Results 11 to 20 of about 2,119 (107)

Hydrophilic sulfonated bis-1,2,4-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes. [PDF]

open access: yesChem Sci, 2015
We report the first examples of hydrophilic 6,6′-bis(1,2,4-triazin-3-yl)-2,2′-bipyridine (BTBP) and 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands, and their applications as actinide(III) selective aqueous complexing agents.
Lewis FW   +6 more
europepmc   +2 more sources

Космический мусор, как следствие человеческой деятельности [PDF]

open access: yes, 2016
В данной статье рассматриваются проблемы загрязнения космического пространства. В статьеописывается, какими опасными могут быть космические полеты, даже беспилотные спутники находятсяв постоянной опасности.
Assipkina, L. A.
core   +2 more sources

Structure and separation quality of various N- and O-donor ligands from quantum-chemical calculations

open access: yesNukleonika, 2015
Although BTP (2,6-di(1,2,4-triazin-3-yl)pyridine) has been proven to be a highly effective N-donor ligand for the selective An(III)/Ln(III) separation, the origin of its selectivity is still under discussion.
Trumm Michael   +2 more
doaj   +1 more source

TS-BTPhen as a promising hydrophilic complexing agent for selective Am(III) separation by solvent extraction

open access: yesNukleonika, 2015
The novel hydrophilic back-extraction agent TS-BTPhen (3,3ʹ,3ʺ,3ʹʺ-[3-(1,10-phenanthroline-2,9-diyl)-1,2,4-triazine-5,5,6,6-tetrayl]tetrabenzenesulfonic acid) was tested for its selectivity towards Am(III) over Cm(III) and Eu(III) with a TODGA (N,N,Nʹ,Nʹ-
Kaufholz Peter   +6 more
doaj   +1 more source

About the Possibility of Disposal of HLRW in Deep Boreholes in Germany

open access: yesGeosciences, 2017
Using deep boreholes for the final disposal of high-level radioactive waste (HLRW) can take advantage of multiple geologic barriers as safety features and aims for the safe containment of radionuclides by containment-providing rock zones (CPRZ).
Guido Bracke   +4 more
doaj   +1 more source

Reprocessability of molybdenum and magnesia based inert matrix fuels

open access: yesNukleonika, 2015
This work focuses on the reprocessability of metallic 92Mo and ceramic MgO, which is under investigation for (Pu,MA)-oxide (MA = minor actinide) fuel within a metallic 92Mo matrix (CERMET) and a ceramic MgO matrix (CERCER). Magnesium oxide and molybdenum
Ebert Elena L.   +5 more
doaj   +1 more source

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH3)2SOH3O+, and in dichlorobis(dimethyl sulfoxide) palladium(II) and platinum(II) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy [PDF]

open access: yes, 2009
The strongly hydrogen bonded species (CH3)(2)SO center dot center dot center dot H3O+ formed in concentrated hydrochloric acid displays a new low energy feature in its sulfur K-edge X-ray absorption near edge structure (XANES) spectrum.
Abbasi   +32 more
core   +1 more source

Gamma radiolytic stability of CyMe4BTBP and the effect of nitric acid

open access: yesNukleonika, 2015
The highly selective nitrogen donor ligand CyMe4BTBP for An(III) separation by solvent extraction was irradiated in a 60Co γ-source under varying conditions.
Schmidt Holger   +5 more
doaj   +1 more source

5d-5f Electric-multipole Transitions in Uranium Dioxide Probed by Non-resonant Inelastic X-ray Scattering

open access: yes, 2010
Non-resonant inelastic x ray scattering (NIXS) experiments have been performed to probe the 5d-5f electronic transitions at the uranium O(4,5) absorption edges in uranium dioxide.
Caciuffo, R.   +6 more
core   +1 more source

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