Results 201 to 210 of about 194,772 (288)

Performance of GPT-based large language models in hepatocellular carcinoma stratification: liver function assessment, BCLC staging, and treatment recommendations. [PDF]

Sci Rep
Masthoff M, Zipser A, Praktiknjo M, Trebicka J, Morgül H, Pascher A, Pöhler G, Köhler M, Schindler P.   +8 more
europepmc   +1 more source

A High Energy Barrier DyIII2 Single‐Molecule Magnet Supported by a Bulky, Anionic N–O Bridging Ligand

Chemistry – A European Journal, EarlyView.
Complex [Dy2(hynad)2(dbm)4] was prepared by the employment of the anionic N–O‐based bridging and chelating N‐hydroxy‐1,8‐naphthalimide ligand, featuring a {Dy2(µ‐OR)2}4+ core and exhibiting zero‐field SMM behavior with a Ueff value of 171 K and double‐S‐shaped hysteresis loops, open up to 3.5 K.
Alexandros S. Armenis, Concepción Molina‐Jirón, Konstantinos N. Pantelis, Wolfgang Wernsdorfer, Mario Ruben, Eufemio Moreno‐Pineda, Theocharis C. Stamatatos   +6 more
wiley   +1 more source

Breaking the Mold: Electrophilic Hydrophosphanation Emerges

Chemistry – A European Journal, EarlyView.
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo, Janeth Navarro, Judit Cano‐Asensio, José A. López, Cristina Tejel   +4 more
wiley   +1 more source

Semiconducting Single‐Wall Antimony Oxide Nanotubes and Oxidotritelluridoantimonate(V) Anions

Chemistry – A European Journal, EarlyView.
Antimony(V) binds directly to tellurium(−II) in the (SbOTe3)3− anion. The latter has been found between Sb2O3 nanotubes in a microporous cetineite structure. The Sb2O3 nanotube is positively polarized on its outer surface and negatively polarized on its inner surface, corresponding to a cylindrical capacitor. Substantial charge transfer from the anions
Huanyu He, Oleg Janson, Vitaliy Romaka, Michael Ruck   +3 more
wiley   +1 more source

Temperature‐Dependent Kinetics of Plasma‐Based CO2 Conversion: Interplay of Electron‐Driven and Thermal‐Driven Chemistry

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The transformation of CO2 into chemical building blocks is essential for a net‐zero energy future. Plasma‐chemical processing offers promising potential to achieve this. Here, we explore a temperature‐dependent plasma‐chemical reaction mechanism, revealing a shift from electron‐driven to thermal‐driven CO2 conversion regimes.
Aswath Mohanan, Ramses Snoeckx, Min Suk Cha   +2 more
wiley   +1 more source

Single‐cell sequencing reveals potential novel insights into appendage‐patterning and joint‐development in a spider

Developmental Dynamics, EarlyView.
Abstract Background Jointed appendages represent one of the key innovations of arthropods, and thus understanding the development and evolution of these structures is important for the understanding of the evolutionary success of Arthropoda. In this paper, we analyze a cell cluster that was identified in a previous single‐cell sequencing (SCS ...
Brenda I. Medina‐Jiménez, Graham E. Budd, Ralf Janssen   +2 more
wiley   +1 more source

Engineering the Lattice and Electronic Configurations of N‐Rich‐CoMoCN by Mo Doping and N Enrichment for Enhanced Water Splitting

EcoEnergy, EarlyView.
This study design Mo‐doped and N‐rich‐CoMoCN bimetal for bi‐functionally efficient overall water splitting catalysts by constructing an active site and engineering the interfacial Co6Mo6C2/Co heterojunction in a N‐doped porous carbon matrix and study on the performance of catalyst for electrocatalytic.
Huimin Yang, Yue Xiao, Zhuo Wang, Mingfang Zhang, Haimei Xu, Yunzhao Fan, Chao Feng, Qingcheng Hu, Chunhua Yuan, Yang Fu, Lingfeng Zhu, Songbo Li, Tianyi Ma   +12 more
wiley   +1 more source

Cobalt‐Free Single‐Crystal Cathodes for Next‐Generation Lithium‐Ion Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Cobalt‐free single‐crystal cathodes enhance lithium‐ion battery stability by mitigating fracture, degradation, and phase transitions. This review highlights Ni‐rich layered, Li‐Mn‐rich, spinel, and olivine frameworks, synthesis strategies enabling morphology and defect control, and structural tuning via doping and coatings, offering pathways toward ...
Srinivasan Alagar, Rakesh Saroha, Jun Kim, Hyung Do Kim, Jung Sang Cho, Sang Mun Jeong   +5 more
wiley   +1 more source

Unraveling Synergistic Regulation Mechanism in Nitrogen/Sulfur Co‐Doped Biomass‐Derived Hard Carbon Toward Durable Sodium‐Ion Battery Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nitrogen/sulfur co‐doping optimizes the electron and spatial structure of biomass‐derived hard carbon, and the anode demonstrates superior long‐term cycling stability over 2000 cycles, validating an improved “adsorption‐intercalation‐pore filling” mechanism.
Qian Long, Fangyuan Zhang, Jiayu Qu, Songtao Li, Renfei Cheng, Yaning Zhao, Di Guo, Zhengwang Zhu, Haifeng Zhang   +8 more
wiley   +1 more source

Entropy‐Driven Innovations: Entropy Stabilized Oxides for High‐Performance Next‐Generation Lithium–Sulfur Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This article explores high‐entropy‐stabilized oxides (HEOs) as novel functional materials for addressing critical issues in lithium–sulfur (Li–S) batteries, including lithium polysulfide (LPS) shuttling, inadequate conductivity, and slow redox kinetics.
Hassan Raza, Jialiang Wei, Zhicai Wang, Zhaoyang Lv, Junye Cheng, Jia Xu, Liang An, Yuliang Liu, Sergey Ryazantsev, Shukui Li, Guangping Zheng   +10 more
wiley   +1 more source