Results 81 to 90 of about 159,205 (268)

Structure and electrochromism of two-dimensional octahedral molecular sieve h’-WO3

open access: yesNature Communications, 2019
Thanks to their versatile redox behaviors, octahedral molecular sieves show promise in a range of electrochemical applications. Here the authors report a hexagonal polymorph of tungsten trioxide, an octahedral molecular sieve that exhibits fast proton ...
Julie Besnardiere   +12 more
doaj   +1 more source

Isomerization Mechanisms of a Labile Co(II) Octahedral Complex

open access: yesCHIMIA, 2006
The labile cobalt (II) complex [Co(TUF)2(Pic)2] with 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (TUF) bidentate and 4-methylpyridine (Pic) monodentate ligands was studied by variable temperature (VT) 19F NMR from 184 to 312 K.
Fabrice Riblet   +4 more
doaj   +1 more source

High‐Yield Synthesis of Fe‐NC Electrocatalysts Using Mg2+ Templating and Schiff‐Base Porous Organic Polymers

open access: yesAdvanced Functional Materials, EarlyView.
Fe─NC porous oxygen reduction electrocatalysts are prepared employing a 2,4,6‐Triaminopyrimidine‐based porous organic polymer, a Mg2+ Lewis acid, and a low‐temperature cation exchange protocol. Using the polymer precursor achieves high pyrolysis yields and results in atomically dispersed FeNx sites. The resulting catalysts feature hierarchical porosity
Eliot Petitdemange   +11 more
wiley   +1 more source

Octahedrality and Gâteaux smoothness

open access: yesJournal of Mathematical Analysis and Applications
We prove that every Banach space admitting a Gateaux smooth norm and containing a complemented copy of $\ell_1$ has an equivalent renorming which is simultaneously Gâteaux smooth and octahedral. This is a partial solution to a problem from the early nineties.
Ch. Cobollo, P. Hájek
openaire   +3 more sources

Atomically Revealing Bulk Point Defect Dynamics in Hydrogen‐Driven γ‐Fe2O3 → Fe3O4 → FeO Transformation

open access: yesAdvanced Functional Materials, EarlyView.
In situ TEM uncovers the atomic‐scale mechanisms underlying hydrogen‐driven γ‐Fe2O3→Fe3O4→FeO reduction. In γ‐Fe2O3, oxygen vacancies cluster around intrinsic Fe vacancies, leading to nanopore formation, whereas in Fe3O4, vacancy aggregation is suppressed, preserving a dense structure.
Yupeng Wu   +14 more
wiley   +1 more source

Synergistic Compatibilization of CsPbBr3 Perovskites and HfO2 Nanocrystals for Hybrid Sensitized Nanoscintillators

open access: yesAdvanced Functional Materials, EarlyView.
Lead halide perovskite nanocrystals are promising scintillators but suffer from reabsorption losses and limited compatibility with high‐Z additives. Hybridization of CsPbBr3 nanocrystals with PbBr2‐passivated HfO2 nanoparticle sensitizers, achieved during or after synthesis, produces stable composites with maintained optical quality, improved ...
Francesco Bruni   +17 more
wiley   +1 more source

Comparison of Octahedral and Spherical Nanoparticles for Plasmonics

open access: yesIEEE Photonics Journal, 2019
Monocrystalline metallic nanoparticles are preferable for plasmonic applications, but grow only in polyhedral shapes, which deviate from the predominantly employed spherical shape.
Simeon Trendafilov   +3 more
doaj   +1 more source

Predicting the Photoelectron Spectra of Quasi Octahedral Al6Mo‐ Cluster

open access: yesChemistryOpen, 2020
We have recently developed a computational methodology to separate the effects of size, composition, symmetry and fluxionality in explaining the experimental photoelectron spectra of mixed‐metal clusters.
Dr. Paulo H. Acioli
doaj   +1 more source

Impact of Lattice Heterogeneity on Broadband Optical Retardation in Stacked 2D Perovskite Single Crystals

open access: yesAdvanced Functional Materials, EarlyView.
It is shown that interfaces between organic and inorganic layers govern long‐range stacking disorder and in‐plane anisotropy in 2D metal‐halide perovskites. By comparing single‐cation AB‐AB and ordered mixed‐cation ABCD‐ABCD stackings, SCXRD reveals enhanced mosaicity, while optics confirm high birefringence.
Yixuan Dou   +6 more
wiley   +1 more source

Crystal structure and Mössbauer study of FeAl2O4

open access: yesNukleonika, 2015
In this work the synthesis of hercynite from Fe2O3 and Al2O3 powders was carried out by arc-melting method under the protective argon atmosphere. The obtained material was characterized with the use of powder X-ray diffractometry (XRD) and Mössbauer ...
Jastrzębska Ilona   +6 more
doaj   +1 more source

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