Results 131 to 140 of about 6,053,605 (298)

Stimuli‐Responsive Low‐Frequency Terahertz Absorption ON‐OFF Switchability in Spin‐Crossover Material

open access: yesAdvanced Materials, EarlyView.
A switchable Fe(II)–Hg(II) coordination polymer exhibits reversible ON‐OFF terahertz (THz) absorption through temperature‐ and light‐induced spin‐crossover. The material shows strong, tunable THz responses linked to phonon modes around Fe(II) centers, supported by spectroscopic measurements and calculations.
Guanping Li   +13 more
wiley   +1 more source

Polycondensation as a Universal Method for Preparing High‐Density Single‐Atom Catalyst Libraries

open access: yesAdvanced Materials, EarlyView.
This paper presents a universal bottom‐up polycondensation strategy for synthesizing high‐density single‐atom catalysts (HD‐SACs) with metal loadings up to 27.5 wt%. Using various metal monomers with 1,10‐phenanthroline‐5,6‐dione ligands, it generates atomically dispersed mono‐ and bimetallic HD‐SACs.
Jaques‐Christopher Schmidt   +21 more
wiley   +1 more source

Multimaterial 3D Printing in Activating Bath Enables In Situ Polymerization of Thermosets with Intricate Geometries and Diverse Elastic Behaviors

open access: yesAdvanced Materials, EarlyView.
A new embedded 3D printing (EMB3D) strategy enables in situ polymerization of DCPD/COD‐based inks within a fugitive reactive matrix where the activator in the matrix cures the printed filament. Cured ink properties are tunable through DCPD‐COD comonomer ratios, yielding materials from stiff thermosets to soft elastomers.
Young Bum Lee   +9 more
wiley   +1 more source

Development of an atomic cluster expansion potential for iron and its oxides. [PDF]

open access: yesNPJ Comput Mater
Bienvenu B   +6 more
europepmc   +1 more source

Ion Valency as a Molecular Switch for Salt‐Resistant Underwater Adhesion

open access: yesAdvanced Materials, EarlyView.
Monovalent K+ ions weaken adhesion by forming K+‐π complexes with weak bridging capacity. In contrast, multivalent cations like Y3+ enhance adhesion by forming stable π‐cation‐π bridging networks, which are resistant to salt and capable of compensating for the loss of native π–π and NH3+‐π interactions.
Chang‐Sheng Wang   +13 more
wiley   +1 more source

Long-lived photoinduced polar states in metal halide perovskites. [PDF]

open access: yesNat Commun
Dou Y   +17 more
europepmc   +1 more source

Valence and Site Engineering Enable Efficient Broadband Near‐Infrared Emission at 960 nm in Cr3+‐Activated Forsterite

open access: yesAdvanced Materials, EarlyView.
This study reports a near‐infrared (NIR) luminescent material (Mg2SiO4:1.5%Cr,5%Li) with efficient (EQE = 48%) ultra‐broadband (FWHM ≈ 2413 cm−1 (226 nm)) NIR emission at 960 nm upon blue‐light excitation. This innovation addresses the low efficiency of long‐wavelength (λmax > 900 nm) NIR‐emitting materials due to the radiationless de‐activation and ...
Lei Zhong   +11 more
wiley   +1 more source

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