Results 71 to 80 of about 1,637 (264)

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

A Tale of Three Cities: Deconstructing the Cross of Gastines in Paris, 1571

open access: yesArtium Quaestiones
This article considers the erection and subsequent removal of the Parisian Cross of Gastines, a monument commemorating the execution of three Protestant men, between 1569 and 1571. It seeks to foreground the spatial qualities of this tumultuous episode,
Tom Joashi, Maximilian Sternberg
doaj   +1 more source

Collagen‐membrane‐covered matrix‐associated chondrocyte implantation improves safety over periosteum‐covered MACI for large knee cartilage defects: A real‐world data analysis in the registry study

open access: yesKnee Surgery, Sports Traumatology, Arthroscopy, EarlyView.
Abstract Purpose This registry study aimed to evaluate the safety and effectiveness of collagen membrane‐covered matrix‐associated autologous chondrocyte implantation (cMACI) versus periosteum‐covered MACI (pMACI) for large knee cartilage defects (Outerbridge III–IV, ≥4 cm²) in the femorotibial and/or patellofemoral joints with a minimum 2‐year follow ...
Yuji Uchio   +4 more
wiley   +1 more source

Loop Quantum Photonic Chip for Coherent Multi‐Time‐Step Evolution

open access: yesLaser &Photonics Reviews, EarlyView.
A loop quantum photonic chip (Loop‐QPC) enabling efficient multi‐step quantum simulation in a single run is demonstrated. Combining recirculating loops with cycle‐or‐measure control, Loop‐QPC eliminates repeated reprogramming and reduces loss. Experimental demonstration of three‐step unitary evolution confirms high‐fidelity operation, showcasing the ...
Yuancheng Zhan   +9 more
wiley   +1 more source

Quantization of Polaritons Confined in Dielectric Structures

open access: yesLaser &Photonics Reviews, EarlyView.
This study addresses the limitations of the Hopfield model of strong light‐matter coupling in the case of structured dieletrics. A method to derive quantum models in the polariton basis using Bogoliubov transformation and third quantization is introduced, demonstrating how to boost interaction strength and engineer nonlocal interactions for strongly ...
Amir Rahmani   +4 more
wiley   +1 more source

Three‐Dimensional Optical Characterization of Magnetostrictive Deformation in Magnomechanical Systems

open access: yesLaser &Photonics Reviews, EarlyView.
An optical approach is proposed for real‐time and high‐precision detection of the magnetostrictive deformation of an yttrium‐iron‐garnet sphere in three dimensions, based on the deformation induced spatial high‐order modes of the scattered field, postselection, and balanced homodyne detection.
Xiaomin Liu   +5 more
wiley   +1 more source

Theory of Supercritical Coupling and Generalized Bound States in the Continuum

open access: yesLaser &Photonics Reviews, EarlyView.
We develop a general theory of supercritical coupling and generalized bound states in the continuum (gBICs), revealing how interference between radiative and absorptive channels enables quality factors beyond conventional material‐loss limits. The framework unifies non‐Hermitian mode coupling, causality‐driven reactive interactions, and interference ...
Sergio Balestrieri   +3 more
wiley   +1 more source

Optimal Universal Bounds for Waves With Varied Coherence Based on Supremum and Infimum Coherence Spectra

open access: yesLaser &Photonics Reviews, EarlyView.
Coherence variation is ubiquitous in nature, yet determining how it constrains physical observables remains challenging for multimode waves. To address this challenge, this work establishes a majorization‐based theory that identifies the supremum and infimum in the set of input coherence spectra, which provide optimal universal bounds for any linear ...
Shiyu Li, Cheng Guo
wiley   +1 more source

Bounded Frequency Lattices in Coupled Lithium Niobate Ring Cavities

open access: yesLaser &Photonics Reviews, EarlyView.
We leverage coupled asymmetric ring resonators in realizing bounded tight‐binding frequency lattices and demonstrate their discrete band structures on an integrated device. Suppression of long‐range coupling with a single auxiliary cavity is demonstrated by combining mode splitting and coupled waveguide dispersion effects.
Hiep Xuan Dinh   +5 more
wiley   +1 more source

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