Results 161 to 170 of about 2,485,930 (195)

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

open access: yesAngewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han   +14 more
wiley   +2 more sources

Degradable Alternating Copolymers With Strained Cyclobutane Backbones via Photocontrolled RAFT Polymerization

open access: yesAngewandte Chemie, EarlyView.
A photocontrolled RAFT strategy enables the alternating copolymerization of 1,3‐disubstituted bicyclo[1.1.0]butanes with electron‐deficient comonomers, affording well‐defined copolymers bearing strained cyclobutane backbones. A high degree of alternation, tunable molecular weights, and excellent end‐group fidelity are achieved through a CTA‐mediated ...
Xia Hu   +4 more
wiley   +2 more sources

Modulating Covalent Organic Framework Nanochannel Microenvironments for Sustainable Hydrogen Peroxide Photosynthesis

open access: yesAngewandte Chemie, EarlyView.
Alkoxy side chains regulate hydrazone‐linked COF nanochannel microenvironments by tuning pore polarity, reactant adsorption, and charge‐separation behavior. The optimized framework facilitates oxygen activation and hydrogen peroxide photosynthesis in real water and a 1 L natural‐sunlight reactor. LCA further shows that natural sunlight and larger‐scale
Ruixue Sun   +11 more
wiley   +2 more sources

One‐Pot Synthesis of Aqueous PEDOT‐Based Conductive Inks via Sequential RAFT/Oxidative Polymerization

open access: yesAngewandte Chemie, EarlyView.
We developed a fast, aqueous one‐pot synthesis for PEDOT:PSTFSI, combining sequential reversible addition–fragmentation chain‐transfer (RAFT) and oxidative polymerization. This method eliminates toxic solvents and purification steps, achieving full monomer conversion in under 3 h.
Fantine Negny   +6 more
wiley   +2 more sources

From Berzelius to Hyperspace: Previously Unrecognized Network of Reactivity in Textbook Brominations

open access: yesAngewandte Chemie, EarlyView.
Robotic scans across multidimensional condition spaces of classic bromination reactions uncover regions of previously unrecognized reactivity, yielding new major products and novel substitution patterns. Correlation and anticorrelation analyses of product distributions across these hyperspaces enable reconstruction of the underlying mechanistic ...
Yankai Jia   +9 more
wiley   +2 more sources

Natural Sunlight IR‐Driven Highly Efficient Synthesis of Acetaldehyde From Bioethanol Over Cu/Fe2O3

open access: yesAngewandte Chemie, EarlyView.
This work reports a Cu/Fe2O3 catalyst for the conversion of bioethanol into valuable acetaldehyde and green hydrogen under both infrared (IR) light and natural sunlight. This IR‐driven system sets a new performance benchmark, with TON and initial TOF enhanced by at least one order of magnitude, enabled by a constructed IR photon‐to‐phonon channel and ...
Xiyi Li   +10 more
wiley   +2 more sources

Microbially-Induced Carbonate Precipitation in Low pH Cement; Potential for Self-Healing in Radioactive Waste Geodisposal Systems

open access: yesACS Omega
Ananya Singh   +6 more
doaj   +1 more source

Plant‐Derived Silver Nanoparticles From Senegalia catechu: Antimicrobial Activity and Sunlight‐Driven Photocatalysis

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Silver nanoparticles (Ag NPs) have garnered attention for their environmental and medicinal potential, emphasizing the need for eco‐friendly synthesis. This study produces Ag NPs by reacting silver nitrate with aqueous Senegalia catechu leaf extract, a reductant and stabilizer.
Devendra Khadka   +6 more
wiley   +1 more source

Catalytic Pyrolysis of Waste Polystyrene Over Fe–B Composite Catalyst for Enhanced Liquid Fuel Production

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Healthcare derived polystyrene waste represents a growing and under addressed fraction of plastic waste streams due to contamination risks and limited recyclability. This study aims to investigate the valorization of waste polystyrene foam through catalytic and noncatalytic pyrolysis pathways to evaluate product yield distribution and identify
Salman Khan   +4 more
wiley   +1 more source

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