Results 81 to 90 of about 6,053,605 (298)

Synthesis and Electronic Structure of the Fractionally Occupied Double Perovskite EuTa2O6 with Ordered Europium Vacancies

Advanced Functional Materials, EarlyView.
Two‐dimensional electronic states are the foundation of modern semiconductor technology. Here, we report molecular‐beam epitaxy growth of fractional double perovskite, EuTa2O6. Reciprocal space mapping and transmission electron microscopy confirm a layered ordering of A‐site cations.
Tobias Schwaigert, Ali Barooni, Benjamin Gregory, Paul Malinowski, Anirudh Tenneti, Sonia Hasko, Brenan Palazzolo, Jeffrey W Hodgson, Brendan Faeth, Patrick M. Woodward, Kyle M. Shen, Andrej Singer, Maryam Ghazisaeidi, Salva Salmani‐Rezaie, Darrell G. Schlom, Kaveh Ahadi   +15 more
wiley   +1 more source

Halide Perovskite Radiation Detectors: Conventional Imaging Applications and New Opportunities

Advanced Functional Materials, EarlyView.
Organic–inorganic hybrid halide perovskite (OIHP) semiconductors, owing to their exceptional optoelectronic properties, are emerging as promising next‐generation integrated radiation detectors for applications in medical radiodiagnosis and healthcare monitoring.
Dou Zhao, Yeon‐Woo Choi, Tomoyuki Yokota, Takao Someya, Nam‐Gyu Park   +4 more
wiley   +1 more source

Ce3+‐Activated Lithium Rare‐Earth Oxonitridolithosilicates: A New Class of LED Phosphors with Similarities to Garnets

Advanced Functional Materials, EarlyView.
Garnet‐like luminescence upon Ce3+‐activation is found in the first six representatives Li9RESi4N4O8 (RE = Y, La, Gd, Dy, Yb, Lu) of the substance class of lithium rare‐earth oxonitridolithosilicates, which also show a novel structure type. High‐temperature solid‐state synthesis yielded crystalline samples for single‐crystal X‐ray diffraction‐based ...
Kilian M. Rießbeck, Markus Seibald, Christiane Stoll, Anja Köbler, Markus Suta, Hubert Huppertz   +5 more
wiley   +1 more source

Hemilabile phosphine ligands in molybdenum and tungsten octahedral environments

, 2010
The synthesis of three bidentate, hemilabile phosphine ligands, newly synthesized in the research group (TPOdiphos, DPPrPOdiphos and SODPdiphos), has been up-scaled and optimized. The ligand substitution reaction on Mo(CO)6 and W(CO)6 has been studied and the corresponding complexes fac-[MTPOdiphos(CO)3], fac-[MDPPrPOdiphos(CO)3 ...
openaire   +1 more source

Ion and Solvent Dynamics in Charged 2D Clay Nanoslits with Unprecedented Ångström‐Precise Slit Height Control

Advanced Functional Materials, EarlyView.
The slit height of fluorohectorite 2D‐nanochannels is tuned with Å‐precision (2.4–250 Å). Slit‐height‐dependent ion and water mobilities are quantified by applying EIS, PFG‐NMR, and SFG‐NMR with MD simulations guiding interpretation. Diffuse properties are investigated with CP‐AFM, MD, and PB.
Max Stevenson, Sandra Pappler, Leonie Kanzler, Aqsa Nisar, Jepsinraj Kakkuzhiyulla Parambath, Markus Rosenstihl, Flora Lebeda, Sebastian Weiß, Georg Papastavrou, Michael Vogel, Jürgen Senker, Josef Breu   +11 more
wiley   +1 more source

Cr3+‐Activated Tunable Near‐Infrared Mechanoluminescence Materials for Potential Water Pollutant Monitoring

Advanced Functional Materials, EarlyView.
Four kinds of magnetite type NIR‐ML materials are synthesized by high‐temperature solid‐state reaction method. The continuous spectral tuning from a sharp R line (698 nm) to a broadband range (650–1000 nm) is realized based on composite engineering, concentration engineering, and lattice engineering strategies.
Xuesong Wang, Yao Xiao, Puxian Xiong, Pan Zheng, Shengbing Xu, Wenzhao He, Haiqiang Fang, Pengzhe Wang, Jiayi Yu, Sheng Wu, Qi Qian   +10 more
wiley   +1 more source

Coupled Ferroelectric–Photoelectrochemical in Water Reduction Over BiFeO3 Thin Film Heterostructure Modulated by Rare‐Earth Doping

Advanced Functional Materials, EarlyView.
Gd‐doped BFO (BGFO) exhibits a ∼2‐order reduction in leakage current owing to its lowest content of oxygen vacancies. This leads to a ∼2.5‐fold increase in remnant polarization. These improvements in BGFO effectively boost charge separation and transportation, resulting in the greatest incident photon‐to‐current efficiency of 12.9 ± 0.73% and a ∼1.5 ...
Ming‐Wei Chu, Narong Chanlek, Cheng‐Sao Chen, Pin‐Yi Chen, Kuei‐Chih Feng, Chi‐Shun Tu, Chang Fu Dee, Wei Sea Chang   +7 more
wiley   +1 more source

Emergent Spin‐Glass Behavior in an Iron(II)‐Based Metal–Organic Framework Glass

Advanced Functional Materials, EarlyView.
A one‐pot, solvent‐free synthesis yields an Fe2+‐based metal‐organic framework (MOF) glass featuring a continuous random network structure. The material exhibits spin‐glass freezing at 14 K, driven by topological‐disorder and short‐range magnetic frustration, showcasing the potential of MOF glasses as a plattform for cooperative magnetic phenomena in ...
Chinmoy Das, Soma Salamon, Joachim Landers, Jan‐Benedikt Weiß, Wen‐Long Xue, Pascal Kolodzeiski, Roman Pallach, Heiko Wende, Sebastian Henke   +8 more
wiley   +1 more source

Zn2(Y)·H2O, (Me4N)2H2Y·3ZnCl2, (Me4N)4Y·5ZnCl2·H2O, (BzNMe3)2H2Y·2ZnBr2, Zn(H2Y)·4ZnCl2·2EtOH·14H2O AND Zn(H2Y)·6ZnCl2·2EtOH·6H2O (Y = EDTA): SYNTHESIS AND INFRARED STUDY

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2015
Six acidic or neutral ethylenediaminetetraacetato [H2Y2-, H3Y- or Y4-] containing adducts and derivatives have been synthesized and studied by infrared.
SERIGNE CISSE, IBRAHIMA CISSE, LIBASSE DIOP   +2 more
doaj  

Computational Simulations of Metal–Organic Frameworks to Enhance Adsorption Applications

Advanced Materials, EarlyView.
This review highlights the significance of molecular simulations in expanding the understanding of metal–organic frameworks (MOFs) and improving their gas adsorption applications. The historical development and implementation of molecular simulations in the MOF field are given, high‐throughput computational screening studies used to unlock the ...
Hilal Daglar, Hasan Can Gulbalkan, Gokhan Onder Aksu, Seda Keskin   +3 more
wiley   +1 more source