnetic centers, metal‐ligand p−d hybridization and π orbitals involved in optical transitions (identified by DFT calculations), as well as ...
Karolina Łempicka‐Mirek +8 more
wiley +1 more source
SLEEPY: a comprehensive Python module for simulating relaxation and dynamics in nuclear magnetic resonance. [PDF]
Smith AA, Zumpfe K.
europepmc +1 more source
Probing Near‐Field EM Fluctuations in Superparamagnetic CoFeB With NV Quantum Dephasometry
We non‐invasively investigate the superparamagnetic spin dynamics of a 1.1 nm CoFeB layer by probing its near‐field EM fluctuations using NV centers‐based quantum dephasometry. Our findings are further supported by theoretical modeling and SQUID‐based magnetization characterization. These results provide critical insight into the magnetization dynamics
Shoaib Mahmud +5 more
wiley +1 more source
Analysis of per- and polyfluoroalkyl substances (PFAS) removal with activated carbon using 19F nuclear magnetic resonance spectroscopy. [PDF]
Earl GF, Stevens LA, Li W, Snape CE.
europepmc +1 more source
On‐Chip Saturated Absorption of CO2 in a Silicon‐on‐Sapphire Waveguide
We demonstrate the first saturated absorption of a molecular gas on a planar photonic chip. By coupling carbon dioxide with the tightly confined light of a silicon‐on‐sapphire waveguide, we achieve optical saturation using only milliwatt powers. This breakthrough provides a practical, low‐power foundation for creating ultra‐compact mid‐infrared ...
Shahar Edelstein +2 more
wiley +1 more source
Modern Quantum Chemistry Methodology for Predicting <sup>31</sup>P Nuclear Magnetic Resonance Chemical Shifts. [PDF]
Rusakova IL, Rusakov YY.
europepmc +1 more source
Negatively charged boron vacancy defects in hexagonal boron nitride promise near‐surface quantum sensing, but their internal spin transition rates are only partly understood. This work directly measures the defect's singlet‐state lifetime, 15(3) ns, using a nanosecond rise‐time dual‐pulse photoluminescence‐recovery method, and shows that high laser ...
Richard A. Escalante +11 more
wiley +1 more source
Amphiphilic chloroazobenzenes, bearing different amino acids as end groups alanine, phenylalanine, and valine, exhibit excellent photoisomerizations. Varying structures of three amino acid groups participate in supramolecular formations and therefore photoinduced morphological transformations via adjusting intermolecular interactions. These interaction
Shuangshuang Meng +3 more
wiley +1 more source
Detection of Phosphite Fungicide in <i>Persea americana</i> Fruits Using Nuclear Magnetic Resonance (NMR) Spectroscopy at 400 and 80 MHz. [PDF]
Bernal A +11 more
europepmc +1 more source
A Superlubricated Magnetically Steerable Microcatheter with Integrated Optical and Fluidic Channels
A magnetically steerable microcatheter with integrated optical and fluidic channels is developed for multifunctional navigation in tortuous anatomical environments. A surface‐grafted hydrogel coating enables low‐friction actuation. The device demonstrates stable light and fluid delivery during magnetic manipulation, offering a compact platform for ...
Yuntian Du +5 more
wiley +1 more source

