Results 91 to 100 of about 6,053,605 (298)

A Ship‐in‐a‐Bottle Strategy: Crosslinking Amines and Epoxides inside MOF Pores for Enhanced CO2 Capture Performance

open access: yesAdvanced Materials, EarlyView.
A “ship‐in‐a‐bottle” strategy is used to grow oligomers inside of a MOF by crosslinking alkylamines with epoxides within the pores of Cr‐BDC. When tested in postcombustion carbon capture applications, the composites show excellent performance with high CO2 adsorption capacity, exceptional CO2/N2 selectivity, and enhanced stability over 100 adsorption ...
Jordi Espín   +7 more
wiley   +1 more source

Computational Modeling of Reticular Materials: The Past, the Present, and the Future

open access: yesAdvanced Materials, EarlyView.
Reticular materials are advanced materials with applications in emerging technologies. A thorough understanding of material properties at operating conditions is critical to accelerate the deployment at an industrial scale. Herein, the status of computational modeling of reticular materials is reviewed, supplemented with topical examples highlighting ...
Wim Temmerman   +3 more
wiley   +1 more source

Structural Control of Photoconductivity in a Flexible Titanium‐Organic Framework

open access: yesAdvanced Materials, EarlyView.
The concept of flexibility is extended to titanium frameworks and use it to gain control over charge transport. MUV‐35 is a flexible doubly interpenetrated framework that can shrink spontaneously its volume by ≈40% to afford a photoconductive, porous state that is thermodynamically favored by non‐covalent interactions. Abstract The soft nature of Metal‐
Clara Chinchilla‐Garzón   +6 more
wiley   +1 more source

Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

open access: yesAdvanced Materials, EarlyView.
This review explores how in situ and operando spectroscopic techniques reveal the real‐time behavior of reticular materials, including MOFs and COFs. These methods track material formation and functionalization, structural changes, defect formation, dynamic responses to external triggers, and catalytic processes.
Bettina Baumgartner   +4 more
wiley   +1 more source

State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials

open access: yesAdvanced Materials, EarlyView.
Different approaches to MOF‐NP composite formation, such as ship‐in‐a‐bottle, bottle‐around‐the‐ship and in situ one‐step synthesis, are used. Owing to synergistic effects, the advantageous features of the components of the composites are beneficially combined, and their individual drawbacks are mitigated.
Stefanos Mourdikoudis   +6 more
wiley   +1 more source

SOME NEW SULFONATO ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES

open access: yesScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2015
Three new adducts have been synthesized and studied by infrared and NMR spectroscopies. The suggested structures are discrete with a pyridine -3- sulfonate acting as a tri O-chelating and N-donor or as a non σ coordinating ligand, a 4 ...
MOUHAMADOU BIRAME DIOP, LIBASSE DIOP
doaj  

Solvent‐Free Fabrication Methods of Metal Halide Perovskites

open access: yesAdvanced Materials, EarlyView.
This review explores the current status of solvent‐free fabrication methods of metal halide perovskites, such as thermal evaporation, magnetron sputtering, pulsed laser deposition, e‐beam and atomic layer deposition, solid phase growth, and laser printing.
Ran Ji   +5 more
wiley   +1 more source

10 Years Development of Potassium‐Ion Batteries

open access: yesAdvanced Materials, EarlyView.
Significant progress is made in PIBs over the past decade, but the improvements based on half‐cell testing, low mass loading, and low energy density are insufficient for practical applications. This review summarizes the challenges and strategies for PIBs, highlights the importance of further research focusing on full cells, and provides an analysis of
Mingnan Li   +7 more
wiley   +1 more source

Advanced Air Electrodes for Reversible Protonic Ceramic Electrochemical Cells: A Comprehensive Review

open access: yesAdvanced Materials, EarlyView.
Reversible protonic ceramic electrochemical cells (R‐PCECs) face challenges from sluggish and unstable oxygen reduction and evolution reactions in the air electrode. This review discusses recent progress in triple‐conducting air electrodes, emphasizing mechanisms, performance factors, and design strategies, offering guidance for creating efficient and ...
Xi Chen   +8 more
wiley   +1 more source

Arsenic Incorporation in Pyrite at Ambient Temperature at Both Tetrahedral S-I and Octahedral FeII Sites: Evidence from EXAFS-DFT Analysis.

open access: yesEnvironmental Science and Technology, 2017
P. Le Pape   +8 more
semanticscholar   +1 more source

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