Results 61 to 70 of about 11,347 (297)

Exciton Binding Energy Modulation in 2D Perovskites: A Phenomenological Keldysh Framework

open access: yesAdvanced Functional Materials, EarlyView.
The intrinsic screening effects are successfully decoupled from structural distortion by rigorously designing a series of 2D perovskites. This enabled us to demonstrate how the dielectric environment modulates the quasiparticle bandgap and exciton binding energy.
Kitae Kim   +15 more
wiley   +1 more source

Impact of Lattice Heterogeneity on Broadband Optical Retardation in Stacked 2D Perovskite Single Crystals

open access: yesAdvanced Functional Materials, EarlyView.
It is shown that interfaces between organic and inorganic layers govern long‐range stacking disorder and in‐plane anisotropy in 2D metal‐halide perovskites. By comparing single‐cation AB‐AB and ordered mixed‐cation ABCD‐ABCD stackings, SCXRD reveals enhanced mosaicity, while optics confirm high birefringence.
Yixuan Dou   +6 more
wiley   +1 more source

Spatially Tailorable Liquid Crystalline Elastomer Alignment During Digital Light Process 3D Printing

open access: yesAdvanced Functional Materials, EarlyView.
Here, we report the fabrication of 3D printable liquid crystalline elastomer (LCE) structures with spatially tailorable alignment domains within the same layer. This work addresses the long‐standing challenge of preparing complex 3D LCE architectures with patterned functional domains to achieve nonlinear deformations. Fabrication of multi‐domains in 3D
Adam Bischoff   +8 more
wiley   +1 more source

Atomic‐Level Dual‐Cation Engineering Enables High‐Performance Na4VMn(PO4)3 Cathodes for Sodium‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Dual‐cation site engineering unlocks stable and fast sodium storage in Na4VMn(PO4)3 cathodes. Li+ at Na2 suppresses Jahn‐Teller distortion, while K+ at Na1 expands ion channels, enabling synchronized V/Mn redox and quasi‐single‐phase kinetics. This atomic‐level strategy achieves ultralong cycling stability, high‐rate capability, and full cell viability
Jiaze Sun   +8 more
wiley   +1 more source

Photoconductivity‐Driven Quantum Efficiency Gain in Inorganic Ruddlesden‐Popper Layered Cs2PbBr2I2 Perovskite Photodetector for Visible Light Detection

open access: yesAdvanced Functional Materials, EarlyView.
Rational halogen mixing strategy was employed to shift the bandgap of Cs2PbBr2I2 from ultraviolet to visible region, enabling first realization of a visible‐light photodetector with this 2D layered Ruddlesden‐Popper perovskite material. Under illumination, light‐induced internal field forms and drives trap‐mediated persistent photoconductivity ...
Md Fahim Al Fattah   +11 more
wiley   +1 more source

Mechanical property of octahedron Ti6Al4V fabricated by selective laser melting

open access: yesReviews on Advanced Materials Science, 2021
The stress shielding effect is a critical issue for implanted prosthesis due to the difference in elastic modulus between the implanted material and the human bone.
Zhai Yun, He Sibo, Lei Lei, Guan Tianmin
doaj   +1 more source

Über die Bildungsweise von Polyanionen in wäßriger Lösung : Der Additionsmechanismus bei der Tetrawolframatbildung

open access: yesCHIMIA, 1969
  A reaction mechanism is developed for the first steps of the formation of isopolytungstates in acidified aqueous tungstate solutions. Because of the fast rate of formation for the tetratungstate ion an addition mechanism is assumed where a WO6 ...
K.H. Tytko, O. Glemser
doaj   +1 more source

Transition From Lattice Oxygen to Radical‐Mediated Oxidation in Ammonium‐Intercalated Birnessite Catalysts for Selective Valorization of Biomass to Produce Formic Acid

open access: yesAdvanced Functional Materials, EarlyView.
The catalytic valorization of biomass represents an essential approach for achieving sustainable chemical production, with formic acid (FA) being recognized as a valuable platform chemical for hydrogen storage and environmentally friendly synthetic applications.
Yiqi Geng   +6 more
wiley   +1 more source

A Programmable Semiconductor Containing Active Molecular Photoswitches Located in the Crystal's Volume Phase

open access: yesAdvanced Functional Materials, EarlyView.
A novel approach for the design of functional semiconductors is presented, which utilizes the excellent optoelectronic properties of layered hybrid perovskites and the possibility to introduce a molecular photoswitch as the organic spacer. This concept is successfully demonstrated on a coumarin‐based system with the possibility to change the bandgap ...
Oliver Treske   +4 more
wiley   +1 more source

Ilmenite-type Na2(Fe2/3Te4/3)O6

open access: yesIUCrData
Na2(Fe2/3Te4/3)O6 (Z = 3) or Na3(FeTe2)O9 (Z = 2), trisodium iron(III) ditellurium(VI) nonaoxide, adopts the ilmenite (FeTiO3, Z = 6) structure type with the Ti site (site symmetry 3.) replaced by Na and the Fe site (site symmetry 3.) replaced by a mixed-
Felix Eder, Matthias Weil
doaj   +1 more source

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